Bromocyclohexane

Product Name: Bromocyclohexane
CAS No.: 108-85-0
Chemical Name: Bromocyclohexane
Synonyms: CYCLOHEXYL BROMIDE;Cyclohexylbromid;Bromocylohexane;BROMOCYCLOHEXANE;bromo-cyclohexan;BroMocyclohexance;1-Bromocyclohexane;Cyelohexyl bromide;Cyclohexane,bromo-;Bromocyclohexane>
CBNumber: CB0234782
Molecular Formula: C6H11Br
Formula Weight: 163.06
MOL File: 108-85-0.mol

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Bromocyclohexane Property

Melting point:: -57°C
Boiling point:: 166-167 °C (lit.)
Density: 1.324 g/mL at 25 °C (lit.)
vapor density: 5.62 (vs air)
refractive index: n20/D 1.495(lit.)
Flash point:: 145 °F
storage temp.: Sealed in dry,Room Temperature
solubility: Miscible with ethanol, ether, acetone, benzene and carbon tetrachloride.
form: Liquid
Specific Gravity: approximate 1.33 (20℃)
color: Clear colorless to light yellow
Odor: Unpleasant Odor
Water Solubility: insoluble
Sensitive: Air & Light Sensitive
Merck: 14,2730
BRN: 1098373
Dielectric constant: 7.9（25℃）
Stability:: Stable. Combustible. Incompatible with strong oxidizing agents, strong bases.
InChIKey: AQNQQHJNRPDOQV-UHFFFAOYSA-N
CAS DataBase Reference: 108-85-0(CAS DataBase Reference)
NIST Chemistry Reference: Cyclohexane, bromo-(108-85-0)
EPA Substance Registry System: Cyclohexane, bromo- (108-85-0)

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Safety

Hazard Codes: Xn
Risk Statements: 36/37/38-20-18-52
Safety Statements: 23-24/25-37/39-26
WGK Germany: 3
RTECS: GU7171700
F: 8
TSCA: Yes
HS Code: 29035990

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H227Combustible liquid

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P403+P235Store in a well-ventilated place. Keep cool.

P405Store locked up.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 135194
Product name: Bromocyclohexane
Purity: 98%
Packaging: 5g
Price: $23
Updated: 2024/03/01

Sigma-Aldrich

Product number: 135194
Product name: Bromocyclohexane
Purity: 98%
Packaging: 1kg
Price: $178
Updated: 2024/03/01

TCI Chemical

Product number: B0581
Product name: Bromocyclohexane
Purity: >98.0%(GC)
Packaging: 25g
Price: $18
Updated: 2024/03/01

TCI Chemical

Product number: B0581
Product name: Bromocyclohexane
Purity: >98.0%(GC)
Packaging: 100g
Price: $30
Updated: 2024/03/01

Alfa Aesar

Product number: A11593
Product name: Bromocyclohexane, 98%
Packaging: 100g
Price: $27.65
Updated: 2024/03/01

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Bromocyclohexane Chemical Properties,Usage,Production

Chemical Properties

colourless liquid

Uses

Bromocyclohexane has been used to study the ionization of equatorial and axial conformational isomers of the chair-bromocyclohexane using vacuum ultraviolet mass-analyzed threshold ionization spectroscopy.

Preparation

Bromocyclohexane is synthesized by the reaction of cycloethanol and hydrobromic acid.

Synthesis Reference(s)

Canadian Journal of Chemistry, 50, p. 3109, 1972 DOI: 10.1139/v72-498
Journal of the American Chemical Society, 112, p. 8212, 1990 DOI: 10.1021/ja00178a080
The Journal of Organic Chemistry, 45, p. 1638, 1980 DOI: 10.1021/jo01297a020

General Description

Axial conformer of bromocyclohexane forms inclusion complexes with 9,9′-bianthryl and exhibits a weak 1,3 diaxial Cl...H interaction. It participates in the alkylation reaction of of para-xylene in the presence of graphite as catalyst to yield hydrocarbon.

Purification Methods

Shake the bromide with 60% aqueous HBr to remove the free alcohol. After removing excess HBr, the sample is dried and fractionally distilled. [IR: Roberts & Chambers J Am Chem Soc 73 5031 1951, Beilstein 5 III 48, 5 IV 67.]

Bromocyclohexane Preparation Products And Raw materials

Raw materials

Hydrogen bromide Cyclohexanol

Preparation Products

1,1'-Bis (di-t-butylphosphino)ferrocene palladium dichloride, 1-Cyclohexylpiperazine Bis(tricyclohexylphosphine)palladium(II) Dichloride 1,1'-Bis(di-tert-butylphosphino)ferrocene 2-Dicyclohexylphosphino-2'-(N,N-dimethylamino)biphenyl 2-(Dicyclohexylphosphino)biphenyl Tricyclohexyl phosphine

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Bromocyclohexane Suppliers

Americas 1 Belgium 4 Canada 1 China 276 Europe 4 France 1 Germany 9 India 28 Israel 2 Japan 10 Slovakia 1 South Korea 2 Switzerland 2 The Netherlands 1 United Kingdom 11 United States 39 Global 392

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View Lastest Price from Bromocyclohexane manufacturers

Hebei Weibang Biotechnology Co., Ltd

Product: CYCLOHEXYL BROMIDE 108-85-0
Price: US $1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 10 mt
Release date: 2024-11-05

Hebei Yanxi Chemical Co., Ltd.

Product: Bromocyclohexane 108-85-0
Price: US $50.00/kg
Min. Order: 1kg
Purity: 99.9（%）
Supply Ability: 30 tons
Release date: 2024-03-12

Hebei Chuanghai Biotechnology Co,.LTD

Product: Bromocyclohexane 108-85-0
Price: US $10.70/KG
Min. Order: 10KG
Purity: 99%
Supply Ability: 10000kg
Release date: 2024-08-20

108-85-0, BromocyclohexaneRelated Search:

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108-85-0

-CH2CH24CHBr

6H11Br

Halogenated Hydrocarbons

Alkyl

Organic Building Blocks

HALOGEN

Building Blocks

Alkyl

Building Blocks

Chemical Synthesis

Pharmaceutical Intermediates

Halogen compounds

Halogenated Hydrocarbons

Organic Building Blocks