Basic information Safety Supplier Related

(4S)-(+)-4-(2-HYDROXYETHYL)-2,2-DIMETHYL-1,3-DIOXOLANE

Basic information Safety Supplier Related

(4S)-(+)-4-(2-HYDROXYETHYL)-2,2-DIMETHYL-1,3-DIOXOLANE Basic information

Product Name:
(4S)-(+)-4-(2-HYDROXYETHYL)-2,2-DIMETHYL-1,3-DIOXOLANE
Synonyms:
  • (S)-1,2-ISOPROPYLIDENEBUTANE-1,2,4-TRIOL
  • (4S)-(+)-4-(2-HYDROXYETHYL)-2,2-DIMETHYL-1,3-DIOXOLANE
  • 2(2,2-DIMETHYL-[1,3] DIOXOLAN-4-YL)-ETHANOL (S)
  • (4S)-2,2-Dimethyl-1,3-Dioxolane-4-Ethanol
  • (4S)-(+)-4-(2-HYDROXYETHYL)-2,2-DIMETHY&
  • (s)-(+)-2,2-dimethyl-1,3-dioxolane-4-ethanol
  • 1,3-dioxolane-4-ethanol,2,2-dimethyl-,(4s)
  • (S)-2-(2,2-Dimethyl-[1,3]dioxolan-4-yl)ethanol
CAS:
32233-43-5
MF:
C7H14O3
MW:
146.18
Product Categories:
  • Alkohols
  • Chiral Building Blocks
  • Dioxanes & Dioxolanes
  • Dioxolanes
  • Glycidyl Compounds, etc. (Chiral)
  • Synthetic Organic Chemistry
Mol File:
32233-43-5.mol
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(4S)-(+)-4-(2-HYDROXYETHYL)-2,2-DIMETHYL-1,3-DIOXOLANE Chemical Properties

Boiling point:
98 °C15 mm Hg(lit.)
Density 
1.027 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.4380(lit.)
Flash point:
213 °F
storage temp. 
2-8°C
pka
14.80±0.10(Predicted)
form 
liquid
color 
Colorless to Almost colorless
optical activity
[α]20/D +2°, c = 1% in chloroform
InChI
InChI=1S/C7H14O3/c1-7(2)9-5-6(10-7)3-4-8/h6,8H,3-5H2,1-2H3/t6-/m0/s1
InChIKey
LMHCQSYOFZFRMI-AGZQWMCOSA-N
SMILES
O1C[C@H](CCO)OC1(C)C
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Safety Information

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36
WGK Germany 
3
HS Code 
2932.99.9090

MSDS

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(4S)-(+)-4-(2-HYDROXYETHYL)-2,2-DIMETHYL-1,3-DIOXOLANE Usage And Synthesis

Uses

(4S)-(+)-4-(2-Hydroxyethyl)-2,2-dimethyl-1,3-dioxolane may be used in the preparation (prop-2-ynyloxy)ethyl-tethered dioxolanes via O-propargylation. It may also be used as an intermediate in the total synthesis of rugulactone.

(4S)-(+)-4-(2-HYDROXYETHYL)-2,2-DIMETHYL-1,3-DIOXOLANESupplier

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