Basic information Reaction Safety Supplier Related

Diacetato[(R)-(+)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole] ruthenium(II) Ru(OAc)2[(R)-segphos] 

Basic information Reaction Safety Supplier Related

Diacetato[(R)-(+)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole] ruthenium(II) Ru(OAc)2[(R)-segphos]  Basic information

Product Name:
Diacetato[(R)-(+)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole] ruthenium(II) Ru(OAc)2[(R)-segphos] 
Synonyms:
  • (R)-Ru(OAc)2(SEGPHOS)
  • R-RU(OAC)2(SEGPHOS)
  • Diacetato[(R)-(+)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole] ruthenium(II) Ru(OAc)2[(R)-segphos] 
  • RU(OAC)2[(R)-SEGPHOS]
  • Diacetato[(R)-(+)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II) Ru(OAc)2[(R)-segphos(R)]
  • (acetyloxy)ruthenio acetate
  • Diacetato[(R)-(+)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II)
  • Diacetato[(R)-(+)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole] ruthenium(II) Ru(OAc)2[(R)-segphos
CAS:
944450-48-0
MF:
C42H36O8P2Ru
MW:
831.76
Product Categories:
  • Ru
Mol File:
944450-48-0.mol
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Diacetato[(R)-(+)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole] ruthenium(II) Ru(OAc)2[(R)-segphos]  Chemical Properties

Melting point:
>100°C
storage temp. 
2-8°C
form 
Powder
color 
dark yellow
Sensitive 
air sensitive
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Safety Information

WGK Germany 
3
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Diacetato[(R)-(+)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole] ruthenium(II) Ru(OAc)2[(R)-segphos]  Usage And Synthesis

Reaction

  1. Highly active highly enantioselective catalyst for hydrogenation of functionalized ketones. The acetate salts are frequently used for hydrogenation of allyl alcohols, unsaturated carboxylic acids and reductive amination.
  2. Asymmetric hydrogenation of substituted allyl alcohols.

Uses

Takasago Ligands and Complexes for Asymmetric Reactions

Diacetato[(R)-(+)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole] ruthenium(II) Ru(OAc)2[(R)-segphos] Supplier

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