1-Bromotetradecane Chemical Properties

Melting point:

5-6 °C(lit.)

Boiling point:

175-178 °C20 mm Hg(lit.)

Density 

0.932 g/mL at 25 °C(lit.)

refractive index 

n20/D 1.460(lit.)

Flash point:

>230 °F

storage temp. 

Store below +30°C.

solubility 

Chloroform

form 

Liquid

color 

Clear yellow

Water Solubility 

insoluble

BRN 

1742640

Dielectric constant

3.8399999999999999

Stability:

Stable. Incompatible with strong bases, strong oxidizing agents.

CAS DataBase Reference

112-71-0(CAS DataBase Reference)

NIST Chemistry Reference

Tetradecane, 1-bromo-(112-71-0)

EPA Substance Registry System

Tetradecane, 1-bromo- (112-71-0)

Safety Information

Hazard Codes 

Xi

Risk Statements 

36/37/38-22

Safety Statements 

26-36-24/25

WGK Germany 

3

TSCA 

Yes

HS Code 

29033036

MSDS

• Language:English Provider:1-Bromotetradecane
• Language:English Provider:ACROS
• Language:English Provider:SigmaAldrich
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1-Bromotetradecane Usage And Synthesis

Chemical Properties

colorless or pale yellow liquid. soluble in acetone, benzene and chloroform. intermediates for organic synthesis.

Uses

1-Bromotetradecane was used in the synthesis of tetradecylferrocene, cationic and zwitterionic gemini surfactants, and 9-tetradecylcarbazole. Also used for synthesis of metallomesogenic polymers based on bis[η1(N)-3,4-dialkyloxybenzylidene-4?-dodecyloxyaniline]dichloropalladium(II) with octyl, decyl, dodecyl, tetradecyl and hexadecyl alkyl groups.

Preparation

1-Bromotetradecane is synthesized from 1-tetradecanol by bromination. The 1-tetradecanol was added to the reaction pot, and the sulfuric acid was added dropwise with stirring, and the stirring was continued for half an hour after the addition. Then add hydrobromic acid, heat to 99-101°C, and react for 8h. Cool to 30°C, stop stirring, stand for 12 hours, and separate the upper layer of oil, and adjust the pH to 8 with 10% sodium carbonate solution. The water layer was separated, the oily substance was washed twice with an equal volume of 50% ethanol, the washed oily substance was added with sodium carbonate, stirred intermittently, and dried for 24h. Filtration to obtain 1-bromotetradecane.

1-Bromotetradecane (112-71-0)Related Product Information

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