(1R)-(-)-(10-Camphorsulfonyl)oxaziridine
(1R)-(-)-(10-Camphorsulfonyl)oxaziridine Basic information
- Product Name:
- (1R)-(-)-(10-Camphorsulfonyl)oxaziridine
- Synonyms:
-
- (-)-(2S,8AR)-(CAMPHORSULFONYL)OXAZIRIDINE
- (2S,8AR)-(-)-(CAMPHORYLSULFONYL)OXAZIRIDINE
- (1R)-(-)-(10-CAMPHORSULFONYL)OXAZIRIDINE
- (1R)-(-)-(10-CAMPHORSULPHONYL)OXAZIRIDINE
- (1R)-(-)-2,N-EPOXY-EXO-10,2-BORNANESULTAM
- (1R)-(-)-(CAMPHORYLSULFONYL)OXAZIRIDINE
- (R)-2,N-EPOXY-EXO-10,2-BORNANESULTAM
- (-)-((CAMPHORYL) SULFONYL)OXAZIRIDINE
- CAS:
- 104372-31-8
- MF:
- C10H15NO3S
- MW:
- 229.3
- EINECS:
- 800-131-0
- Product Categories:
-
- Biochemistry
- Oxidation
- Sulfur Compounds (for Synthesis)
- Synthetic Organic Chemistry
- Terpenes
- Intermediates & Fine Chemicals
- chiral
- Chiral Reagents
- Asymmetric Synthesis
- Bicyclic Monoterpenes
- Pharmaceuticals
- Mol File:
- 104372-31-8.mol
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(1R)-(-)-(10-Camphorsulfonyl)oxaziridine Chemical Properties
- Melting point:
- 170-174 °C
- alpha
- -46.6 º (c=2, CHCl3 25 ºC)
- Boiling point:
- 317.6±25.0 °C(Predicted)
- Density
- 1.2486 (rough estimate)
- refractive index
- 1.5060 (estimate)
- Flash point:
- 170℃
- storage temp.
- 2-8°C
- solubility
- Chloroform (Slightly), Methanol (Slightly)
- pka
- -11.75±0.40(Predicted)
- form
- Powder
- color
- White
- optical activity
- [α]20/D 44°, c = 2.2 in chloroform
- BRN
- 6274369
- CAS DataBase Reference
- 104372-31-8(CAS DataBase Reference)
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Safety Information
- Hazard Codes
- Xi
- Risk Statements
- 36/37/38
- Safety Statements
- 26-36-24/25
- WGK Germany
- 3
- F
- 10
- HS Code
- 29349990
MSDS
- Language:English Provider:ACROS
- Language:English Provider:SigmaAldrich
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(1R)-(-)-(10-Camphorsulfonyl)oxaziridine Usage And Synthesis
Chemical Properties
White crystalline powder
Uses
Reactant involved in:
- Asymmetric synthesis of proton pump inhibitors
- Asymmetric synthesis of polyhydroxylated pyrrolidines
- Diastereoselective hydroxylation of chlorophylls a and b enolate anions
Used in impregnated silica nanoparticles for removal of sulfur mustard from wastewater
Used to modify blebbistatin for investigations of myosin inhibitor design
Uses
(1R)-(-)-(10-Camphorsulfonyl)oxaziridine is a useful synthetic intermediate. Used for asymmetric hydroxylation.
(1R)-(-)-(10-Camphorsulfonyl)oxaziridineSupplier
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(1R)-(-)-(10-Camphorsulfonyl)oxaziridine(104372-31-8)Related Product Information
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- 3-METHYLCYCLOHEXYLAMINE
- BORNYLAMINE
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- (1S)-(+)-(10-CAMPHORSULFONYL)OXAZIRIDINE,(1S)-(+)-(10-Camphorsulfonyl)oxaziridine (1S)-(+)-2,N-Epoxy-exo-10,2-bornanesultam
- Camphor
- DL-Camphor
- EPOXY
- 1-PENTANESULFONAMIDE
- 4-04-00-00045 (Beilstein Handbook Reference)
- 1-HEXANESULFONAMIDE
- PROPANE-1-SULFONAMIDE