Basic information Safety Supplier Related

O-Allyl-N-(9-anthracenylmethyl)cinchonidinium bromide

Basic information Safety Supplier Related

O-Allyl-N-(9-anthracenylmethyl)cinchonidinium bromide Basic information

Product Name:
O-Allyl-N-(9-anthracenylmethyl)cinchonidinium bromide
Synonyms:
  • O-ALLYL-N-(9-ANTHRACENYLMETHYL)CINCHONIDINIUM BROMIDE
  • (-)-O-(9)-ALLYL-N-(9-ANTHRACENYLMETHYL) CINCHONIDINIUM BROMIDE
  • A16450
  • 4-((1R)-((1-(Anthracen-9-yl)but-3-en-2-yl)oxy)((2S)-5-vinylquinuclidin-2-yl)methyl)quinolin-1-ium bromide
  • O-Allyl-N-[(9-anthracenyl)methyl]cinchonidium bromide
  • O-Allyl-N-(9-anthracenylmethyl)cinchonidinium bromide 90%
  • O-Allyl-1-(anthracen-9-ylmethyl)cinchonidinium bromide
  • (1S,2S,4S,5R)-2-((R)-(allyloxy)(quinolin-4-yl)methyl)-1-(anthracen-9-ylmethyl)-5-vinylquinuclidin-1-ium bromide
CAS:
200132-54-3
MF:
C37H37BrN2O
MW:
605.61
Product Categories:
  • pharmacetical
  • Asymmetric Synthesis
  • Chiral Catalysts, Ligands, and Reagents
  • Phase Transfer Reaction
Mol File:
200132-54-3.mol
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O-Allyl-N-(9-anthracenylmethyl)cinchonidinium bromide Chemical Properties

Melting point:
170 °C (dec.)(lit.)
alpha 
-340 º (C=0.45 IN CHLOROFORM)
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
optical activity
[α]20/D 345±30°, c = 0.45 in chloroform
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Safety Information

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36
WGK Germany 
3

MSDS

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O-Allyl-N-(9-anthracenylmethyl)cinchonidinium bromide Usage And Synthesis

Uses

O-Allyl-N-(9-anthracenylmethyl)cinchonidinium bromide can catalyze the asymmetric alkylation of tert-butyl glycinate-benzophenone Schiff base with different arylmethyl bromides in a micellar medium.

General Description

O-Allyl-N-(9-anthracenylmethyl)cinchonidinium bromide is a cinchona-based chiral phase-transfer catalyst (PTC) that can be used in asymmetric synthesis. It can be prepared from N-(9-anthracenylmethyl)cinchonindinium chloride.

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