ChemicalBook > Product Catalog > Chemical Reagents > Organic reagents > Phosphine ligand > (R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis[bis(3,5-di-tert-butyl-4-methoxypheny
(R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis[bis(3,5-di-tert-butyl-4-methoxypheny
(R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis[bis(3,5-di-tert-butyl-4-methoxypheny Basic information
- Product Name:
- (R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis[bis(3,5-di-tert-butyl-4-methoxypheny
- Synonyms:
-
- (R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis[bis(3,5-di-tert-butyl-4-methoxypheny
- (R)-(-)-2,2'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97%
- (R)-(-)-2,2''-BIS[DI(3,5-DI-T-BUTYL-4-METHOXYPHENYL)PHOSPHINO]-6,6''-DIMETHOXY-1,1''-BIPHENYL, MIN. 97%
- (S)-(6,6μ-Dimethoxybiphenyl-2,2μ-diyl)bis[bis(3,5-di-tert-butyl-4-methoxyphenyl)phosphine]
- (S)-3,5-t-Bu-4-MeO-MeOBIPHEP, SL-A109-2, (S)-[6,6μ-Dimethoxy(1,1μ-biphenyl)-2,2μ-diyl]bis{bis[3,5-bis(1,1-dimethylethyl)-4-methoxyphenyl]phosphine}
- (R)-(6,6μ-Dimethoxybiphenyl-2,2μ-diyl)bis[bis(3,5-di-tert-butyl-4-methoxyphenyl)phosphine]
- (R)-3,5-t-Bu-4-MeO-MeOBIPHEP, SL-A109-1, (R)-[6,6μ-Dimethoxy(1,1μ-biphenyl)-2,2μ-diyl]bis{bis[3,5-bis(1,1-dimethylethyl)-4-methoxyphenyl]phosphine}
- (R)-(-)-2,2'-Bis[di-(3,5-di-tert-butyl-4-methoxy-phenyl)phosphino]-(diphenylphosphino)-6,6'-dimethoxy-1,1'-biphenyl
- CAS:
- 352655-61-9
- MF:
- C74H104O6P2
- MW:
- 1151.56
- Product Categories:
-
- Chiral Phosphine
- MeOBIPHEP Series
- Mol File:
- 352655-61-9.mol
More
Less
(R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis[bis(3,5-di-tert-butyl-4-methoxypheny Chemical Properties
- Boiling point:
- 951.5±65.0 °C(Predicted)
- form
- crystal
- color
- white
More
Less
(R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis[bis(3,5-di-tert-butyl-4-methoxypheny Usage And Synthesis
Reaction
- Rh-catalyzed reductive coupling of acetylene to aldehydes and ketones.
- Pt-catalyzed intramolecular hydroarylation of unactivated alkenes with indoles.
- Enantioselective C-C bond activation of allenyl cyclobutanes.
- Enantioselective ring-opening of rac-ethynyl epoxides.
- Enantioselective Au-catalyzed allylic alkylation of indoles with alcohols.
- Enantioselective Rh-catalyzed conjugate alkynylation with TMS-acetylene.
- Enantioselective Rh-catalyzed [3+2] annulation of aromatic ketimines.
- Asymmetric Rh-catalyzed Pausan-Khand reaction.
Chemical Properties
Off-white powder
Uses
Atropisomeric MeOBIPHEP ligands
- Asymmetrical conjugate addition of arylboronic acids to maleimides and enones catalyzed by rhodium complexes
- Intramolecular ketone hydroacylation
- Desymmetrization through enantioselective C-C bond activation and ring expansion of allenyl cyclobutanols
- Hydroamination of bicyclic alkenes and dienes with anilines
- 1,4-addition/asymmetric protonation of amino acrylates
General Description
sold in collaboration with Solvias AG
(R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis[bis(3,5-di-tert-butyl-4-methoxyphenySupplier
J & K SCIENTIFIC LTD.
- Tel
- 010-82848833 400-666-7788
- jkinfo@jkchemical.com
Energy Chemical
- Tel
- 021-021-58432009 400-005-6266
- sales8178@energy-chemical.com
Bide Pharmatech Ltd.
- Tel
- 400-164-7117 13681763483
- product02@bidepharm.com
Sigma-Aldrich
- Tel
- 021-61415566 800-8193336
- orderCN@merckgroup.com
Zhengzhou Kingorgchem Chemical Technology Co., Ltd.gy Co., Ltd.
- Tel
- 0371-65511006 18625597674
- sales@kingorgchem.com
More
Less
(R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis[bis(3,5-di-tert-butyl-4-methoxypheny(352655-61-9)Related Product Information
- (S)-H8-BINAP
- (R)-DM-BINAP
- (R)-DIFLUORPHOS(TM)
- (S)-SunPhos
- (S)-(+)-2,2'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97%
- (R)-(+)-TolBINAP
- R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-&
- (S)-(-)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl
- (S)-(-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl
- (R)-SEGPHOS
- (R)-(+)-2,2'-Bis(di-i-propylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97%
- (S)-(-)-5,5'-Bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole,min.98%(S)-SEGPHOS
- (R)-H8-BINAP
- (R)-DIFLUORPHOS(TM)
- (S)-(-)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL
- (S)-(+)-5,5'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole,min.98%(S)-DTBM-SEGPHOS
- (R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis[bis(3,5-di-tert-butyl-4-methoxypheny
- Chloro[(R)-(-)5,5μ-bis[bis(3,5-di-tert-butyl-4-methoxyphenyl)phosphino]-4,4μ-bi-1,3-benzodioxole](p-cymene)ruthenium(II) chloride