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BARIUM TRIFLUOROMETHANESULFONATE

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BARIUM TRIFLUOROMETHANESULFONATE Basic information

Product Name:
BARIUM TRIFLUOROMETHANESULFONATE
Synonyms:
  • trifluoro-methanesulfonicacibariumsalt
  • barium trifluoromethanesulphonate
  • TRIFLUOROMETHANESULFONIC ACID BARIUM
  • BARIUM TRIFLUOROMETHANESULFONATE, 99% (BARIUM TRIFLATE)
  • Trifluoromethanesulfonic acid barium salt
  • Barium triflate, Trifluoromethanesulfonic acid barium salt
  • Bis(trifluoromethanesulfonic acid)barium salt
  • Barium trifluoromethanesulfonate,98%
CAS:
2794-60-7
MF:
C2BaF6O6S2
MW:
435.47
EINECS:
220-526-6
Product Categories:
  • OTf&NTf series
  • Other Metal
  • triflate
  • metal triflate compounds
Mol File:
2794-60-7.mol
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BARIUM TRIFLUOROMETHANESULFONATE Chemical Properties

Melting point:
>300 °C(lit.)
storage temp. 
Inert atmosphere,Room Temperature
form 
Powder
color 
white
Water Solubility 
Soluble in water.
Sensitive 
Hygroscopic
Hydrolytic Sensitivity
5: forms reversible hydrate
BRN 
3729346
Exposure limits
ACGIH: TWA 0.5 mg/m3
NIOSH: IDLH 50 mg/m3; TWA 0.5 mg/m3
Stability:
hygroscopic
InChI
InChI=1S/2CHF3O3S.Ba/c2*2-1(3,4)8(5,6)7;/h2*(H,5,6,7);/q;;+2/p-2
InChIKey
DXJURUJRANOYMX-UHFFFAOYSA-L
SMILES
C(F)(F)(F)S(=O)(=O)[O-].C(F)(F)(F)S([O-])(=O)=O.[Ba+2]
EPA Substance Registry System
Methanesulfonic acid, trifluoro-, barium salt (2794-60-7)
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Safety Information

Hazard Codes 
Xn
Risk Statements 
20/22
Safety Statements 
28
RIDADR 
UN 1564 6.1/PG 3
WGK Germany 
1
TSCA 
No
HazardClass 
6.1
PackingGroup 
III
HS Code 
29049020

MSDS

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BARIUM TRIFLUOROMETHANESULFONATE Usage And Synthesis

Chemical Properties

White powder

Uses

Ba(CF3SO3) can be utilized as a precursor to synthesize:

  • Alkali metal and silver trifluoromethanesulfonates.
  • Sodium trifluoromethanesulfonate (sodium triflate) by reacting with sodium sulfate. Sodium triflate finds application in organic synthesis as an efficient catalyst as well as a reactant in catalytic asymmetric Mannich-type reactions, and Diels-Alder reactions.

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