Josiphos SL-J009-1 Pd G3
Josiphos SL-J009-1 Pd G3 Basic information
- Product Name:
- Josiphos SL-J009-1 Pd G3
- Synonyms:
-
- Chloro{(R)-(-)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyldi-t-butylphosphine}(2'-amino-1,1'-biphenyl-2-yl)palladium(II)
- JOSIPHOS Palladacycle Gen. 3
- Methanesulfonato{(R)-(-)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyldi-t-butylphosphine}(2'-amino-1,1'-biphenyl-2-yl)palladium(II)
- METHANESULFONATO{(R)-(-)-1-[(S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-T-BUTYLPHOSPHINE}(2'-AMINO-1,1'-BIPHENYL-2-YL)PALLADIUM(II),MIN.98%[JOSIPHOSPALLADACYCLEGEN.3]
- Methanesulfonato{(R)-(-)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyldi-t-butylphosphine}(2'-amino-1,1'-biphenyl-2-yl)palladium(II),[Josiphos Palladacycle Gen. 3]
- BRUNO PALLADACYCLE
- Josiphos Pd G3
- Methanesulfonato{(R)-(-)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyldi-t-butylphosphine}(2'-amino-1,1'-biphenyl-2-yl)palladium(II)Josiphos Pd G3
- CAS:
- 1702311-34-9
- MF:
- C45H66FeNO3P2PdS10*-
- MW:
- 925.287962
- Mol File:
- 1702311-34-9.mol
Josiphos SL-J009-1 Pd G3 Chemical Properties
- Melting point:
- 180-186 °C
- storage temp.
- 2-8°C, protect from light, stored under nitrogen
- form
- solid
- color
- red-orange
- InChIKey
- VXSQFQJKYCLYAK-DHOIFHORSA-N
Josiphos SL-J009-1 Pd G3 Usage And Synthesis
Reaction
Catalyst used for C-O coupling reactions between electron-deficient phenols and functionalized heteroaryl chlorides.
Uses
Josiphos SL-J009-1 Pd G3 is a good catalyst, widely used in various cross-coupling reactions, including: Buchwald-Hartwig cross-coupling reaction, Hiyama Coupling, Negishi Coupling, Heck Reaction, Sonogashira Coupling and Suzuki-Miyaura Coupling, etc.
General Description
Josiphos SL-J009-1 Pd G3 (Josiphos SL-J009-1-G3-palladacycle) is a modified G3 precatalyst (G3′). It has been synthesized by Buchwald and coworkers from second generation (G2) precatalyst by methylation of the amino group present on biphenyl backbone. It is a useful catalyst for various cross-coupling reactions. G3 precatalysts are versatile catalysts. They have long life in solution and are readily soluble in various organic solvents. G3- precatalysts have been employed in various C-N bond forming reactions.
reaction suitability
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Cross Couplings
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
Josiphos SL-J009-1 Pd G3Supplier
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