2-Bromopyridine-5-boronic acid Chemical Properties

Melting point:

161-166 °C

Boiling point:

358.2±52.0 °C(Predicted)

Density 

1.78±0.1 g/cm3(Predicted)

storage temp. 

2-8°C

solubility 

soluble in Methanol

pka

6.62±0.10(Predicted)

form 

solid

color 

white to off-white

BRN 

9119918

CAS DataBase Reference

223463-14-7(CAS DataBase Reference)

Safety Information

Hazard Codes 

Xi

Risk Statements 

36/37/38-20/21/22

Safety Statements 

26-36-36/37/39

RIDADR 

2811

WGK Germany 

3

TSCA 

No

HazardClass 

IRRITANT

HS Code 

29333990

MSDS

• Language:English Provider:SigmaAldrich
• Language:English Provider:ALFA

2-Bromopyridine-5-boronic acid Usage And Synthesis

Chemical Properties

Off-white solid

Uses

Reactant involved in:

• Iterative cross-coupling reactions for synthesis of non-cytotoxic terpyridines
• The Garlanding approach for synthesis of phenyl-pyridyl scaffolds
• Cyanation for synthesis of aromatic nitriles
• Suzuki-Miyaura cross-coupling with dihalopyridines and dihalobipyridines
• Petasis boronic Mannich reaction

General Description

May contain varying amounts of anhydride

2-Bromopyridine-5-boronic acid(223463-14-7)Related Product Information

• Zinc borate
• 2-Chloro-3-hydroxypyridine
• 2-Bromopyridine
• 1-Hexadecylpyridinium bromide
• 2,2'-Bipyridine
• 2,6-Lutidine
• 3-Hydroxypyridine
• 3-Aminopyridine
• EPA
• 2-Bromo-5-nitropyridine
• Chromium picolinate
• Ascoric Acid
• 6-BROMO-4-METHYLPYRIDIN-3-YLBORONIC ACID
• 6-BROMO-2,4-DIMETHYLPYRIDIN-3-YLBORONIC ACID
• 2-BROMO-3-METHYLPYRIDINE-5-BORONIC ACID
• 6-BROMOPYRIDINE-3-BORONIC ACID, PINACOL ESTER,2-BROMOPYRIDINE-5-BORONIC ACID PINACOL ESTER,2-BROMOPYRIDINE-5-BORONIC ACID PINACOLATE
• 6-BROMO-2-METHYLPYRIDIN-3-YLBORONIC ACID
• 3,5-Dibromopyridine-4-boronic acid