4,5-Bis(diphenylphosphino)-9,9-dimethylxanthene
Application- Product Name
- 4,5-Bis(diphenylphosphino)-9,9-dimethylxanthene
- CAS No.
- 161265-03-8
- Chemical Name
- 4,5-Bis(diphenylphosphino)-9,9-dimethylxanthene
- Synonyms
- XANT PHOS;(9,9-Dimethyl-9H-xanthene-4,5-diyl)bis(diphenylphosphane);9,9-DIMETHYL-4,5-BIS(DIPHENYLPHOSPHINO)XANTHENE;Dimethylbisdiphenylphosphinoxanthene;[5-(diphenylphosphanyl)-9,9-diMethyl-9H-xanthen-4-yl]diphenylphosphane;Bis(diphenylphosphino)-9,9-diMethylxanthene;4,5-Bis(diphenylphosphino)-9,9;4,5-Bis(diphenylphosphino)-9,9-dimethyl;4,5-BIS(DIPHENYLPHOSPHINO)-9,9-DIMETHYLX;9,9-Dimethyl-4,5-bis(diphenylphosphino)xanthene, XANTPHOS
- CBNumber
- CB0141028
- Molecular Formula
- C39H32OP2
- Formula Weight
- 578.62
- MOL File
- 161265-03-8.mol
4,5-Bis(diphenylphosphino)-9,9-dimethylxanthene Property
- Melting point:
- 224-228 °C(lit.)
- Boiling point:
- 665.7±55.0 °C(Predicted)
- Flash point:
- 450℃
- storage temp.
- Keep in dark place,Sealed in dry,Room Temperature
- solubility
- Soluble in organic solvents.
- form
- Crystals
- color
- White to light yellow
- InChIKey
- CXNIUSPIQKWYAI-UHFFFAOYSA-N
- CAS DataBase Reference
- 161265-03-8(CAS DataBase Reference)
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P271Use only outdoors or in a well-ventilated area.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 526460
- Product name
- 4,5-Bis(diphenylphosphino)-9,9-dimethylxanthene
- Purity
- 97%
- Packaging
- 1g
- Price
- $66.1
- Updated
- 2024/03/01
- Product number
- 526460
- Product name
- 4,5-Bis(diphenylphosphino)-9,9-dimethylxanthene
- Purity
- 97%
- Packaging
- 5g
- Price
- $189
- Updated
- 2024/03/01
- Product number
- B2709
- Product name
- 4,5-Bis(diphenylphosphino)-9,9-dimethylxanthene
- Purity
- >98.0%(HPLC)
- Packaging
- 1g
- Price
- $57
- Updated
- 2024/03/01
- Product number
- B2709
- Product name
- 4,5-Bis(diphenylphosphino)-9,9-dimethylxanthene
- Purity
- >98.0%(HPLC)
- Packaging
- 5g
- Price
- $169
- Updated
- 2024/03/01
- Product number
- H26241
- Product name
- 4,5-Bis(diphenylphosphino)-9,9-dimethylxanthene, 97%
- Packaging
- 1g
- Price
- $83.3
- Updated
- 2024/03/01
4,5-Bis(diphenylphosphino)-9,9-dimethylxanthene Chemical Properties,Usage,Production
Application
4,5-Bis(diphenylphosphino)-9,9-dimethylxanthene is an organophosphorus compound derived from the heterocycle xanthene. It is used as a bidentate ligand and is noteworthy for having a particularly wide bite angle. Such ligands are useful in the hydroformylation of alkenes.
Chemical Properties
White to light yellow crystals
Uses
suzuki reaction
Uses
4,5-Bis(diphenylphosphino)-9, 9-dimethylxanthene is used as a bidentate ligand, which finds application in hydroformylation of alkenes.
Uses
1,1'-(9,9-Dimethyl-9H-xanthene-4,5-diyl)bis[1,1-diphenyl-phosphine is an organophosphorus compound derived from the heterocycle xanthene. It is used as a bidentate ligand and is noteworthy for having a particularly wide bite angle. Such ligands are useful in the hydroformylation of alkenes.
Reactions
- Ligand used for the hydroformylation of alkenes.
- Ligand used in the intermolecular coupling of amides and hydrazones with aryl halides.
- Ligand used in the intermolecular coupling of amides with aryl halides or triflates.
- Ligand used in the coupling of heteroarylamines and aryl halides.
- Ligand used in the hydrophosphinylation of alkenes and alkynes.
- Ligand used for the Au(I)-catalyzed dehydrogenative silation of alcohols.
- Ligand used for the sulfinylation of aryl iodides.
- Ligand used for the Pd-catalyzed carbonylation reaction of aryl bromides and amines.
- Ligand used for the Ni-cataltzed alkynylcyanation of alkynes.
- Ligand used for the Pd-catalyzed N-arylation of 3-amino-1H-pyrazole.
- Ligand used for the Rh-catalyzed dehydrogenation borylation of cyclic alkenes.
- Ligand used for the Pd-catalyzed intermolecular coupling of H-Phosphonate diesters with benzyl halides.
- Ligand used for the Pd-catalyzed one pot synthesis of 4-aryl-1H-1,2,3-triazoles.
- Ligand used for the Pd-catalyzed intermolecular addition of formamides to alkynes.
- Ligand used for the Pd-catalyzed decarboxylative couplings of 2-(2-azaaryl)acetates with aryl halides and triflates.
- Ligand used for the Pd-catalyzed benzylic arylation of 2-methyl azaarenes
- Ligand used for the Pd-catalyzed α-arylation of heteroaromatic ketones.
- Ligand used for the Pd-catalyzed direct alkynlation of both azoles and azolines.
- Ligand used for the Cu-catalyzed intermolecular coupling of alkynes with aryl iodides.
- Ligand used for the Pd-catalyzed ene-type reaction of aldehydes with 1,3-diene.
- Ligand used for the Ru-catalyzed intermolecular addition of 2-phenylbenzoic acid onto unactivated olefins.
- Ligand used for the Pd/Cu-catalyzed direct arylation of heteroarenes.
- Ligand used for the Pd-catalyzed reaction of propargyl-substituted malonate esters with aryl halides.
- Ligand used for the Pd-catalyzed decarboxylative coupling of tertiary cyanoacetate salts with aryl halides and triflates.
- Ligand used for the Pd-catalyzed hydroesterification of alkynes.
- Ligand used for the Cu-catalyzed arylation of arylboronic acids with aldehydes.
- Ligand used for the Ru-catalyzed oxidative synthesis of heterocycles from alcohols.
- Ligand used for the Rh-catalyzed borylation of nitriles.
- Ligand used in the Pd-catalyzed α-arylation of benzylic phosphine oxides.
- Ligand used in the Pd-Catalyzed Oxidative Coupling of Enamides and Alkynes.
- Ligand used in the Pd-catalyzed difunctionalization of enol ethers to amino acetals with aminals and alcohols.
- Ligand used in the Pd-catalyzed alkoxycarbonylation of α-chloroketones.
reaction suitability
reagent type: catalyst
reaction type: Cross Couplings
4,5-Bis(diphenylphosphino)-9,9-dimethylxanthene Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 4,5-Bis(diphenylphosphino)-9,9-dimethylxanthene manufacturers
- Product
- 4,5-Bis(diphenylphosphino)-9,9-dimethylxanthene 161265-03-8
- Price
- US $55.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 5000kg/week
- Release date
- 2024-06-03
- Product
- 4,5-Bis(diphenylphosphino)-9,9-dimethylxanthene 161265-03-8
- Price
- US $80.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 1000
- Release date
- 2024-03-26
- Product
- 4, 5-Bis(diphenylphosphino)-9,9-dimethylxanthene 161265-03-8
- Price
- US $20.00-370.00/g
- Min. Order
- 25g
- Purity
- 0.99
- Supply Ability
- 100kg
- Release date
- 2024-10-25