Basic information Safety Supplier Related

(1R)-(-)-(10-Camphorsulfonyl)oxaziridine

Basic information Safety Supplier Related

(1R)-(-)-(10-Camphorsulfonyl)oxaziridine Basic information

Product Name:
(1R)-(-)-(10-Camphorsulfonyl)oxaziridine
Synonyms:
  • (-)-(2S,8AR)-(CAMPHORSULFONYL)OXAZIRIDINE
  • (2S,8AR)-(-)-(CAMPHORYLSULFONYL)OXAZIRIDINE
  • (1R)-(-)-(10-CAMPHORSULFONYL)OXAZIRIDINE
  • (1R)-(-)-(10-CAMPHORSULPHONYL)OXAZIRIDINE
  • (1R)-(-)-2,N-EPOXY-EXO-10,2-BORNANESULTAM
  • (1R)-(-)-(CAMPHORYLSULFONYL)OXAZIRIDINE
  • (R)-2,N-EPOXY-EXO-10,2-BORNANESULTAM
  • (-)-((CAMPHORYL) SULFONYL)OXAZIRIDINE
CAS:
104372-31-8
MF:
C10H15NO3S
MW:
229.3
EINECS:
800-131-0
Product Categories:
  • Biochemistry
  • Oxidation
  • Sulfur Compounds (for Synthesis)
  • Synthetic Organic Chemistry
  • Terpenes
  • Intermediates & Fine Chemicals
  • chiral
  • Chiral Reagents
  • Asymmetric Synthesis
  • Bicyclic Monoterpenes
  • Pharmaceuticals
Mol File:
104372-31-8.mol
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(1R)-(-)-(10-Camphorsulfonyl)oxaziridine Chemical Properties

Melting point:
170-174 °C
alpha 
-46.6 º (c=2, CHCl3 25 ºC)
Boiling point:
317.6±25.0 °C(Predicted)
Density 
1.2486 (rough estimate)
refractive index 
1.5060 (estimate)
Flash point:
170℃
storage temp. 
2-8°C
solubility 
Chloroform (Slightly), Methanol (Slightly)
pka
-11.75±0.40(Predicted)
form 
Powder
color 
White
optical activity
[α]20/D 44°, c = 2.2 in chloroform
BRN 
6274369
CAS DataBase Reference
104372-31-8(CAS DataBase Reference)
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Safety Information

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36-24/25
WGK Germany 
3
10
HS Code 
29349990

MSDS

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(1R)-(-)-(10-Camphorsulfonyl)oxaziridine Usage And Synthesis

Chemical Properties

White crystalline powder

Uses

Reactant involved in:

  • Asymmetric synthesis of proton pump inhibitors
  • Asymmetric synthesis of polyhydroxylated pyrrolidines
  • Diastereoselective hydroxylation of chlorophylls a and b enolate anions

Used in impregnated silica nanoparticles for removal of sulfur mustard from wastewater

Used to modify blebbistatin for investigations of myosin inhibitor design

Uses

(1R)-(-)-(10-Camphorsulfonyl)oxaziridine is a useful synthetic intermediate. Used for asymmetric hydroxylation.

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