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Methyltriphenylphosphonium iodide

Basic information Safety Supplier Related

Methyltriphenylphosphonium iodide Basic information

Product Name:
Methyltriphenylphosphonium iodide
Synonyms:
  • METHYLTRIPHENYLPHOSPHONIUM IODIDE
  • MPJ
  • TRIPHENYLMETHYL PHOSPHONIUM IODIDE
  • Methyl triphenylphosphonium iodide, 98+%
  • METHYLTRIPHENYPHOSPHONIUMIODIDE
  • Methyltriphenylphosphanium iodide
  • Phosphonium, methyltriphenyl-, iodide
  • Triphenylmethylphosphine iodide
CAS:
2065-66-9
MF:
C19H18IP
MW:
404.22
EINECS:
218-178-5
Product Categories:
  • C-C Bond Formation
  • Olefination
  • Phosphonium Compounds
  • Synthetic Organic Chemistry
  • Wittig & Horner-Emmons Reaction
  • Wittig Reagents
  • Wittig Reaction
Mol File:
2065-66-9.mol
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Methyltriphenylphosphonium iodide Chemical Properties

Melting point:
183-185 °C(lit.)
storage temp. 
Keep in dark place,Inert atmosphere,Room temperature
solubility 
Chloroform (Slightly), Methanol (Slightly)
form 
Powder
color 
White to light yellow
Water Solubility 
SOLUBLE
Sensitive 
Light Sensitive & Hygroscopic
InChI
InChI=1S/C19H18P.HI/c1-20(17-11-5-2-6-12-17,18-13-7-3-8-14-18)19-15-9-4-10-16-19;/h2-16H,1H3;1H/q+1;/p-1
InChIKey
JNMIXMFEVJHFNY-UHFFFAOYSA-M
SMILES
[P+](C)(C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1.[I-]
CAS DataBase Reference
2065-66-9(CAS DataBase Reference)
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Safety Information

Hazard Codes 
Xi,T
Risk Statements 
36/37/38-25
Safety Statements 
26-36-45-37/39-28A
RIDADR 
UN3464
WGK Germany 
3
HazardClass 
6.1
PackingGroup 
III
HS Code 
29319090

MSDS

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Methyltriphenylphosphonium iodide Usage And Synthesis

Chemical Properties

WHITE TO LIGHT YELLOW POWDER

Uses

suzuki reaction

Uses

Methyltriphenylphosphonium iodide is as a reactant for synthesis of triphenylamine-based dyes and polyolefinic aromatic molecules with pyrene for use in dye-sensitized solar cells. Used as ligand in coupling reaction. It is also used as a precursor to a Wittig reagent.

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