Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II)
Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II) Basic information
- Product Name:
- Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II)
- Synonyms:
-
- Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II)
- (S)-Ru(OAc)2(SEGPHOS(R))
- Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II) Ru(OAc)2[(S)-segphos]
- (S)-Ru(OAc)2(SEGPHOS)
- RU(OAC)2[(S)-SEGPHOS]
- Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II) Ru(OAc)2[(S)-segphos(R)]
- Diacetoxyruthenium, [4-(5-diphenylphosphanyl-1,3-benzodioxol-4-yl )-1,3-benzodioxol-5-yl]-diphenyl-phosphane
- Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-be...
- CAS:
- 373650-12-5
- MF:
- C38H28O4P2.C4H6O4Ru
- MW:
- 829.741
- Product Categories:
-
- Ru
- Mol File:
- 373650-12-5.mol
More
Less
Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II) Chemical Properties
- Melting point:
- >100°C
- storage temp.
- 2-8°C
- form
- solid
- color
- yellow to black
- Sensitive
- air sensitive
More
Less
Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II) Usage And Synthesis
Reaction
- Highly active highly enantioselective catalyst for hydrogenation of functionalized ketones. The acetate salts are frequently used for hydrogenation of allyl alcohols, unsaturated carboxylic acids and reductive amination.
- Asymmetric hydrogenation of substituted allyl alcohols.
Uses
(S)-Ru(OAc)2(SEGPHOS?) can be used as a catalyst:
- To prepare highly chemo, enantio, and diastereoselective primary β-amino lactams by asymmetric reductive amination of racemic β-keto lactams.
- To synthesize chiral primary diarylmethylamines and sterically bulky benzylamines from diaryl and sterically hindered ketones via asymmetric reductive amination reaction.
- For the conversion of levulinic acid to optically active γ-valerolactone via asymmetric hydrogenation reaction.
Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II)Supplier
Jiangsu Qianyu Molecular Technology Co., Ltd Gold
- Tel
- 18552882512
- 2314725130@qq.com
J & K SCIENTIFIC LTD.
- Tel
- 010-82848833 400-666-7788
- jkinfo@jkchemical.com
BeiJing Hwrk Chemicals Limted
- Tel
- 0757-86329057 18501085097
- sales3.gd@hwrkchemical.com
Energy Chemical
- Tel
- 021-021-58432009 400-005-6266
- sales8178@energy-chemical.com
Shanghai Topbiochem Technology Co., Ltd
- Tel
- 021-58170097
- info@topbiochem.com
More
Less
Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II)(373650-12-5)Related Product Information
- Diacetato[(R)-(+)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole] ruthenium(II) Ru(OAc)2[(R)-segphos]
- Diacetato[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II)
- [1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II)
- Dichloro(cycloocta-1,5-diene)ruthenium(II)
- Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II)
- DICHLORO[1,3-BIS(DIPHENYLPHOSPHINO)PROPANE]PALLADIUM(II)
- Dichloro(2-pyridinecarboxylato)gold
- (S)-(-)-5,5'-Bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole,min.98%(S)-SEGPHOS
- Diacetato{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II)
- Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II)