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Vinylmagnesium chloride

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Vinylmagnesium chloride Basic information

Product Name:
Vinylmagnesium chloride
Synonyms:
  • VINYLMAGNESIUM CHLORIDE
  • chlorovinylmagnesium
  • Vinylmagnesium
  • VINYLMAGNESIUM CHLORIDE, 1.6M SOLUTION IN TETRAHYDROFURAN
  • VINYLMAGNESIUM CHLORIDE SOLUTION, ~1.7 M IN TETRAHYDROFURAN
  • Vinylmagnesium chloride, 15 wt% solution in tetrahydrofuran
  • VINYLMAGNESIUMCHLORIDE,15%(W/W)SOLUTIONINTETRAHYDROFURAN
  • Chlorvinylmagnesium
CAS:
3536-96-7
MF:
C2H3ClMg
MW:
86.8
EINECS:
222-575-9
Product Categories:
  • Grignard Reagent
  • Alkenyl
  • Grignard Reagents
  • Organometallic Reagents
Mol File:
3536-96-7.mol
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Vinylmagnesium chloride Chemical Properties

Boiling point:
66 °C
Density 
0.980 g/mL at 20 °C
Flash point:
−1 °F
storage temp. 
0-6°C
form 
Crystalline Powder
color 
White to beige
Water Solubility 
vigorous reaction
BRN 
3535268
InChIKey
NAFZXKWEUWVSAW-UHFFFAOYSA-M
CAS DataBase Reference
3536-96-7(CAS DataBase Reference)
EPA Substance Registry System
Magnesium, chloroethenyl- (3536-96-7)
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Safety Information

Hazard Codes 
F,C
Risk Statements 
11-14/15-19-22-34-40-37
Safety Statements 
16-26-36/37/39-43-45-7/8-43B-30
RIDADR 
UN 3399 4.3/PG 1
WGK Germany 
1
1-3-10
HS Code 
29319090

MSDS

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Vinylmagnesium chloride Usage And Synthesis

Chemical Properties

dark brown solution

Uses

Grignard reagent.

Uses

Vinylmagnesium chloride (Grignard reagent) can be prepared from vinyl chloride and then used to make a variety of useful end products or intermediates by adding a vinyl anion to organic functional groups. For instance, the vinylmagnesium compounds can be coupled with cuprous chloride, CuCl, at ?60 °C (?76 °F) to give 1,3-butadiene, while vinyl ketones and alcohols can be prepared by the addition of vinylmagnesium chloride to organic acids.

Uses

Used with iron pentadienoate complexes in a synthesis of divinyl cyclopropanes.

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