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1-Bromotridecane

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1-Bromotridecane Basic information

Product Name:
1-Bromotridecane
Synonyms:
  • 1-Bromotridecane,99%
  • 1-bromo-tridecan
  • n-Tridecyl-1-bromide
  • tridecane,1-bromo-
  • 1-BROMOTRIDECANE
  • TRIDECYL BROMIDE
  • N-TRIDECYL BROMIDE
  • 1-Bromotridecane >
CAS:
765-09-3
MF:
C13H27Br
MW:
263.26
EINECS:
212-138-0
Product Categories:
  • Alkyl Bromides
  • Monofunctional & alpha,omega-Bifunctional Alkanes
  • Monofunctional Alkanes
  • Aliphatics
  • Intermediates
Mol File:
765-09-3.mol
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1-Bromotridecane Chemical Properties

Melting point:
4-7 °C (lit.)
Boiling point:
148-150 °C/10 mmHg (lit.)
Density 
1.03 g/mL at 25 °C (lit.)
vapor density 
9.2 (vs air)
refractive index 
n20/D 1.459(lit.)
Flash point:
>230 °F
storage temp. 
Keep in dark place,Sealed in dry,Room Temperature
solubility 
Chloroform, Methanol
form 
Oil
color 
Colourless
BRN 
1739992
Stability:
Stable. Incompatible with strong bases, strong oxidizing agents.
CAS DataBase Reference
765-09-3(CAS DataBase Reference)
NIST Chemistry Reference
Tridecane, 1-bromo-(765-09-3)
EPA Substance Registry System
Tridecane, 1-bromo- (765-09-3)
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Safety Information

Hazard Codes 
Xn
Risk Statements 
22-37/38-41
Safety Statements 
26-39
WGK Germany 
3
RTECS 
YD3100000
8
HS Code 
2903.99.8001

MSDS

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1-Bromotridecane Usage And Synthesis

Chemical Properties

light yellow liquid

Uses

1-Bromotridecane is a long chain alkyl bromide with skin sensitization potency. 1-Bromotridecane may potentially enhance plant stimulator activity.

Preparation

1-Bromotridecane is prepared from 1-tridecanol.

Application

1-Bromotridecane was used in the synthesis of:
tetradecanoic acid enriched with 13C at carbons 1, 3, or 6
(Z)-7-henicosene
Pentadecanal
(Z)-(2′R)-[N-carboethoxypyrrolidine]tetradec-1-ene
2,3,6,7,10,11,14,15-octaalkyloxytetrabenzo[a,d,g,jlcyclododecatetraenes (CTTV-n) containing n=4-15 methylenic units in the alkyloxy substituents
Coupling reaction between the dilithio-derivative of propargyl alcohol with 1-bromotridecane in liquid ammonia gave 2-hexadecyne-1-ol.

Synthesis Reference(s)

The Journal of Organic Chemistry, 44, p. 3405, 1979 DOI: 10.1021/jo01333a029

1-Bromotridecane Preparation Products And Raw materials

Preparation Products

1-BromotridecaneSupplier

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