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Methyl 3-amino-5-bromobenzoate

Product Name
Methyl 3-amino-5-bromobenzoate
CAS No.
706791-83-5
Chemical Name
Methyl 3-amino-5-bromobenzoate
Synonyms
3-AMINO-5-BROMOBENZOATE;Methyl 3-Amino-5-bromobenzoate;METHYL-3-BROMO-5-AMINO BENZOATE;Benzoic acid, 3-amino-5-bromo-, methyl ester
CBNumber
CB01471014
Molecular Formula
C8H8BrNO2
Formula Weight
230.06
MOL File
706791-83-5.mol
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Methyl 3-amino-5-bromobenzoate Property

Melting point:
83-88℃
Boiling point:
332.3±22.0 °C(Predicted)
Density 
1.578±0.06 g/cm3(Predicted)
storage temp. 
2-8°C(protect from light)
pka
2.38±0.10(Predicted)
Appearance
Yellow to brown Solid
InChI
InChI=1S/C8H8BrNO2/c1-12-8(11)5-2-6(9)4-7(10)3-5/h2-4H,10H2,1H3
InChIKey
MNXLJDUZJCMJCI-UHFFFAOYSA-N
SMILES
C1(C=C(Br)C=C(N)C=1)C(=O)OC
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC
Product number
M328553
Product name
Methyl3-amino-5-bromobenzoate
Packaging
250mg
Price
$55
Updated
2021/12/16
Usbiological
Product number
455148
Product name
Methyl 3-amino-5-bromobenzoate
Packaging
100mg
Price
$305
Updated
2021/12/16
Matrix Scientific
Product number
065397
Product name
Methyl 3-amino-5-bromobenzoate
Packaging
500mg
Price
$40
Updated
2021/12/16
Matrix Scientific
Product number
065397
Product name
Methyl 3-amino-5-bromobenzoate
Packaging
1g
Price
$54
Updated
2021/12/16
Matrix Scientific
Product number
065397
Product name
Methyl 3-amino-5-bromobenzoate
Packaging
5g
Price
$162
Updated
2021/12/16
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Methyl 3-amino-5-bromobenzoate Chemical Properties,Usage,Production

Synthesis

3-Bromo-5-aminobenzoic acid (1.0 g, 4.62 mmol) was stirred in methanol (15mL) with ice cooling, and the yellow solution was treated with thionyl chloride (4.00 mL, 55.0 mmol) dropwise over 20 mm. The resulting mixture was allowed to warm to room temperature and left stirring overnight. The reaction mixture was quenched with aqueous saturated NaHCO3 solution at 0 C. The solvent was then removed under vacuum, and the residue was suspended in ethyl acetate (200 mL). The organic phase was washed with brine (100 mL), dried (Na2504) and concentrated to afford Methyl 3-amino-5-bromobenzoate as a yellow solid (1.08 g, 98%). NMR (400 MHz, Methanol-d) oe 7.10 (t, J 1.6 Hz, 1H), 6.83 (t, J 1.6 Hz, 1H), 6.57 (t, J= 1.6 Hz, 1H), 3.46 (s, 3H). 13C NMR (100 MHz, CDC13) oe: 52.3, 114.6, 121.6, 122.3, 122.9, 132.6, 147.7, 166.0. m/z (ESI, MH) 231.

References

[1] Tetrahedron, 2010, vol. 66, # 42, p. 8254 - 8260
[2] Patent: WO2004/50619, 2004, A1. Location in patent: Page 21
[3] Chirality, 2015, vol. 27, # 8, p. 487 - 491
[4] Journal of the American Chemical Society, 2013, vol. 135, # 46, p. 17408 - 17416
[5] Patent: WO2014/19685, 2014, A1. Location in patent: Page/Page column 13; 39; 40

Methyl 3-amino-5-bromobenzoate Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from Methyl 3-amino-5-bromobenzoate manufacturers

Hebei Chuanghai Biotechnology Co., Ltd
Product
3-AMINO-5-BROMOBENZOATE 706791-83-5
Price
US $10.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10 mt
Release date
2025-03-10
Henan Fengda Chemical Co., Ltd
Product
3-AMINO-5-BROMOBENZOATE 706791-83-5
Price
US $3.00-0.20/KG
Min. Order
1KG
Purity
98%
Supply Ability
g-kg-tons, free sample is available
Release date
2024-03-26
Henan Bao Enluo International TradeCo.，LTD
Product
3-AMINO-5-BROMOBENZOATE 706791-83-5
Price
US $50.00/kg
Min. Order
1kg
Purity
99.9%
Supply Ability
10000MT
Release date
2023-08-17

706791-83-5, Methyl 3-amino-5-bromobenzoateRelated Search:

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  • 3-AMINO-5-BROMOBENZOATE
  • Methyl 3-Amino-5-bromobenzoate
  • Benzoic acid, 3-amino-5-bromo-, methyl ester
  • METHYL-3-BROMO-5-AMINO BENZOATE
  • 706791-83-5