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(ACETYLACETONATO)DICARBONYLIRIDIUM(I)

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(ACETYLACETONATO)DICARBONYLIRIDIUM(I) Basic information

Product Name:
(ACETYLACETONATO)DICARBONYLIRIDIUM(I)
Synonyms:
  • DICARBONYL-2,4-PENTANEDIONATOIRIDATE (I)
  • DICARBONYLACETYLACETONATO IRIDIUM (I)
  • IRIDIUM I DICARBONYL PENTANEDIONATE
  • (ACETYLACETONATO)DICARBONYLIRIDIUM(I)
  • dicarbonyl(2,4-pentandione)iridium
  • Iridium, dicarbonyl(2,4-pentanedionato-O,O')-
  • DicarbonylacetylacetonatoiridiumIcopperbrownxtl
  • dicarbonyl-2,4-pentanedionatoiridium(i)
CAS:
14023-80-4
MF:
C7H7IrO4
MW:
347.35
Product Categories:
  • Catalysis and Inorganic Chemistry
  • Chemical Synthesis
  • Iridium
  • metal carbonyl complexes
Mol File:
14023-80-4.mol
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(ACETYLACETONATO)DICARBONYLIRIDIUM(I) Chemical Properties

Melting point:
>145℃
Boiling point:
100°C 0,05mm
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
form 
crystal
color 
copper brown
Stability:
store cold
InChI
InChI=1S/C5H8O2.2CO.Ir/c1-4(6)3-5(2)7;2*1-2;/h3,6H,1-2H3;;;/q;;;+1/p-1/b4-3-;;;
InChIKey
DFIAYCFHPDOZLK-FGSKAQBVSA-M
SMILES
C(=C/C(=O)C)(\C)/O[Ir].[O+]#[C-].[O+]#[C-]
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Safety Information

Hazard Codes 
Xn
Risk Statements 
20/21/22-36/37/38-63
Safety Statements 
22-26-36
RIDADR 
UN3466
WGK Germany 
3
TSCA 
No
HazardClass 
6.1
PackingGroup 
III

MSDS

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(ACETYLACETONATO)DICARBONYLIRIDIUM(I) Usage And Synthesis

Chemical Properties

metallic brown

Uses

Catalyst for isomerization and anti-Markovnikov arylation of olefins

Reactant for:

  • Oxidative addition of perfluoroalkyl iodides
  • Synthesis of iridium heterocycles
  • Scaffolding of iridium complexes
  • Metal carbonyl cluster synthesis
  • Mixed-bridged bimetallic d8 complex synthesis

reaction suitability

core: iridium
reagent type: catalyst

(ACETYLACETONATO)DICARBONYLIRIDIUM(I)Supplier

Guiyan Chemical Materials (Yunnan) Co., LTD Gold
Tel
18317061306
Email
wanghongyou@ipm.com.cn
Yunnan Precious Metals Laboratory Co., Ltd Gold
Tel
871-15559856 15559856215
Email
yujuan@ipm.com.cn
J & K SCIENTIFIC LTD.
Tel
18210857532; 18210857532
Email
jkinfo@jkchemical.com
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
4006356688 18621169109
Email
market03@meryer.com
Alfa Aesar
Tel
400-6106006
Email
saleschina@alfa-asia.com
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