(-)-CITRONELLAL
(-)-CITRONELLAL Basic information
- Product Name:
- (-)-CITRONELLAL
- Synonyms:
-
- (S)-(-)-Citronellal 96%
- L(-)-Citronellal
- CITRONELLAL(L-)
- (3S)-3,7-dimethyl-6-Octenal
- (-)-CITRONELLAL WITH GC
- (S)-(-)-3,7-DIMETHYL-6-OCTENAL
- (S)-3,7-DIMETHYL-6-OCTENAL
- (S)-(-)-CITRONELLAL
- CAS:
- 5949-05-3
- MF:
- C10H18O
- MW:
- 154.25
- EINECS:
- 227-707-9
- Product Categories:
-
- Asymmetric Synthesis
- Building Blocks
- C10-C12
- Carbonyl Compounds
- Chemical Synthesis
- Chiral Building Blocks
- Acyclic Monoterpenes
- Biochemistry
- Citrus aurantium (Seville orange)
- Elettaria Cardamomum (Cardamom)
- Nutrition Research
- Organic Building Blocks
- Phytochemicals by Plant (Food/Spice/Herb)
- Zingiber officinale (Ginger)
- Terpenes
- Aldehydes
- Mol File:
- 5949-05-3.mol
(-)-CITRONELLAL Chemical Properties
- Boiling point:
- 227.64°C (estimate)
- Density
- 0.851 g/mL at 20 °C (lit.)
- refractive index
- n20/D 1.447
- Flash point:
- 168 °F
- storage temp.
- Hygroscopic, Refrigerator, under inert atmosphere
- solubility
- Chloroform (Sparingly), Ethyl Acetate (Slightly), Methanol (Slightly)
- form
- Oil
- color
- Colourless
- Odor
- at 10.00 % in dipropylene glycol. clean herbal citrus
- Odor Type
- citrus
- optical activity
- [α]20/D 15°, neat
- BRN
- 1720790
- LogP
- 3.482 (est)
- CAS DataBase Reference
- 5949-05-3(CAS DataBase Reference)
- EPA Substance Registry System
- 6-Octenal, 3,7-dimethyl-, (3S)- (5949-05-3)
MSDS
- Language:English Provider:SigmaAldrich
(-)-CITRONELLAL Usage And Synthesis
Chemical Properties
CLEAR COLOURLESS TO PALE YELLOW LIQUID
Uses
(S)-(-)-Citronellal may be used in the synthesis of bioactive compounds like (+)-hexahydrocannabinol, (S)-isopulegol, machaeriols A and B.
Definition
ChEBI: The (3S)-stereoisomer of 3,7-dimethyloct-6-enal (citronellal).
General Description
(S)-(-)-Citronellal is a monoterpenoid compound mainly found in Corymbia citriodora and Cymbopogon nardus essential oils.
Purification Methods
Fractionally distil it. Alternatively extract it with NaHSO3 solution, wash it with Et2O, then acidify it to decompose the bisulfite adduct and extract with Et2O, dry (Na2SO4), evaporate and distil. Check for purity by hydroxylamine titration. The ORD in MeOH (c 0.167) is: []700 +9o, []589 +11o, []275 +12o and []260 +12o. The semicarbazone has m 85o, and the 2,4-dinitrophenylhydrazone has m 79-80o. [(+)-compound: Tietze & Beifuss Org Synth 71 167 1993, IR: Carroll et al. J Chem Soc 3457 1950, ORD: Djerassi & Krakower J Am Chem Soc 81 237 1959, Beilstein 1 IV 3515.]
(-)-CITRONELLALSupplier
- Tel
- 010-82848833 400-666-7788
- jkinfo@jkchemical.com
- Tel
- 4006608290; 18621169109
- market03@meryer.com
- Tel
- 021-67121386
- Sales-CN@TCIchemicals.com
- Tel
- 021-021-58432009 400-005-6266
- sales8178@energy-chemical.com
- Tel
- 021-58099652-8005 13585536065
- bin.wu@shlschem.com
(-)-CITRONELLAL(5949-05-3)Related Product Information
- Dehydroepiandrosterone
- Sodium prasterone sulfate
- PHORBOL 12-MYRISTATE 13-ACETATE
- Citronellal
- DEHYDROANDROSTERONE ACETATE
- PHORBOL 12,13,20-TRIACETATE, 4BETA
- 4ALPHA-PHORBOL
- PHORBOL-12-MONOMYRISTATE
- 4ALPHA-PHORBOL 12,13-DIDECANOATE
- 20-OXO-20-DEOXYPHORBOL 12,13-DIBUTYRATE
- PHORBOL 12-MYRISTATE 13-ACETATE 4-O-METHYL ETHER, 4BETA
- PHORBOL 13-ACETATE
- PHORBOL 12,13-DIACETATE
- PHORBOL-12-DECANOATE
- PHORBOL 12,13-DIBUTYRATE
- PHORBOL 12,13-DIBENZOATE
- PHORBOL 13,20-DIACETATE
- PHORBOL 12-MONOACETATE, 4BETA