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Pentamethylcyclopentadienyltitanium trichloride

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Pentamethylcyclopentadienyltitanium trichloride Basic information

Product Name:
Pentamethylcyclopentadienyltitanium trichloride
Synonyms:
  • eta5-Pentamethylcyclopentadienyl
  • Trichloro(pentamethylcyclopentadienyl)titanium(Ⅳ)
  • pentamethylcyclopentadienyltitaniumtrochloride
  • Titanium, eta5-pentamethylcyclopentadienyl trichloride)-
  • TRICHLORO(PENTAMETHYLCYCLOPENTADIENYL)TITANIUM(IV)
  • (PENTAMETHYLCYCLOPENTADIENYL)TITANIUM(IV) TRICHLORIDE
  • PENTAMETHYLCYCLOPENTADIENYLTITANIUM TRICHLORIDE
  • PENTAMETHYLCYCLOPENTADIENE TITANIUM TRICHLORIDE
CAS:
12129-06-5
MF:
C10H15Cl3Ti
MW:
289.45
Product Categories:
  • metallocene
  • Catalysts for Organic Synthesis
  • Classes of Metal Compounds
  • Half Metallocenes
  • Homogeneous Catalysts
  • Metallocenes
  • Synthetic Organic Chemistry
  • Ti (Titanium) Compounds
  • Titanium Alkoxides, etc. (Homogeneous Catalysts)
  • Transition Metal Compounds
  • Catalysis and Inorganic Chemistry
  • Chemical Synthesis
  • Titanium
Mol File:
12129-06-5.mol
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Pentamethylcyclopentadienyltitanium trichloride Chemical Properties

Melting point:
200 °C (dec.) (lit.)
Boiling point:
190-220 °C(Press: 4-7 Torr)
form 
crystal
color 
red
Water Solubility 
reacts
Sensitive 
Moisture Sensitive
Hydrolytic Sensitivity
7: reacts slowly with moisture/water
CAS DataBase Reference
12129-06-5(CAS DataBase Reference)
NIST Chemistry Reference
«eta»5-Pentamethylcyclopentadienyl titanium trichloride(12129-06-5)
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Safety Information

Hazard Codes 
C
Risk Statements 
34
Safety Statements 
26-36/37/39-45
RIDADR 
UN 3261 8/PG 2
WGK Germany 
3
TSCA 
No
HazardClass 
8
PackingGroup 
II
HS Code 
29319090

MSDS

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Pentamethylcyclopentadienyltitanium trichloride Usage And Synthesis

Description

Trichloro(pentamethylcyclopentadienyl)titanium(IV) is a versatile catalyst for transesterification reactions and styrene polymerization.

Chemical Properties

Pentamethylcyclopentadienyl)titanium(IV) Trichloride is a red to bordeaux crystals.

Uses

Pentamethylcyclopentadienyl)titanium(IV) Trichloride is used as a catalyst in Transesterification reactions and styrene polymerization. It is also used as Piano-stool catalyst.

General Description

Pentamethylcyclopentadienyltitanium trichloride has been shown to have mononuclear structure and high molecular weight, which can be confirmed by its crystal x-ray diffraction pattern. It belongs to the class of syndiotactic compounds and has an MM value of 1.3 g/mol. It also has a high degree of crystallinity, which can be seen from its diffraction pattern on a hexamethylenetetramine plate.

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