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(-)-2,3-O-Isopropylidene-D-threitol

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(-)-2,3-O-Isopropylidene-D-threitol Basic information

Product Name:
(-)-2,3-O-Isopropylidene-D-threitol
Synonyms:
  • D(-)-2,2-DIMETHYL-1,3-DIOXOLANE-4,5-DIMETHANOL
  • 2,3-DI-O-ISOPROPYLIDENE-D-THREITOL
  • (-)-2,3-O-ISOPROPYLIDINE-D-THREITOL
  • (+)-2,3-O-ISOPROPYLIDINE-D-THREITOL
  • (-)-2,3-O-ISOPROPYLIDENE-D-THREITOL
  • 2,3-O-ISOPROPYLIDENE-D-THREITOL
  • (4S,5R)-(-)-4,5-BIS(HYDROXYMETHYL)-2,2-DIMETHYL-1,3-DIOXOLANE
  • (4R-TRANS) 1,3-DIOXOLANE-4,5-DIMETHANOL-2,2-DIMETHYL BUTANOIC ACID
CAS:
73346-74-4
MF:
C7H14O4
MW:
162.18
EINECS:
277-391-1
Product Categories:
  • Heterocycles series
  • chiral
  • Chiral Reagents
  • Biochemistry
  • Chiral Building Blocks
  • Dioxanes & Dioxolanes
  • Dioxolanes
  • Glycidyl Compounds, etc. (Chiral)
  • O-Substituted Sugars
  • Sugar Alcohols
  • Sugars
  • Synthetic Organic Chemistry
  • Chiral Compound
  • Heterocycles
Mol File:
73346-74-4.mol
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(-)-2,3-O-Isopropylidene-D-threitol Chemical Properties

Melting point:
48-51 °C(lit.)
Boiling point:
91-93 °C0.01 mm Hg(lit.)
alpha 
-3.1 º (c=5, CHCl3 26 ºC)
Density 
1.0585 (rough estimate)
refractive index 
-4 ° (C=5, Acetone)
Flash point:
>230 °F
storage temp. 
Inert atmosphere,Store in freezer, under -20°C
solubility 
Chloroform, Dichloromethane, Ethyl Acetate, THF
pka
13.90±0.10(Predicted)
form 
Oil
color 
Yellow
Water Solubility 
Soluble in water.
Sensitive 
Hygroscopic
BRN 
1798
CAS DataBase Reference
73346-74-4(CAS DataBase Reference)
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Safety Information

Hazard Codes 
Xn
Risk Statements 
20/21/22-36/37/38
Safety Statements 
22-24/25-36-26
WGK Germany 
3
3-10
HS Code 
29329970

MSDS

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(-)-2,3-O-Isopropylidene-D-threitol Usage And Synthesis

Chemical Properties

Colorless to light yellow liqui

Uses

(-)-2,3-O-Isopropylidene-D-threitol is used in the synthesis of the optically active enantiomorphic 2,3-butanediols. It react with toluene-4-sulfonyl chloride to get O2,O3-isopropylidene-O1,O4-bis-(toluene-4-sulfonyl)-D-threitol.

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