(1S)-(+)-(Camphorylsulfonyl)oxaziridine
(1S)-(+)-(Camphorylsulfonyl)oxaziridine Basic information
- Product Name:
- (1S)-(+)-(Camphorylsulfonyl)oxaziridine
- Synonyms:
-
- (+)-(2R,8AS)-(CAMPHORYLSULFONYL)OXAZIRIDINE
- (2R,8AS)-(+)-(CAMPHORYLSULFONYL)OXAZIRIDINE
- (1S)-(+)-2,N-EPOXY-EXO-10,2-BORNANESULTAM
- (IS)-(+)-(10-Camphorsulfonyl)oxaziridine
- S-(10-Camphorsulfonyl)oxaziridine
- (4aS,7R,8aS)-9,9-DiMethyltetrahydro-4H-4a,7-Methanobenzo[c][1,2]oxazireno[2,3-b]isothiazole 3,3-dioxide
- (+)-(2R,8aS)-10-(CaMphorylsulfonyl)oxaziridine
- (4aS,7R,8aS)-Tetrahydro-9,9-diMethyl-4H-4a,7-Methanooxazirino[3,2-i][2,1]benzisothiazole 3,3-Dioxide
- CAS:
- 104322-63-6
- MF:
- C10H15NO3S
- MW:
- 229.3
- Product Categories:
-
- Intermediates & Fine Chemicals
- Pharmaceuticals
- pharmacetical
- chiral
- Chiral Reagents
- Asymmetric Synthesis
- Bicyclic Monoterpenes
- Biochemistry
- Oxidation
- Sulfur Compounds (for Synthesis)
- Synthetic Organic Chemistry
- Terpenes
- Mol File:
- 104322-63-6.mol
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(1S)-(+)-(Camphorylsulfonyl)oxaziridine Chemical Properties
- Melting point:
- 172-174 °C(lit.)
- alpha
- 45 º (c=2, chloroform)
- Boiling point:
- 317.6±25.0 °C(Predicted)
- Density
- 1.2486 (rough estimate)
- refractive index
- 1.5060 (estimate)
- storage temp.
- 2-8°C
- solubility
- Chloroform (Sparingly), Methanol (Slightly)
- pka
- -11.75±0.40(Predicted)
- form
- Crystals or Crystalline Powder
- color
- White
- optical activity
- [α]28/D +45°, c = 2 in chloroform
- BRN
- 6274370
- CAS DataBase Reference
- 104322-63-6(CAS DataBase Reference)
MSDS
- Language:English Provider:SigmaAldrich
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(1S)-(+)-(Camphorylsulfonyl)oxaziridine Usage And Synthesis
Chemical Properties
(1S)-(+)-(Camphorylsulfonyl)oxaziridine is white crystall powder
Uses
(1S)-(+)-(Camphorylsulfonyl)oxaziridine is a useful synthetic intermediate. Used for asymmetric hydroxylation
Uses
(1S)-(+)-(10-Camphorsulfonyl)oxaziridine can be used:
- To convert prochiral ketone enolates into optically active α-hydroxy ketones via enantioselective asymmetric oxidation.
- In the synthesis of thymidine oligonucleotides connected through pyrophosphates.
- In the asymmetric synthesis of proton pump inhibitors like (R)-Rabeprazole sodium and (R)-Lansoprazole sodium from the corresponding DBU salt of prochiral sulfide.
- In the preparation of phosphonoacetate and thiophosphonoacetate oligodeoxynucleotides by oxidizing the corresponding phosphinoacetate.
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(1S)-(+)-(Camphorylsulfonyl)oxaziridine(104322-63-6)Related Product Information
- (1S)-(+)-(Camphorylsulfonyl)oxaziridine
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- 2-Ethyl-1-hexanethiol
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- 4-04-00-00045 (Beilstein Handbook Reference)
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