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Methyl 3-(bromomethyl)benzoate

Product Name
Methyl 3-(bromomethyl)benzoate
CAS No.
1129-28-8
Chemical Name
Methyl 3-(bromomethyl)benzoate
Synonyms
TIMTEC-BB SBB005793;METHYL ALPHA-BROMO-M-TOLUATE;M-CARBOMETHOXYBENZYL BROMIDE;3-CARBOMETHOXYBENZYL BROMIDE;Methyl 3-(bromomethyl)benzoat;METHYL 3-(BROMOMETHYL)BENZOATE;Methyle3-(bromomethyl)benzoate;Methyl 3-aMino-4-fluorobezoate;Methyl m-(Bromomethyl)benzoate;3-(BROMOMETHYL)PHENYLACETICACID
CBNumber
CB0331184
Molecular Formula
C9H9BrO2
Formula Weight
229.07
MOL File
1129-28-8.mol
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Methyl 3-(bromomethyl)benzoate Property

Melting point:
46-47 °C(lit.)
Boiling point:
112-114 °C3 mm Hg(lit.)
Density 
1,47 g/cm3
Flash point:
115°C/0.8mm
storage temp. 
2-8°C
form 
Crystals or Crystalline Powder
color 
White
Water Solubility 
Slightly soluble in water.
BRN 
638569
InChI
InChI=1S/C9H9BrO2/c1-12-9(11)8-4-2-3-7(5-8)6-10/h2-5H,6H2,1H3
InChIKey
YUHSMQQNPRLEEJ-UHFFFAOYSA-N
SMILES
C(OC)(=O)C1=CC=CC(CBr)=C1
CAS DataBase Reference
1129-28-8(CAS DataBase Reference)
NIST Chemistry Reference
Methyl 3-bromomethylbenzoate(1129-28-8)
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Safety

Hazard Codes 
C,Xi
Risk Statements 
22-34-43
Safety Statements 
26-36/37/39-45
RIDADR 
UN 3261 8/PG 2
WGK Germany 
2
F 
19
Hazard Note 
Irritant/Corrosive
HazardClass 
8
PackingGroup 
III
HS Code 
29163990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H302Harmful if swallowed

H314Causes severe skin burns and eye damage

H317May cause an allergic skin reaction

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P270Do not eat, drink or smoke when using this product.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
648116
Product name
Methyl 3-(bromomethyl)benzoate
Purity
97%
Packaging
5g
Price
$54.7
Updated
2025/07/31
Sigma-Aldrich
Product number
648116
Product name
Methyl 3-(bromomethyl)benzoate
Purity
97%
Packaging
25g
Price
$232.75
Updated
2025/07/31
TCI Chemical
Product number
B2224
Product name
Methyl 3-(Bromomethyl)benzoate
Purity
>97.0%(GC)
Packaging
5g
Price
$47
Updated
2025/07/31
TCI Chemical
Product number
B2224
Product name
Methyl 3-(Bromomethyl)benzoate
Purity
>97.0%(GC)
Packaging
25g
Price
$142
Updated
2025/07/31
TRC
Product number
M294015
Product name
Methyl 3-(Bromomethyl)benzoate
Packaging
1g
Price
$50
Updated
2021/12/16
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Methyl 3-(bromomethyl)benzoate Chemical Properties,Usage,Production

Chemical Properties

white crystalline powder or crystals

Uses

Methyl 3-(bromomethyl)benzoate is used in organic synthesis of other chemicals.

Synthesis

99-36-5

1129-28-8

General procedure for the synthesis of methyl 3-bromomethylbenzoate from methyl m-methylbenzoate: 30 mL of carbon tetrachloride (CCl4) and 7.9 g of methyl m-methylbenzoate were added to a dry 100 mL three-necked flask, and after dissolution, 0.23 g of AIBN (azobisisobutyronitrile) and 9.36 g of NBS (N-bromosuccinimide) were sequentially added in three additions (with an interval of about 2-3 hours). The reaction system was heated to 70°C and the color of the reaction solution was observed to change gradually from yellow to orange and finally to white. The reaction was monitored by TLC (eluent: cyclohexane/ethyl acetate = 5:1) until the reaction was almost complete. At the end of the reaction, the resulting succinimide and unreacted N-bromosuccinimide were removed by filtration. The filtrate was rotary evaporated to give 11.5 g of a yellow oily product, methyl 3-bromomethylbenzoate, in 95% yield.

References

[1] Organic and Biomolecular Chemistry, 2003, vol. 1, # 14, p. 2506 - 2511
[2] Patent: CN106146413, 2016, A. Location in patent: Paragraph 0027; 0028
[3] European Journal of Medicinal Chemistry, 2009, vol. 44, # 1, p. 7 - 17
[4] Molecules, 2016, vol. 21, # 12,
[5] Patent: WO2018/169777, 2018, A1. Location in patent: Paragraph 0227

Methyl 3-(bromomethyl)benzoate Preparation Products And Raw materials

Raw materials

Benzoyl peroxide N-Bromosuccinimide Carbon tetrachloride Methyl 3-methylbenzoate PETROLEUM ETHER

Preparation Products

METHYL 3-((PIPERIDIN-4-YL)METHYL)BENZOATE 3-((1-(TERT-BUTOXYCARBONYL)PIPERIDIN-4-YL)METHYL)BENZOIC ACID Methyl 3-(aminomethyl)benzoate hydrochloride
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View Lastest Price from Methyl 3-(bromomethyl)benzoate manufacturers

Hebei Fengjia New Material Co., Ltd
Product
Methyl 3-(bromomethyl)benzoate 1129-28-8
Price
US $5.00/kg
Min. Order
1kg
Purity
0.99
Supply Ability
10000
Release date
2024-09-10
Hebei Chuanghai Biotechnology Co., Ltd
Product
Methyl 3-(bromomethyl)benzoate 1129-28-8
Price
US $10.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
5tons
Release date
2024-12-02
Shaanxi Dideu Medichem Co. Ltd
Product
Methyl 3-(bromomethyl)benzoate 1129-28-8
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
99.0%
Supply Ability
1000MT
Release date
2024-07-17

1129-28-8, Methyl 3-(bromomethyl)benzoateRelated Search:

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