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2'-Bromoacetophenone

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2'-Bromoacetophenone Basic information

Product Name:
2'-Bromoacetophenone
Synonyms:
  • Acetophenone, o-bromo-
  • ETHANONE, 1-(2-BROMOPHENYL)-
  • AKOS BBS-00004325
  • 1-(2-BROMOPHENYL)ETHANONE
  • 1-(2-BROMOMPHENYL)ETHANONE
  • 1-ACETYL-2-BROMOBENZENE
  • O-BROMOACETOPHENONE
  • O-BROMOPHENYL METHYL KETONE
CAS:
2142-69-0
MF:
C8H7BrO
MW:
199.04
EINECS:
218-398-1
Product Categories:
  • Building Blocks
  • C7 to C8
  • Acetophenone series
  • Chemical Synthesis
  • Ketones
  • Organic Building Blocks
  • Carbonyl Compounds
  • Aromatic Acetophenones & Derivatives (substituted)
  • Benzene series
  • Adehydes, Acetals & Ketones
  • Bromine Compounds
Mol File:
2142-69-0.mol
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2'-Bromoacetophenone Chemical Properties

Melting point:
°C
Boiling point:
116-117 °C (12 mmHg)
Density 
1.476 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.568(lit.)
Flash point:
>230 °F
storage temp. 
Sealed in dry,Room Temperature
form 
Liquid
Specific Gravity
1.476
color 
Clear pale yellow to orange
Water Solubility 
PRACTICALLY INSOLUBLE
BRN 
1931534
InChIKey
PIMNFNXBTGPCIL-UHFFFAOYSA-N
CAS DataBase Reference
2142-69-0(CAS DataBase Reference)
NIST Chemistry Reference
Ethanone, 1-(2-bromophenyl)-(2142-69-0)
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Safety Information

Hazard Codes 
Xi,C
Risk Statements 
36/37/38-34
Safety Statements 
26-36-37/39-45-36/37/39
WGK Germany 
3
Hazard Note 
Irritant
HS Code 
29147090

MSDS

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2'-Bromoacetophenone Usage And Synthesis

Chemical Properties

Clear pale yellow to orange liquid

Uses

2-bromoacetophenone is employed in the selective derivatization of cytosine moieties for the determination of global DNA methylation by reversed phase high performance liquid chromatography with spectrofluorimetric detection.

Uses

2′-Bromoacetophenone (2-Bromoacetophenone) was used in the synthesis of novel series of non-condensed 5,5-bicycles.

General Description

2′-Bromoacetophenone (2-Bromoacetophenone) undergoes enantioselective addition reaction with phenylacetylene catalyzed by chiral camphorsulfonamide. It reacts with aliphatic primary amines in the presence of palladium catalyst to afford 3-methyleneisoindolin-1-ones.

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