3-Bromo-2-methoxypyridine
- Product Name
- 3-Bromo-2-methoxypyridine
- CAS No.
- 13472-59-8
- Chemical Name
- 3-Bromo-2-methoxypyridine
- Synonyms
- 2-METHOXY-3-BROMOPYRIDINE;3-BROWN-2-METHOXYPYRIDINE;3-BROMO-2-METHOXYPYRIDINE;Pyridine, 3-bromo-2-methoxy-;3-Bromo-2-methoxypyridine >3-BROMO-2-METHOXYPYRIDINE ,98%;3-BroMo-2-Methoxypyridine, 95+%;3-Bromo-2-methoxypyridine ISO 9001：2015 REACH
- CBNumber
- CB0194569
- Molecular Formula
- C6H6BrNO
- Formula Weight
- 188.02
- MOL File
- 13472-59-8.mol
3-Bromo-2-methoxypyridine Property
- Boiling point:
- 87 °C(Press: 16 Torr)
- Density
- 1.5856 g/mL at 25 °C
- refractive index
- 1.566
- Flash point:
- 93 °C
- storage temp.
- Keep in dark place,Inert atmosphere,2-8°C
- pka
- 1.04±0.10(Predicted)
- form
- clear liquid
- color
- Colorless to Light yellow
- Water Solubility
- Not miscible or difficult to mix in water.
- Sensitive
- Moisture Sensitive/Light Sensitive
- InChIKey
- PORGLLGXCAQORO-UHFFFAOYSA-N
- CAS DataBase Reference
- 13472-59-8(CAS DataBase Reference)
Safety
- Hazard Codes
- Xn
- Risk Statements
- 22-37/38-41
- Safety Statements
- 26-36/37/39
- WGK Germany
- 3
- HS Code
- 29333990
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H302Harmful if swallowed
H315Causes skin irritation
H318Causes serious eye damage
H335May cause respiratory irritation
- Precautionary statements
-
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
N-Bromosuccinimide Price
- Product number
- 687413
- Product name
- 3-Bromo-2-methoxypyridine
- Purity
- 96%
- Packaging
- 1g
- Price
- $124
- Updated
- 2023/01/07
- Product number
- B3737
- Product name
- 3-Bromo-2-methoxypyridine
- Purity
- >98.0%(GC)(T)
- Packaging
- 1g
- Price
- $39
- Updated
- 2025/07/31
- Product number
- B3737
- Product name
- 3-Bromo-2-methoxypyridine
- Purity
- >98.0%(GC)(T)
- Packaging
- 5g
- Price
- $124
- Updated
- 2025/07/31
- Product number
- B696878
- Product name
- 3-Bromo-2-methoxypyridine
- Packaging
- 1g
- Price
- $75
- Updated
- 2021/12/16
- Product number
- 074014
- Product name
- 3-Bromo-2-methoxypyridine
- Purity
- 95+%
- Packaging
- 1g
- Price
- $36
- Updated
- 2021/12/16
3-Bromo-2-methoxypyridine Chemical Properties,Usage,Production
Uses
It is employed in the facile synthesis of 2-unsubstituted benzofuran-3-carboxylates using diazo(trimethylsilyl)methyl magnesium bromide.
Synthesis
52200-48-3
124-41-4
13472-59-8
A) 3-bromo-2-chloropyridine (4.76 g) was dissolved in N,N-dimethylformamide (DMF, 30 mL) under argon protection. Subsequently, a methanolic solution of 28% sodium methanol (5.73 g) was added to this solution. The reaction mixture was stirred at 80°C for 30 minutes. After completion of the reaction, the mixture was cooled to room temperature and the reaction was quenched by the addition of water. The reaction mixture was extracted with ethyl acetate and the organic phases were combined. The organic phase was washed sequentially with water and saturated sodium chloride solution and dried over anhydrous magnesium sulfate. The solvent was removed by concentration under reduced pressure to give the crude product 3-bromo-2-methoxypyridine (4.43 g) as a light yellow oil.
References
[1] Patent: EP2816023, 2014, A1. Location in patent: Paragraph 0393; 0394
3-Bromo-2-methoxypyridine Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 3-Bromo-2-methoxypyridine manufacturers
- Product
- 3-Bromo-2-methoxypyridine 13472-59-8
- Price
- US $3.00/kg
- Min. Order
- 1kg
- Purity
- 0.99
- Supply Ability
- 100000
- Release date
- 2024-08-19
- Product
- 3-Bromo-2-methoxypyridine 13472-59-8
- Price
- US $9.90/KG
- Min. Order
- 100KG
- Purity
- 99%
- Supply Ability
- 100 mt
- Release date
- 2024-12-02
- Product
- 3-Bromo-2-methoxypyridine 13472-59-8
- Price
- US $1.10/g
- Min. Order
- 1g
- Purity
- 99.00%
- Supply Ability
- 100 Tons Min
- Release date
- 2021-10-25