Basic information Reaction Safety Supplier Related

1,3-BIS(2,4,6-TRIMETHYLPHENYL)-4,5-DIHYDROIMIDAZOLIUM TETRAFLUOROBORATE

Basic information Reaction Safety Supplier Related

1,3-BIS(2,4,6-TRIMETHYLPHENYL)-4,5-DIHYDROIMIDAZOLIUM TETRAFLUOROBORATE Basic information

Product Name:
1,3-BIS(2,4,6-TRIMETHYLPHENYL)-4,5-DIHYDROIMIDAZOLIUM TETRAFLUOROBORATE
Synonyms:
  • 1,3-BIS-(2,4,6-TRIMETHYL-PHENYL)-4,5-DIHYDRO-3H-IMIDAZOL-1-IUM TETRAFLUORO BORATE
  • 1,3-bis(2,4,6-trimethylphenyl)imidazolidin-1-ium tetrafluoroborate
  • 1,3-Bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazoliumtetrafluoroborate,min.95%
  • 1,3-BIS(2,4,6-TRIMETHYLPHENYL)-4,5-DIHYDROIMIDAZOLIUM TETRAFLUOROBORATE, MIN. 95%
  • 4,5-Dihydro-1,3-dimesitylimidazolium tetrafluoroborate, SIMes-HBF4, 4,5-Dihydro-1,3-dimesityl-1H-imidazolium tetrafluoroborate, 4,5-Dihydro-1,3-bis(2,4,6-trimethylphenyl)-1H-imidazolium tetrafluoroborate(1-)
  • 4,5-Dihydro-1,3-bis(2,4,6-trimethylphenyl)-1H-imidazolium
  • 4,5-Dihydro-1,3-dimesityl-1H-imidazolium tetrafluoroborate
  • 4,5-Dihydro-1,3-dimesitylimidazolium tetrafluoroborate
CAS:
245679-18-9
MF:
C21H27BF4N2
MW:
394.26
Product Categories:
  • Achiral Nitrogen
  • NHC
  • organic amine
Mol File:
245679-18-9.mol
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1,3-BIS(2,4,6-TRIMETHYLPHENYL)-4,5-DIHYDROIMIDAZOLIUM TETRAFLUOROBORATE Chemical Properties

Melting point:
290-296 °C
storage temp. 
Inert atmosphere,Room Temperature
form 
Powder
color 
off-white
CAS DataBase Reference
245679-18-9(CAS DataBase Reference)
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Safety Information

Hazard Codes 
C
Risk Statements 
36/37/38-34-20
Safety Statements 
24/25-45-36/37/39-26
RIDADR 
UN 1759 8/PG 2
WGK Germany 
3
TSCA 
No
HS Code 
29332990

MSDS

  • Language:English Provider:ACROS
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1,3-BIS(2,4,6-TRIMETHYLPHENYL)-4,5-DIHYDROIMIDAZOLIUM TETRAFLUOROBORATE Usage And Synthesis

Reaction

  1. Ligand for ruthenium-catalyzed selective reduction of nitriles to primary amines.
  2. Ligand for nickelcatalyzed [2+2+2] cycloaddition of arynes and an unactivated alkene.
  3. Ligand for copper-catalyzed [3+2] cycloaddition of azides and alkynes under mild conditions.
  4. Ligand for copper-catalyzed direct aryl quaternization of N-substituted imidazoles to form imidazolium salts.
  5. Ligand for copper-catalyzed silylation of allenes.

Chemical Properties

White powder

1,3-BIS(2,4,6-TRIMETHYLPHENYL)-4,5-DIHYDROIMIDAZOLIUM TETRAFLUOROBORATESupplier

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