Bromotris(dimethylamino)phosphonium hexafluorophosphate Chemical Properties

Melting point:

>300 °C(lit.)

storage temp. 

Keep in dark place,Inert atmosphere,Room temperature

form 

powder to crystal

color 

White to Almost white

Sensitive 

Light Sensitive

Major Application

peptide synthesis

InChI

InChI=1S/C6H18BrN3P.F6P/c1-8(2)11(7,9(3)4)10(5)6;1-7(2,3,4,5)6/h1-6H3;/q+1;-1

InChIKey

XELPBWPBGHCIKX-UHFFFAOYSA-N

SMILES

[P-](F)(F)(F)(F)(F)F.[P+](Br)(N(C)C)(N(C)C)N(C)C

CAS DataBase Reference

50296-37-2(CAS DataBase Reference)

Safety Information

Hazard Codes 

T

Risk Statements 

45-34

Safety Statements 

53-26-36/37/39-45

RIDADR 

UN 3263 8/PG 2

WGK Germany 

3

F 

10-21

HazardClass 

8

PackingGroup 

II

HS Code 

29299090

Storage Class

6.1C - Combustible acute toxic Cat.3
toxic compounds or compounds which causing chronic effects

Hazard Classifications

Carc. 1B
Skin Corr. 1B

MSDS

• Language:English Provider:SigmaAldrich

Bromotris(dimethylamino)phosphonium hexafluorophosphate Usage And Synthesis

Chemical Properties

White to off-white powder

Uses

Reagent for:
Conjugate addition of nitroalkanes to an acrylate equivalent
A novel polymer supported approach to nucleoside modification
Asymmetric hydrogenations
Peptide coupling
Pyrrolidine hydroxylation
Synthesis of cyclic PNA-based compound directed against HIV-1 TAR RNA

reaction suitability

reaction type: Coupling Reactions

Bromotris(dimethylamino)phosphonium hexafluorophosphate(50296-37-2)Related Product Information

• Profenofos
• Sodium hexafluorophosphate
• Lithium hexafluorophosphate
• Potassium hexafluorophosphate
• 3-Dimethylaminopropylamine
• N,N-Dimethyl-1,4-phenylenediamine
• imino(methyl)(4-nitrophenyl)-lambda6-sulfanone
• 11-Bromoundecanoic acid
• Cyclopropyl bromide
• 1-Bromotetradecane
• Bromoferrocene
• 1-Bromononane
• 1-Bromotridecane
• 1-Bromohexadecane
• Cyclobutyl bromide
• Bromocyclohexane
• Hexafluorophosphoric acid
• Bromo-tris-pyrrolidino-phosphonium hexafluorophosphate