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Pyrimidinetetramine sulfate

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Pyrimidinetetramine sulfate Basic information

Product Name:
Pyrimidinetetramine sulfate
Synonyms:
  • pyrimidinetetrayltetraamine sulphate
  • PYRIMIDINE-2,4,5,6-TETRAMINE SULPHATE
  • 2,4,5,6-TETRAAMINIOPYRIMIDINE SULFATE
  • 2,4,5,6-TETRAAMINO-PYRIMIDINE SULFATE SALT
  • 2,4,5,6-Tetraaminopyrimidine sulfate hydrate,98%
  • 2,4,5,6-Tetraaminopyrimidine sulfate
  • 6-TetraaMinopyriMidine sulfate
  • PyriMidine-2,4,5,6-tetraaMine sulfate
CAS:
5392-28-9
MF:
C4H10N6O4S
MW:
238.22
EINECS:
226-393-0
Product Categories:
  • Building Blocks
  • C4 to C5
  • Aromatics
  • Chemical Synthesis
  • Heterocyclic Building Blocks
  • Heterocycle-Pyrimidine series
  • FINE Chemical & INTERMEDIATES
  • Amines
  • (intermediate of methotrexate)
  • Pyrimidines
  • Building Blocks
  • Heterocyclic Building Blocks
  • Heterocycles
  • Intermediates
  • bc0001
Mol File:
5392-28-9.mol
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Pyrimidinetetramine sulfate Chemical Properties

Melting point:
>300 °C(lit.)
storage temp. 
Sealed in dry,Room Temperature
solubility 
DMSO (Slightly, Heated), Water (Very Slightly, Heated)
form 
Crystalline Powder
color 
Ochre to brown
Water Solubility 
slightly soluble
BRN 
3785189
InChIKey
MQEFDQWUCTUJCP-UHFFFAOYSA-N
CAS DataBase Reference
5392-28-9(CAS DataBase Reference)
EPA Substance Registry System
Pyrimidinetetramine, sulfate (1:1) (5392-28-9)
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Safety Information

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
22-24/25-37/39-26-36
WGK Germany 
3
RTECS 
UV9738000
TSCA 
Yes
HS Code 
29335990

MSDS

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Pyrimidinetetramine sulfate Usage And Synthesis

Chemical Properties

Light yellow crystal powder

Uses

2,4,5,6-Tetraaminopyrimidine Sulfate is an intermediate for the synthesis of the antitumor drugs methotrexate and fludarabine.

Purification Methods

Purify the salt by recrystallisation from H2O, 2N H2SO4 (20 parts, 67% recovery) or 0.1N H2SO4 (40 parts, 62% recovery), and dried in air. [UV: Konrad & Pfleiderer Chem Ber 103 722 1970, Malletta et al. J Am Chem Soc 69 1814 1947, Cavalieri et al. J Am Chem Soc 70 3875 1948, Beilstein 25 H 423, 25 III/IV 3106.]

References

[1] SAUMYA SHUKLA. Toxic potential assessment of hair dye developer 2,4,5,6-tetraaminopyrimidine sulfate exposed under ambient UVB radiation.[J]. Toxicology and Industrial Health, 2024: 1-8. DOI:10.1177/07482337231209352.
[2] https://ec.europa.eu/health/ph_risk/committees/04_sccp/docs/sccp_o_152.pdf

Pyrimidinetetramine sulfate Preparation Products And Raw materials

Raw materials

Preparation Products

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