DICHLOROBIS(METHYLDIPHENYLPHOSPHINE)PALLADIUM(II)
DICHLOROBIS(METHYLDIPHENYLPHOSPHINE)PALLADIUM(II) Basic information
- Product Name:
- DICHLOROBIS(METHYLDIPHENYLPHOSPHINE)PALLADIUM(II)
- Synonyms:
-
- Nsc148042
- Dichlorobis[methylene-bis(diphenylphosphine)]dipalladium(II)
- Bis(methyldiphenylphosphine)palladium(II) Dichloride (cis- and trans- mixture)
- Bis(methyldiphenylphosphin
- BIS(METHYLDIPHENYLPHOSPHINE)PALLADIUM(II) DICHLORIDE
- DICHLOROBIS(METHYLDIPHENYLPHOSPHINE)PALLADIUM(II)
- Bis(methyldiphenylphosphine)palladium(II) Dichloride >
- Palladium,dichlorobis(methyldiphenylphosphine)-
- CAS:
- 52611-08-2
- MF:
- C26H26Cl2P2Pd
- MW:
- 577.76
- Product Categories:
-
- Catalysis and Inorganic Chemistry
- Homogeneous Pd Catalysts
- Catalysts for Organic Synthesis
- Synthetic Organic Chemistry
- Transition Metal Compounds
- Palladium
- Classes of Metal Compounds
- Homogeneous Catalysts
- Metal Complexes
- Pd (Palladium) Compounds
- Mol File:
- 52611-08-2.mol
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DICHLOROBIS(METHYLDIPHENYLPHOSPHINE)PALLADIUM(II) Chemical Properties
- Melting point:
- >120*C (dec.)
- storage temp.
- under inert gas (nitrogen or Argon) at 2-8°C
- solubility
- Chloroform (Slightly, Heated), DMSO (Slightly, Heated), Methanol (Slightly, Heat
- form
- Solid
- color
- Light Yellow to Yellow
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MSDS
- Language:English Provider:SigmaAldrich
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DICHLOROBIS(METHYLDIPHENYLPHOSPHINE)PALLADIUM(II) Usage And Synthesis
Uses
Catalyst for:
- Ullmann reactions (homocoupling reactions)
- Cross coupling reaction of tributyltin hydride with aryl iodides
- Double silylation, double carbonylation and cyclocarbonylation reactions
Application
Dichlorobis(methyldiphenylphosphine)palladium(II) is a catalyst for the dicarbonylation of aryl halides with amines.
Preparation
Dichlorobis(methyldiphenylphosphine)palladium(II) is prepared by treating commercially available K2PdCl2 (in DMF) with methyldiphenylphosphine (in CH2Cl2), or from K2PdCl2 (in H2O) and methyldiphenylphosphine (in CH2Cl2) using Bu4NCl (in CH2Cl2) as a phase-transfer catalyst.
reaction suitability
core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Cross Couplings
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
DICHLOROBIS(METHYLDIPHENYLPHOSPHINE)PALLADIUM(II)Supplier
J & K SCIENTIFIC LTD.
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- 010-82848833 400-666-7788
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Meryer (Shanghai) Chemical Technology Co., Ltd.
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- 021-61259108 18621169109
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TCI (Shanghai) Development Co., Ltd.
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- 021-67121386
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Energy Chemical
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- 021-021-58432009 400-005-6266
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Shanghai Hanhong Scientific Co.,Ltd.
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- 021-54306202 13764082696
- info@hanhongsci.com
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DICHLOROBIS(METHYLDIPHENYLPHOSPHINE)PALLADIUM(II)(52611-08-2)Related Product Information
- Diamminedinitritoplatinum(II)
- Platinum dioxide
- Bis(triphenylphosphine)palladium(II) chloride
- dichlorobis(di-tert-butylphenylphosphine)palladium(II)
- BIS(DI-TERT-BUTYLPHOSPHINO)METHANE
- Bis[Tris(2-methylphenyl)phosphine]palladium
- BIS(NORBORNADIENE)RHODIUM (I) TETRAFLUOROBORATE
- Bis(cyclopentadienyl)zirconium dichloride
- Bis(dibenzylideneacetone)palladium
- Bis(triphenylphosphinepalladium) acetate
- BIS(TRIPHENYLPHOSPHINE)COBALT (II) CHLORIDE
- DICHLOROBIS(CHLORODI-TERT-BUTYLPHOSPHINE) PALLADIUM (II)
- BIS(TRIPHENYLPHOSPHINE)NICKEL(II) BROMIDE
- Bis(tricyclohexylphosphine)palladium(II) Dichloride
- TRANS-DICHLOROBIS(TRIETHYLPHOSPHINE)PALLADIUM(II)
- Bis(tri-tert-butylphosphine)palladium(0)
- Bis(acetonitrile)dichloropalladium(II)
- Bis(tricyclohexylphosphine)nickel(II) chloride, 99%