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Glucose pentaacetate

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Glucose pentaacetate Basic information

Product Name:
Glucose pentaacetate
Synonyms:
  • Pentaacetate Pentaacetyl-alpha-D-glucose
  • ALPHA-D-GLUCOPYRANOSE-PENTAACETATE
  • ALPHA-GLUCOSE PENTAACETATE
  • A-D-GLUCOSE PENTAACETATE
  • D-A-GLUCOSE PENTAACETATE
  • 1,2,3,4,6-PENTA-O-ACETYL-A-D-GLUCOPYRANOSE
  • 1,2,3,4,6-PENTA-O-ACETYL-A-GLUCOPYRANOSE
  • 1,2,3,4,6-PENTA-O-ACETYL-ALPHA-D-GLUCOPYRANOSE
CAS:
604-68-2
MF:
C16H22O11
MW:
390.34
EINECS:
210-073-2
Product Categories:
  • chiral
  • Biochemistry
  • Glucose
  • O-Substituted Sugars
  • Sugars
  • Dextrins、Sugar & Carbohydrates
  • Carbohydrates & Derivatives
Mol File:
604-68-2.mol
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Glucose pentaacetate Chemical Properties

Melting point:
111-113 °C
alpha 
97 º (c=1, CHCl3)
Boiling point:
435.58°C (rough estimate)
Density 
1.3984 (rough estimate)
vapor pressure 
0-0Pa at 20-50℃
FEMA 
2524 | GLUCOSE PENTAACETATE
refractive index 
105.5 ° (C=1.5, MeOH)
storage temp. 
Sealed in dry,Room Temperature
solubility 
chloroform: 0.1 g/mL, clear, colorless
form 
Powder
color 
White to off-white
Odor
at 100.00 %. odorless
Odor Type
odorless
optical activity
[α]20/D ≥+98°, c = 1 in ethanol
Water Solubility 
< 5 G/L (25 ºC)
BRN 
98852
LogP
1.87 at 25℃ and pH5.7
CAS DataBase Reference
604-68-2(CAS DataBase Reference)
NIST Chemistry Reference
«alpha»-D-Glucopyranose, pentaacetate(604-68-2)
EPA Substance Registry System
.alpha.-D-Glucopyranose, pentaacetate (604-68-2)
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Safety Information

Hazard Codes 
Xn,Xi
Risk Statements 
21-36/38-46-62-63
Safety Statements 
24/25-53-36/37-26-25
WGK Germany 
3
TSCA 
Yes
HS Code 
29400000

MSDS

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Glucose pentaacetate Usage And Synthesis

Chemical Properties

white to light yellow crystal powde

Uses

D-Glucose pentaacetate was reported to stimulate insulin release in rat pancreatic islets. Only α-D-glucose pentaacetate caused an immediate increase in insulin output. The β-anomer of D-glucose pentaacetate first transiently inhibited insulin release, this initial effect being followed by a secondary rise in secretory rate.

Purification Methods

Crystallise it from MeOH, EtOH or three recrystallisations from 95% EtOH. [Wolfrom & Thompson Methods in Carbohydrate Chemistry II 212 1963, Academic Press, Beilstein 17/7 V 318.]

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