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Ethylmagnesium chloride

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Ethylmagnesium chloride Basic information

Product Name:
Ethylmagnesium chloride
Synonyms:
  • ETHYLMAGNESIUM CHLORIDE
  • Ethylmagnesium Chloride (18% in Tetrahydrofuran, ca. 2mol/l)
  • chloroethylmagnesium
  • ETHYLMAGNESIUM CHLORIDE, 2.0M SOLUTION I N DIETHYL ETHER
  • ETHYLMAGNESIUM CHLORIDE, 2.0M SOLUTION &
  • ETHYLMAGNESIUM CHLORIDE SOLUTION, ~2.8 M IN TETRAHYDROFURAN
  • ETHYLMAGNESIUM CHLORIDE, 2.0M SOLUTION I N TETRAHYDROFURAN
  • ETHYLMAGNESIUM CHLORIDE, 2M SOLUTION IN TETRAHYDROFURAN
CAS:
2386-64-3
MF:
C2H5ClMg
MW:
88.82
EINECS:
219-206-9
Product Categories:
  • grignard reagent
  • AlkylChemical Synthesis
  • Grignard Reagents
  • Organic Bases
  • Organometallic Reagents
  • Synthetic Reagents
  • GRIGNARD REAGENTS
  • Classes of Metal Compounds
  • Grignard Reagents & Alkyl Metals
  • Mg (Magnesium) Compounds
  • Synthetic Organic Chemistry
  • Typical Metal Compounds
Mol File:
2386-64-3.mol
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Ethylmagnesium chloride Chemical Properties

Boiling point:
66℃
Density 
1.00 g/mL at 20 °C
Flash point:
1 °F
storage temp. 
water-free area
form 
Solution
color 
Yellow to dark brown
Water Solubility 
reacts
Sensitive 
Air & Moisture Sensitive
BRN 
3647886
InChIKey
ZWNJJACKPNTXHY-UHFFFAOYSA-M
CAS DataBase Reference
2386-64-3(CAS DataBase Reference)
EPA Substance Registry System
Magnesium, chloroethyl- (2386-64-3)
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Safety Information

Hazard Codes 
F+,C,F
Risk Statements 
12-14-20/21/22-34-40-14/15-11-22-19-67-37
Safety Statements 
26-30-36/37/39-43-45-7/8-33-16-6A-43A-24/25
RIDADR 
UN 3399 4.3/PG 1
WGK Germany 
1
1-3-10
TSCA 
Yes
HazardClass 
4.3
PackingGroup 
II
HS Code 
29319090

MSDS

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Ethylmagnesium chloride Usage And Synthesis

Chemical Properties

DARK BROWN SOLUTION

Uses

Grignard-type reactions.

Uses

Ethylmagnesium chloride solution can be used:

  • In Cp2ZrCl2 catalyzed ethylcarboxylation of alkenes using carbon dioxide to corresponding carboxylic acids.
  • In the preparation of cyclobutylmagnesium carbenoids by reacting with 1-chlorocyclobutyl p-tolyl sulfoxides.

Definition

CHEBI:Ethylmagnesium chloride is an alkylmagnesium halide. It has a role as a Grignard reagent.

Hazard

Flammable, dangerous fire risk.

Ethylmagnesium chloride Preparation Products And Raw materials

Preparation Products

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