Dibromomethane Chemical Properties

Melting point:

-52 °C

Boiling point:

96-98 °C(lit.)

Density 

2.477 g/mL at 25 °C(lit.)

vapor density 

6.05 (vs air)

vapor pressure 

34.9 mm Hg ( 20 °C)

refractive index 

n20/D 1.541(lit.)

Flash point:

96-98°C

storage temp. 

Store below +30°C.

solubility 

11.7g/l

form 

Liquid

color 

Clear colorless to slightly brown

Water Solubility 

0.1 g/100 mL (20 ºC)

Merck 

14,6061

BRN 

969143

Dielectric constant

6.7（10℃）

Stability:

Stable. Incompatible with strong oxidizing agents, aluminium, magnesium. Reacts violently with potassium.

CAS DataBase Reference

74-95-3(CAS DataBase Reference)

NIST Chemistry Reference

Methane, dibromo-(74-95-3)

EPA Substance Registry System

Dibromomethane (74-95-3)

Safety Information

Hazard Codes 

Xn,T,F

Risk Statements 

20-52/53-39/23/24/25-23/24/25-11

Safety Statements 

24-61-45-36/37-16-7

RIDADR 

UN 2664 6.1/PG 3

WGK Germany 

2

RTECS 

PA7350000

TSCA 

Yes

HS Code 

2903 39 15

HazardClass 

6.1

PackingGroup 

III

Hazardous Substances Data

74-95-3(Hazardous Substances Data)

Toxicity

LD50 orally in Rabbit: 108 mg/kg LD50 dermal Rabbit > 4000 mg/kg

MSDS

• Language:English Provider:SigmaAldrich
• Language:English Provider:ACROS
• Language:English Provider:ALFA

Dibromomethane Usage And Synthesis

Description

Dibromomethane is a member of the class of bromomethanes that is methane substituted by two bromo groups. It is produced by marine algae. It has a role as a marine metabolite and an algal metabolite. It is a member of bromomethanes and a bromohydrocarbon.

Chemical Properties

colourless liquid

Chemical Properties

Dibromomethane is a colorless liquid with a sweet, pleasant odor.

Uses

Organic synthesis, solvent.

Uses

Dibromomethane is used as solvent in organic synthesis. It acts as an intermediate in the manufacture of specialty chemicals, agrochemicals and pharmaceuticals. It is useful as extractant and utilized for the determination of 5-nitroimidazoles (5-NDZ) in environmental waters. It is involved in the convertion of catechols to their methylenedioxy derivatives.

Definition

ChEBI: A member of the class of bromomethanes that is methane substituted by two bromo groups. It is produced by marine algae.

General Description

A colorless liquid with a pleasant odor. Insoluble in water and denser than water. May be toxic by ingestion. Used as a solvent and as a motor fuel.

Air & Water Reactions

Insoluble in water.

Reactivity Profile

Halogenated aliphatic compounds, such as Dibromomethane, are moderately or very reactive. Reactivity generally decreases with increased degree of substitution of halogen for hydrogen atoms. Low molecular weight haloalkanes are highly flammable and can react with some metals to form dangerous products. Materials in this group are incompatible with strong oxidizing and reducing agents. Also, they are incompatible with many amines, nitrides, azo/diazo compounds, alkali metals (potassium), and epoxides.

Health Hazard

INHALATION: Anesthetic effects, nausea and drunkenness. CONTACT WITH SKIN AND EYES: Skin irritation of eyes and nose.

Fire Hazard

Special Hazards of Combustion Products: Dissociation products generated in a fire may be irritating or toxic.

Toxicology

A poison. Moderately toxic by subcutaneous route. Mdly toxic by inhalation. Mutation data reported. mxtures with potassium explode on light impact. When heated to decomposition it emits toxic fumes of Br-. See also BROMIDES

Hazard

In laboratory studies, animals experienced CNS depression at 2400-2800 ppm and liver and kidney damage after repeated exposures to 1000 ppm. Dichloromethane rarely causes hepatotoxicity unless exposure is extremely heavy or agent ingested. If left on clothes, it may cause reddening of skin; may have effects on the nervous system and blood, causing impaired functions, carboxyhemoglobinemia, and lowering of consciousness; chronic exposure may cause liver and kidney effects; an irritant; harmful by inhalation; a simple asphyxiant; may cause blood disorders, cardiac irregularities, and CNS depression;

Synthesis

Dibromomethane is synthesized commercially from dichloromethane via bromochloromethane:
6 CH₂Cl₂  + 3 Br₂  + 2 Al  →  6 CH₂BrCl  +  2 AlCl₃
CH₂Cl₂  + HBr  →  CH₂BrCl  +  HCl
The latter route requires aluminium trichloride as a catalyst. The bromochloromethane product from either reaction can further react in a similar manner:
6 CH₂BrCl  + 3 Br₂  + 2 Al  →  6 CH₂Br₂  +  2 AlCl₃
CH₂BrCl  + HBr  →  CH₂Br₂  +  HCl
In the laboratory, it is synthesized from bromoform:
CHBr3 + Na₃AsO₃ + NaOH → CH₂Br₂ + Na₃AsO₄ + NaBr
using sodium arsenite and sodium hydroxide.
Another way is to synthesize it from diiodomethane and bromine. 

Potential Exposure

Methylene bromide is used as a solvent and as a chemical intermediate.

First aid

If this chemical gets into the eyes, remove anycontact lenses at once and irrigate immediately for at least15 min, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts theskin, remove contaminated clothing and wash immediatelywith soap and water. Seek medical attention immediately. Ifthis chemical has been inhaled, remove from exposure,begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR ifheart action has stopped. Transfer promptly to a medicalfacility. When this chemical has been swallowed, get medical attention. Give large quantities of water and inducevomiting. Do not make an unconscious person vomit

storage

Color Code—Blue: Health Hazard/Poison: Storein a secure poison location. Prior to working with thischemical you should be trained on its proper handling andstorage. Store in tightly closed container in a well-ventilatedarea away from potential high heat sources. Where possible,automatically pump liquid from drums or other storage containers to process containers.

Shipping

UN2664 Dibromomethane, Hazard Class: 6.1; Labels: 6.1-Poisonous materials.

Incompatibilities

Mixture with potassium forms a shocksensitive explosive. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, sodium amide, strong acids, strong bases, alkaline earth metals, aluminum, magnesium. The substance decomposes on contact with hot surfaces producing hydrogen bromide

Waste Disposal

Consult with environmental regulatory agencies for guidance on acceptable disposal practices. Generators of waste containing this contaminant (≥100 kg/mo) must conform to EPA regulations governing storage, transportation, treatment, and waste disposal

Dibromomethane(74-95-3)Related Product Information

• Bromodiphenylmethane
• Bromofluoromethane
• Clidinium bromide
• Sodium bromate
• 4,4'-Diphenylmethane diisocyanate
• Methylene Blue
• CHLORODIBROMOMETHANE
• Bromoform
• Ethidium bromide
• Bromochloromethane
• Methyl bromide
• DIBROMODIFLUOROMETHANE
• BROMOTRIFLUOROMETHANE
• Methylene Chloride
• BENZAL BROMIDE
• Tribromoacetic acid
• DIBROMOACETONITRILE
• DIBROMOMETHANE-D2,Dibromomethane-d2, 99.0 atom % D