ChemicalBook > Product Catalog > Organic Chemistry > Heterocyclic Compounds > 2,6-Bis[(4R)-4-phenyl-2-oxazolinyl]pyridine
2,6-Bis[(4R)-4-phenyl-2-oxazolinyl]pyridine
2,6-Bis[(4R)-4-phenyl-2-oxazolinyl]pyridine Basic information
- Product Name:
- 2,6-Bis[(4R)-4-phenyl-2-oxazolinyl]pyridine
- Synonyms:
-
- 2,6-Bis[(4R)-4-phenyl-2-oxazolinyl]pyridine
- 2,6-BIS[(4R)-PHENYL-2-(OXAZOLIN-2-YL)]PYRIDINE
- (R,R)-2,6-Bis(4,5-dihydro-4-phenyl-2-oxazolyl)pyridine
- (R,R)-2,6-BIS(4-PHENYL-2-OXAZOLIN-2-YL)PYRIDINE
- (r,r)-2,6-bis(4-phenyl-2-oxazolinyl)pyridine
- (R,R)-2,2'-(2,6-PYRIDINEDIYL)BIS(4-PHENYL-2-OXAZOLINE)
- [R-(R,R)]-2,6-BIS(4,5-DIHYDRO-4-PHENYL-2-OXAZOLYL)PYRIDINE
- (R-(R*,R*))-2,6-bis(4,5-dihydro-4-phenyl-2-oxazol
- CAS:
- 128249-70-7
- MF:
- C23H19N3O2
- MW:
- 369.42
- Product Categories:
-
- BOX series
- Chiral Nitrogen
- Asymmetric Synthesis
- Synthetic Organic Chemistry
- organic amine
- Heterocycle-Pyridine series
- Mol File:
- 128249-70-7.mol
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2,6-Bis[(4R)-4-phenyl-2-oxazolinyl]pyridine Chemical Properties
- Melting point:
- 171-175 °C(lit.)
- alpha
- 185 º (c=1, methylene chloride)
- Boiling point:
- 600.4±55.0 °C(Predicted)
- Density
- 1.28±0.1 g/cm3(Predicted)
- storage temp.
- Inert atmosphere,Room Temperature
- pka
- 3.07±0.70(Predicted)
- form
- crystal
- color
- white
- optical activity
- [α]22/D 187°, c = 1 in methylene chloride
- Water Solubility
- Insoluble
- CAS DataBase Reference
- 128249-70-7(CAS DataBase Reference)
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Safety Information
- Hazard Codes
- Xi
- Risk Statements
- 36/37/38
- Safety Statements
- 26-36/37/39
- WGK Germany
- 3
- HS Code
- 29339900
MSDS
- Language:English Provider:SigmaAldrich
- Language:English Provider:ACROS
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2,6-Bis[(4R)-4-phenyl-2-oxazolinyl]pyridine Usage And Synthesis
Reactions
- Ligand for Copper catalyzed syn-selective Mukaiyama aldol reaction.
- Ligand for Tin catalyzed anti-selective aldol reaction.
- Ligand for Ytterbuim catalyzed desymmetrization of meso epoxides.
- Ligand for Copper catalyzed enantioselective addition of terminal alkynes to imines.
- Ligand for Scandium catalyzed enantioselective syn-selective ene reactions.
- Ligand for Copper catalysed asymmetric alkynylation of cyclic azomethine Imines.
- Ligand for Europium catalyzed asymmetric alpha amination.
Chemical Properties
White needles
Uses
2,6-Bis[(4R)-4-phenyl-2-oxazolinyl]pyridine [Pybox] may be used as a chiral ligand in the copper-catalyzed enatioselective arylation of N-arylated tetrahydroisoquinolines (THIQs) with arylboronic acids in the presence of a photoredox catalyst.
2,6-Bis[(4R)-4-phenyl-2-oxazolinyl]pyridineSupplier
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2,6-Bis[(4R)-4-phenyl-2-oxazolinyl]pyridine(128249-70-7)Related Product Information
- Phenyl salicylate
- Fenoxaprop-P
- Diphenyl ether
- PHENYL VALERATE
- Pyridine
- Isoxazole
- Sulfamethoxazole
- 4-Phenylpyridine
- PHENYL RESIN
- 2,6-bis[(4s)-4-phenyl-2-oxazolinyl]pyridine
- Phenylacetic acid
- 2,6-BIS((3AR,8AS)-8H-INDENO(1,2-D)OXAZO&
- METHYL PICOLINIMIDATE
- PYRIDINE-2-CARBOXIMIDIC ACID ETHYL ESTER
- 2,6-Bis[(4R)-4-phenyl-2-oxazolinyl]pyridine