alpha-Toluenesulfonyl chloride
alpha-Toluenesulfonyl chloride Basic information
- Product Name:
- alpha-Toluenesulfonyl chloride
- Synonyms:
-
- α-Toluenesulfonyl chloride ,98%
- Benzylsulfonyl chlorideDISC 06/12/2000
- Phenylmethanesulphonyl chloride
- alpha-Toluenesulfonyl chloride, 98% 5GR
- NSC 41894
- Toluen-alphaSulfonyl chloride
- ALPHA TOLUENE SULHONYL CHLORIDE
- Benzenemethanesulfonylchloride
- CAS:
- 1939-99-7
- MF:
- C7H7ClO2S
- MW:
- 190.65
- EINECS:
- 217-717-1
- Product Categories:
-
- Building Blocks
- Chemical Synthesis
- Pharmaceutical Intermediates
- Organic Building Blocks
- Sulfonyl Halides
- Sulfur Compounds
- Benzene derivatives
- Benzenesulfonyl chloride
- Mol File:
- 1939-99-7.mol
alpha-Toluenesulfonyl chloride Chemical Properties
- Melting point:
- 92-94 °C(lit.)
- Boiling point:
- 120 °C / 10mmHg
- Density
- 1.3264 (estimate)
- refractive index
- 1.624-1.626
- storage temp.
- Inert atmosphere,2-8°C
- solubility
- soluble in Toluene
- form
- Crystalline Powder
- color
- Almost white
- Water Solubility
- decomposes
- Sensitive
- Moisture Sensitive
- BRN
- 972806
- InChIKey
- OAHKWDDSKCRNFE-UHFFFAOYSA-N
- CAS DataBase Reference
- 1939-99-7(CAS DataBase Reference)
- NIST Chemistry Reference
- Benzenemethanesulfonyl chloride(1939-99-7)
- EPA Substance Registry System
- Benzenemethanesulfonyl chloride (1939-99-7)
Safety Information
- Hazard Codes
- C
- Risk Statements
- 34
- Safety Statements
- 26-36/37/39-45
- RIDADR
- UN 3261 8/PG 2
- WGK Germany
- 3
- F
- 10-21
- Hazard Note
- Corrosive
- TSCA
- T
- HazardClass
- 8
- PackingGroup
- II
- HS Code
- 29049020
MSDS
- Language:English Provider:Benzylsulfonyl chloride
- Language:English Provider:ACROS
- Language:English Provider:SigmaAldrich
- Language:English Provider:ALFA
alpha-Toluenesulfonyl chloride Usage And Synthesis
Chemical Properties
almost white crystalline powder
Uses
a-Toluenesulfonyl Chloride inhibits intracellular protein breakdown in the L1210 ascites leukemia in mouse. It also functions as a reagent for the protection of amino groups as benzylsulfonamides which can be cleaved off through reduction.
Synthesis Reference(s)
The Journal of Organic Chemistry, 16, p. 621, 1951 DOI: 10.1021/jo01144a013
Synthesis, p. 1203, 1992 DOI: 10.1055/s-1992-26333
General Description
Phenylmethanesulfonyl chloride is an aliphatic sulfonyl chloride. It reacts with triethylamine in methylene chloride or ether to yield trans-stilbene and cis diphenylethylene sulfone. Its reaction with 1,1-bis(diethylamino)ethane has been studied. Addition of phenylmethanesulfonyl chloride to 1,3-diphenyl-2-pyrrolidinopropene in the presence of water was studied.
alpha-Toluenesulfonyl chloride Preparation Products And Raw materials
Raw materials
Preparation Products
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alpha-Toluenesulfonyl chloride(1939-99-7)Related Product Information
- Calcium chloride
- N-Acetylsulfanilyl chloride
- Potassium chloride
- Ammonium chloride
- Sodium chloride
- Thionyl chloride
- Zinc chloride
- O-TOLUENESULFONYL CHLORIDE
- Oxalyl chloride
- Sulfuryl chloride
- Tosyl chloride
- Ethanesulfonyl chloride
- 4-Nitrobenzenesulfonyl chloride
- Choline chloride
- Benzenesulfonyl chloride
- Methylene Chloride
- Methanesulfonyl chloride
- 4-TRIFLUOROMETHYLBENZYLSULFONYL CHLORIDE