3,4,6-Tri-O-benzyl-beta-D-mannopyranose-1,2-(methyl orthoacetate) Chemical Properties

Melting point:

74-76°C

Boiling point:

601.1±55.0 °C(Predicted)

Density 

1.22±0.1 g/cm3(Predicted)

storage temp. 

Refrigerator

solubility 

Chloroform (Slightly), Ethyl Acetate (Slightly), Methanol (Slightly)

form 

Solid

color 

White to Off-White

3,4,6-Tri-O-benzyl-beta-D-mannopyranose-1,2-(methyl orthoacetate) Usage And Synthesis

Description

3,4,6-Tri-O-benzyl-β-D-mannopyranose 1,2-(methyl orthoacetate) is a synthetic intermediate used in glycosylation reactions. Typically, the methyl orthoester protecting group is first removed by mild acid hydrolysis, producing a glycosyl donor. Removal of the O-benzyl protecting groups is performed late in the synthesis.

Chemical Properties

White Solid

Uses

3,4,6-Tri-O-benzyl-β-D-mannopyranose 1,2-(Methyl Orthoacetate) (cas# 16697-49-7) is a compound useful in organic synthesis.

References

[1] JOSé R. MARINO-ALBERNAS. Synthesis and Growth Inhibitory Properties of Glycosides of 1-O-Hexadecyl-2-O-methyl-sn-glycerol, Analogs of the Antitumor Ether Lipid ET-18-OCH3 (Edelfosine)[J]. Journal of Medicinal Chemistry, 1996, 39 17: 3241-3247. DOI: 10.1021/jm960164j
[2] NILANJANA CHAKRABORTY  Marc d’Alarcao. An anionic inositol phosphate glycan pseudotetrasaccharide exhibits high insulin-mimetic activity in rat adipocytes[J]. Bioorganic & Medicinal Chemistry, 2005, 13 24: Pages 6732-6741. DOI: 10.1016/j.bmc.2005.07.020

3,4,6-Tri-O-benzyl-beta-D-mannopyranose-1,2-(methyl orthoacetate)(16697-49-7)Related Product Information

• Benzyldimethylcarbinyl butyrate
• 2-Methylphenylacetic acid
• D-Mannitol
• Thiophanate-methyl
• Bensulfuron methyl
• Benzyl chloride
• Benzyl alcohol
• Benzyl benzoate
• Benzyl nicotinate
• Methyl salicylate
• Pivalic acid
• Tetrahydropyran
• Methyl
• Methyl bromide
• Benzyl
• 2-METHOXY-1,3-DIOXOLANE
• 3,4,6-TRI-O-BENZYL-2-DEOXY-D-GLUCOPYRANOSE
• 3-O-Benzyl-alpha-D-mannopyranose