Isobornyl methacrylate
Isobornyl methacrylate Basic information
- Product Name:
- Isobornyl methacrylate
- Synonyms:
-
- 2-methyl-,1,7,7-trimethylbicyclo(2.2.1)hept-2-ylester,exo-2-propenoicaci
- IBOMA
- Isobornyl methacrylate ,98%
- Isobornyl Methacrylate 
- Isobornyl Methacrylate, stabilized, 85-90% 50GR
- (1R,2R,4R)-1,7,7-TriMethylbicyclo[2.2.1]heptan-2-yl Methacrylate
- Isobornyl Methacrylat
- Isobornyl Methacrylate technical grade
- CAS:
- 7534-94-3
- MF:
- C14H22O2
- MW:
- 222.33
- EINECS:
- 231-403-1
- Product Categories:
-
- Bicyclic Monoterpenes
- Biochemistry
- Terpenes
- 7534-94-3
- Mol File:
- 7534-94-3.mol
Isobornyl methacrylate Chemical Properties
- Melting point:
- -60 °C
- Boiling point:
- 127-129 °C15 mm Hg(lit.)
- Density
- 0.983 g/mL at 25 °C(lit.)
- vapor pressure
- 7.5Pa at 20℃
- refractive index
- n20/D 1.477(lit.)
- Flash point:
- 225 °F
- storage temp.
- Keep in dark place,Sealed in dry,Room Temperature
- form
- Liquid
- color
- Clear colorless to yellow
- Specific Gravity
- 0.985
- Water Solubility
- negligible
- InChIKey
- HHHKSPVBHWRWNA-QOZQQMKHSA-N
- LogP
- 5.09
- CAS DataBase Reference
- 7534-94-3(CAS DataBase Reference)
- EPA Substance Registry System
- Isobornyl methacrylate (7534-94-3)
Safety Information
- Hazard Codes
- Xi
- Risk Statements
- 36/37/38
- Safety Statements
- 26-36
- WGK Germany
- 2
- HS Code
- 29161400
- Hazardous Substances Data
- 7534-94-3(Hazardous Substances Data)
MSDS
- Language:English Provider:(1,7,7-Trimethyltricyclo[2.2.1]hepten-2-yl)-2-methyl-2-propenoate
- Language:English Provider:SigmaAldrich
- Language:English Provider:ACROS
- Language:English Provider:ALFA
Isobornyl methacrylate Usage And Synthesis
Chemical Properties
CLEAR COLORLESS TO YELLOW LIQUID
Characteristics
Isobornyl methacrylate is a colorless transparent liquid. It is a monomer that unifies hardness and flexibility. Due to its molecular structure, its polymer has excellent high gloss, sharp image, scratch resistance, medium resistance and weather resistance, and Its hygroscopicity is significantly lower than that of MMA (methyl methacrylate). In addition, IBOMA-added acrylic resin has good compatibility with polyester, alkyd and many volatile paint film-forming substances.
Uses
Isobornyl methacrylate is a versatile hydrophobic monomer with a good combination of hardness and flexibility that can improve the chemical and water resistance of polymer systems.
Preparation
Isobornyl methacrylate was synthesized by direct esterification of camphene and methacrylic acid.
General Description
Isobornyl methacrylate is a reactive solvent with low vapor pressure. It facilitates the free radical polymerization by forming a polymer with high glass transition temperature (Tg).
Flammability and Explosibility
Not classified
Synthesis
Isobornyl methacrylate is obtained by reacting (1S,2S,4S)-(+)-isoborneol and 4-methoxyphenol.Dissolve5g (1S,2S,4S)-(+)-isoborneol in 15 mL toluene. Add 4 mg (0.032 mmol) 4-methoxyphenol to the solution. After the addition of 0.4 g (3.24 mmol)4-dimethylamino pyridine, add a solution of 10 g (64.8 mmol) methacrylic anhydride (MAA) in 10 mL toluene dropwise to the mixture. Heat the reaction mixture to 80 °C. Stir the reaction mixture for 16 hours. After cooling down to room temperature, wash the mixture with 50 mL 1M sodium bicarbonate solution four times. Wash the organic phase with 50 mL brine two times. Separate the organic phase. Remove the toluene by rotary evaporation followed by a fractional distillation under reduced pressure.
1H NMR (CDCl3, 300 MHz): δ(ppm) = 6.06 (dq, 1H, 1); 5.51 (dq, 1H, 2); 4.71 (m ,1H, 4); 1.93 (dd, 3H, 3); 1.87-1.5 (m, 5H, 6,7,8); 1.23-1.04 (m, 2H, 5); 1.012 (s, 3H, 9);0.86 (s, 3H, 10); 0.85 (s, 3H, 11). IR (film): ν(cm-1) = 2954 (CH2), 2879 (CH2), 1715 (C=O) 1454 (CH2), 1157 and 1053 (C=O).
Fig The synthetic method of Isobornyl methacrylate
Isobornyl methacrylateSupplier
- Tel
- 25-86736275 15896456536
- marketing@royal-chem.com
- Tel
- 0532-0532-86867058 18562606086
- sales@qdrenas.com
- Tel
- 25-86655873 13962173137
- marketing@royal-chem.com
- Tel
- 512-83500002 13862111431
- sales2@senfeida.com
- Tel
- 020-82567763 13609796592
- summitchem@163.com
Isobornyl methacrylate(7534-94-3)Related Product Information
- PHENYL METHACRYLATE
- Butyl methacrylate
- Dimethyl succinate
- tetradecyl methacrylate
- Dodecyl 2-methylacrylate
- Methyl propiolate
- Isobornyl acrylate
- Octadecyl methacrylate
- 2-Methyl-2-propenoic acid cyclohexyl ester
- Methyl acrylate
- Tris(trimethylsilyl)phosphate
- 2-Isocyanatoethyl methacrylate
- Ethylene dimethacrylate
- Methacrylic acid
- Poly(methyl methacrylate)
- Diethyl phthalate
- METHYLTHYMOL BLUE
- 2-Hydroxypropyl methacrylate