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1,4-Bis(diphenylphosphino)butane-palladium(II) chloride

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1,4-Bis(diphenylphosphino)butane-palladium(II) chloride Basic information

Product Name:
1,4-Bis(diphenylphosphino)butane-palladium(II) chloride
Synonyms:
  • Palladium(ii) chloride 1,4-b
  • 1,4-Bis(diphenylphosphino)butane-palladium(II) chloride,98+%
  • Dichloro-1,4-bis(diphenylphosphino)butane-palladium(II), Palladium(II) chloride 1,4-bis(diphenylphosphino)butane complex
  • Dichloro[bis(1,4-diphenylphosphino)butane]palladium(II), Pd 17.6%
  • 1,4-Butylenebis(diphenylphosphine)-palladium dichloride
  • Dichloro[1,4-bis(diphenylphosphino)butane]palladium (II) ,98%
  • 4-Bis(diphenylphosphino)butane-palladiuM(II) chloride
  • PDCI2(DPPB)
CAS:
29964-62-3
MF:
C28H28P2.Cl2Pd
MW:
603.8
EINECS:
678-067-6
Product Categories:
  • Pd (Palladium) Compounds
  • Synthetic Organic Chemistry
  • Catalysts for Organic Synthesis
  • Classes of Metal Compounds
  • Homogeneous Catalysts
  • Transition Metal Compounds
  • Metal Compounds
  • Metal Complexes
  • Pd
Mol File:
29964-62-3.mol
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1,4-Bis(diphenylphosphino)butane-palladium(II) chloride Chemical Properties

Melting point:
285-305 °C
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
solubility 
Soluble in ethanol, benzene, and ethereal solvents.
form 
Powder
color 
light-yellow
InChIKey
JQXJBXVWVPVTOO-UHFFFAOYSA-L
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Safety Information

Hazard Codes 
Xn
Risk Statements 
36/37/38
Safety Statements 
24/25-36-27
WGK Germany 
3
1-10
HS Code 
28439000

MSDS

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1,4-Bis(diphenylphosphino)butane-palladium(II) chloride Usage And Synthesis

Reaction

  1. Catalyst for the Grignard coupling for regioand stereoselective monoalkylation and arylation of 1,1-dichloro-1-alkenes
  2. Synthetic pyrethriods: catalyst for the Negishi coupling of (2,2-dihaloethenyl)cyclopropanecarboxylates

Chemical Properties

yellow solid

Uses

Dichloro[bis(1,4-diphenylphosphino)butane]palladium(II) is used for the catalysis of styrene carbonylation, coupling of alkyl Grignard reagents with organic halides, selective monoalkylation of organic polyhalides, and modification of the dihalovinyl moiety of synthetic pyrethroids.

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