Diallylamine Chemical Properties

Melting point:

-88 °C (lit.)

Boiling point:

111-112 °C (lit.)

Density 

0.787 g/mL at 25 °C (lit.)

vapor density 

3.35 (vs air)

vapor pressure 

18 mm Hg ( 20 °C)

refractive index 

n20/D 1.440(lit.)

Flash point:

60 °F

storage temp. 

Store below +30°C.

solubility 

86g/l

form 

Liquid

pka

pK1:9.29(+1) (25°C,μ=0.02)

color 

Clear colorless to yellow

PH

11.5 (9.7g/l, H2O)

Odor

ammonia-like odor

explosive limit

0.93-14.2%(V)

Water Solubility 

8.6 g/100mL

Sensitive 

Air Sensitive

Merck 

14,2971

BRN 

773718

Dielectric constant

3.7799999999999998

LogP

-0.653 at 23℃

CAS DataBase Reference

124-02-7(CAS DataBase Reference)

NIST Chemistry Reference

2-Propen-1-amine, N-2-propenyl-(124-02-7)

EPA Substance Registry System

Diallylamine (124-02-7)

Safety Information

Hazard Codes 

F,T

Risk Statements 

11-20/22-24-34

Safety Statements 

16-26-36/37/39-45-28A

RIDADR 

UN 2359 3/PG 2

WGK Germany 

3

RTECS 

UC6650000

F 

2-10

Autoignition Temperature

273 °C

TSCA 

Yes

HS Code 

2921 19 99

HazardClass 

3

PackingGroup 

II

Hazardous Substances Data

124-02-7(Hazardous Substances Data)

Toxicity

LD50 orally in rats: 0.65 g/kg (Smyth)

MSDS

• Language:English Provider:ACROS
• Language:English Provider:SigmaAldrich
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Diallylamine Usage And Synthesis

Chemical Properties

Diallylamine is a clear colourless to yellow flammable liquid. Soluble in water, alcohol, ether, benzene, with ammonia smell. It can be detected, but it is not unpleasant at 2-9 ppm and is not intolerable at 70 ppm.

Uses

Diallylamine is used as a solvent and in organic synthesis, including crop protection, an auxiliary in paper making, ionic water purifier, polymer monomer, pharmaceutical intermediate, etc. It is also used in the production of N,N-diallyldimethylammonium chloride and N,N-diallyldichloroacetamide, which is used as a safener in the preemergence herbicide EPTC (S-ethyl dipropylthiocarbamate).

Preparation

Diallylamine is synthesized by hydrolysis of diallyl cyanamide. The hydrolysis reaction was carried out in a sulfuric acid medium, and the reflux was moderated for 6h. Yield 80-88%.

Application

Diallylamine can be used:
(1) as a copper hole filling additive in printed circuit board (PCB) stacking technology. The adsorption behaviour of Diallylamine levelers agent was probed by adding it to copper sulphate electroplating solution. And the relationship between alkalinity and electrodeposition was investigated by changing the length and functional groups of the side chains.
(2) A weak base poly(diallylamine) resin was prepared for gold extraction. The resin showed high adsorption capacity (up to 5 mmol/g dry resin) and good gold selectivity for most pH ranges and many different types of solutions, including contaminated wastewater. However, the slow dissolution of the uncrosslinked polymer chains in the resin matrix limits the gold adsorption properties at low gold concentrations (less than 5 mg/dm3).

General Description

A liquid with a disagreeable odor. Less dense than water. Flash point 70°F. May be toxic by inhalation and skin absorption. Irritates skin and eyes. Used to make other chemicals.

Air & Water Reactions

Highly flammable. Soluble in water.

Reactivity Profile

Diallylamine neutralizes acids in exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen may be generated in combination with strong reducing agents, such as hydrides.

Health Hazard

May cause toxic effects if inhaled or ingested/swallowed. Contact with substance may cause severe burns to skin and eyes. Fire will produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution.

Fire Hazard

Diallylamine is a flammable liquid and a dangerous fire hazard when exposed to heat or flame. Vapors may travel to a source of ignition and flash back, while containers may explode in the heat of a fire. The compound may present a vapor explosion hazard indoors, outdoors, or in sewers. When heated to decomposition, diallylamine emits toxic fumes of NOx (Lewis, 1992).

Toxicology

Diallylamine can cause myocardial degeneration as well as damage to the kidneys and liver. This has been observed in rats and rabbits. Allylamines cause a severe primary fibrosis of the myocardium, The oral application of allylamine in the drinking water over 81–104 days caused a dose-dependent myocardial degeneration in rats.

Safety Profile

Poison by ingestion, skin contact, and intraperitoneal routes. Moderately toxic by inhalation. Human systemic effects by inhalation route: eye lachrymation and changes in the trachea or bronchi. A skin and severe eye irritant. A dangerous fire hazard when exposed to heat or flame. When heated to decomposition it emits toxic fumes of NOx. See also AMINES and ALLYL COMPOUNDS.

Purification Methods

Keep the amine over KOH pellets overnight, decant and distil it from a few pellets of KOH at atmospheric pressure (b 108-111o), then fractionate through a Vigreux column (p 11). [Vliet J Am Chem Soc 46 1307 1924, Org Synth Coll Vol 1 201 1941.] The hydrochloride has m 164-165o (from Me2CO/EtOH). [Butler & Angels J Am Chem Soc 79 3128 1957.]

Diallylamine(124-02-7)Related Product Information

• Allyl bromide
• N,N-Diisopropylethylamine
• N-Ethylmethylamine
• Dibenzylamine
• Triallylamine
• Bis(2-ethylhexyl)amine
• Sodium allylsulfonate
• Triethylamine
• Triethanolamine
• Allyl chloride
• Diallyldisulfide
• N,N-Dimethylallylamine
• Diisopropylamine
• Diallyl trisulfide
• PROPYLENE
• Allicin
• Methyldiallylamine
• Allylamine