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Methyl 2-hexenoate

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Methyl 2-hexenoate Basic information

Product Name:
Methyl 2-hexenoate
Synonyms:
  • FEMA 2709
  • METHYL TRANS-2-HEXENOATE
  • METHYL T2 HEXENOATE
  • METHYL 2-HEXENOATE
  • Methyl-2-Furaote
  • Methyl hex-2-enoate
  • 2-Hexenoic acid methyl
  • Methyl trans-2-hexenoate(kosher)
CAS:
2396-77-2
MF:
C7H12O2
MW:
128.17
EINECS:
607-296-6
Mol File:
2396-77-2.mol
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Methyl 2-hexenoate Chemical Properties

Melting point:
32 °C
Boiling point:
56-58 °C(Press: 13 Torr)
Density 
0.907±0.06 g/cm3(Predicted)
FEMA 
2709 | METHYL 2-HEXENOATE
storage temp. 
2-8°C
Odor
at 100.00 %. fatty green fruity pineapple earthy
Odor Type
fatty
JECFA Number
1809
LogP
2.38
CAS DataBase Reference
2396-77-2(CAS DataBase Reference)
NIST Chemistry Reference
2-Hexenoic acid, methyl ester(2396-77-2)
EPA Substance Registry System
2-Hexenoic acid, methyl ester (2396-77-2)
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Safety Information

HS Code 
2916199590

MSDS

  • Language:English Provider:ALFA
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Methyl 2-hexenoate Usage And Synthesis

Description

Methyl 2-hexenoate has a green, musty, earthy, sweet, fruity odor with a very powerful, sharp, green-fruity flavor. May be prepared by boiling the corresponding acid with methanol in the presence of concentrated H2S04 in chloroform and subsequent elimination of water from the vapors using MgS04; also from 3-chloropropionic acid methyl ester and anhydrous sodium acetate in acetic acid.

Chemical Properties

Methyl 2-hexenoate has a green, musty, earthy, sweet, fruity odor and a very powerful, sharp, green-fruity flavor

Occurrence

Reported found in papaya, peas, soursop and mountain papaya

Definition

ChEBI: Methyl 2E-hexenoate is a fatty acid ester.

Preparation

By boiling the corresponding acid with methanol in the presence of concentrated H2SO4 in chloroform and subsequent elimination of water from the vapors using MgSO4; also from 3-chloropropionic acid methyl ester and anhydrous sodium acetate in acetic acid

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