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Chloro{[(1R,2R)-(-)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(mesitylene)ruthenium(II), min. 90% RuCl[(R,R)-Tsdpen(mesitylene)

Basic information Reactions Safety Supplier Related

Chloro{[(1R,2R)-(-)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(mesitylene)ruthenium(II), min. 90% RuCl[(R,R)-Tsdpen(mesitylene) Basic information

Product Name:
Chloro{[(1R,2R)-(-)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(mesitylene)ruthenium(II), min. 90% RuCl[(R,R)-Tsdpen(mesitylene)
Synonyms:
  • Chloro{[(1R,2R)-(-)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(mesitylene)ruthenium(II), min. 90% RuCl[(R,R)-Tsdpen(mesitylene)
  • Chloro{[(1R,2R)-(-)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(
    mesitylene)ruthenium(II), min. 90% RuCl[(R,R)-Tsdpen(mesitylene)
  • Chloro[[(1R,2R)-(-)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido](mesitylene)ruthenium(II)
  • Chloro{[(1R,2R)-(-)-2-aMino-1,2-diphenylethyl](4-toluenesulfonyl)aMido}(Mesitylene)rutheniuM(II),90% RuCl[(R,R)-Tsdpen(Mesitylene)
  • [(R,R)-TsDPEN-Ru(Mesitylene)Cl]
  • [R-(R*,R*)]-[N-(2-Amino-1,2-diphenylethyl)-4-methylbenzenesulfonamidato-N,N']chloro[(1,2,3,4,6-η)-1,3,5-trimethylbenzene]ruthenium
  • Chloro[(1R,2R)-N-(p-toluenesulfonyl)-1,2-diphenylethanediamine](mesitylene)ruthenium(II)
  • Chloro{[(1R,2R)-(-)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(mesitylene)ruthenium(II),min.90%RuCl[(R,R)-Tsdpen(mesitylene),S)-Tsdpen](mesitylene)
CAS:
174813-82-2
MF:
C30H30ClN2O3RuS-
MW:
635.1588
Product Categories:
  • Ru
  • organometallic complex
Mol File:
174813-82-2.mol
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Chloro{[(1R,2R)-(-)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(mesitylene)ruthenium(II), min. 90% RuCl[(R,R)-Tsdpen(mesitylene) Chemical Properties

Melting point:
241-249°C
storage temp. 
2-8°C
form 
Powder
color 
orange
Sensitive 
air sensitive
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Safety Information

WGK Germany 
3
HS Code 
2931.90.6000
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Chloro{[(1R,2R)-(-)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(mesitylene)ruthenium(II), min. 90% RuCl[(R,R)-Tsdpen(mesitylene) Usage And Synthesis

Reactions

Catalyst used in the asymmetric transfer hydrogenation of ketones using formic acid-triethylamine mixture.

Uses

RuCl[(R,R)-TsDPEN](mesitylene) may be used as a catalyst to synthesize:

  • (2R,3S)-4-Benzyl-2-(hydroxyphenylmethyl)morpholin-3-one from racemic N-benzyl-2-benzoyl-3-morpholinone via dynamic kinetic resolution-based asymmetric transfer hydrogenation (ATH).
  • Chiral nonracemic δ-phenylseleno alcohols from δ-phenylseleno ketones via catalytic ATH reaction.

Chloro{[(1R,2R)-(-)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(mesitylene)ruthenium(II), min. 90% RuCl[(R,R)-Tsdpen(mesitylene)Supplier

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