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Poly(ethyl vinyl ether)

Product Name
Poly(ethyl vinyl ether)
CAS No.
25104-37-4
Chemical Name
Poly(ethyl vinyl ether)
Synonyms
POLY(VINYL ETHYL ETHER);ebdc;Vinyl Ethyl Ether Resin (Low M.Wt.);edbc;ehbc;ehb-m;lutonala25;lutonala50;luthonala20;bakeliteehbc
CBNumber
CB0365101
Molecular Formula
C4H8O
Formula Weight
72.11
MOL File
25104-37-4.mol
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Poly(ethyl vinyl ether) Property

Density 
0.968 g/mL at 25 °C (lit.)
Tg
-60
vapor pressure 
22.5 mm Hg ( 20 °C)
refractive index 
n20/D 1.454(lit.)
Flash point:
140
form 
Viscous liquid
InChI
InChI=1S/C4H8O/c1-3-5-4-2/h3H,1,4H2,2H3
InChIKey
FJKIXWOMBXYWOQ-UHFFFAOYSA-N
SMILES
O(C=C)CC
CAS DataBase Reference
25104-37-4
EPA Substance Registry System
Poly(vinyl ethyl ether) (25104-37-4)
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Safety

Safety Statements 
24/25
WGK Germany 
3
RTECS 
CQ6693000
Autoignition Temperature
446 °F
TSCA 
TSCA listed
Toxicity
LD50 intraperitoneal in mouse: 2590mg/kg
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H226Flammable liquid and vapour

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
182656
Product name
Poly(ethyl vinyl ether)
Purity
average Mw ~3,800 by GPC
Packaging
100g
Price
$190.39
Updated
2025/07/31
scipoly
Product number
154
Product name
Poly(vinyl ethyl ether)
Packaging
250g
Price
$27
Updated
2024/07/03
scipoly
Product number
154
Product name
Poly(vinyl ethyl ether)
Packaging
500g
Price
$43
Updated
2024/07/03
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Poly(ethyl vinyl ether) Chemical Properties,Usage,Production

Chemical Properties

Poly(ethyl vinyl ether) is a opaque amber viscous liquid, It is a hydrophobic material that is insoluble in water or other polar solvents.

Uses

Poly(ethyl vinyl ether) can used as a plasticiser for cellulose nitrate and cellulose resin lacquers, as a base for pressure-sensitive adhesives in films and tapes, especially in surgical applications. Also used for non-irritating surgical casts requiring moisture permeability and to impart dry-film flexibility and increased viscosity of photochemical resist-coating compositions.

Preparation

To a flask containing 200 gm of benzene is added 1.0 gm of aluminum chloride. The mixture is stirred vigorously to suspend the catalyst and then the gradual addition of 200 gm (2.78 moles) of vinyl ether is begun. The reaction is exothermic, and when the temperature rises to 60°-80°C the addition is slowed so that only 1-2 gm of vinyl ethyl ether is added at one time. Polymerization is detected by the onset of turbidity and a slight brown color. When the brown color disappears, the next increment of vinyl ethyl ether is added. After the complete addition the reaction mixture is heated to 80°C. The benzene and volatiles are steam-distilled off, and the residue amounts to about 144 gm (72%) of a yellow balsamlike product.

Preparation of Poly(vinyl ethyl ether) Using Aluminum Chloride Catalyst

Hazard

Moderately toxic.

Safety Profile

Moderately toxic by intraperitoneal route. When heated to decomposition it emits acrid smoke and irritating vapors.

Solubility in organics

alcohols, aliphatic, aromatic and chlorinated hydrocarbons, esters, ketones

Poly(ethyl vinyl ether) Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from Poly(ethyl vinyl ether) manufacturers

Nanjing Paron Technology Co., Ltd
Product
Poly(ethyl vinyl ether), LUT-A25 & A50 25104-37-4
Price
US $0.00/kg
Min. Order
1kg
Purity
48.0-52.0%
Supply Ability
1000000
Release date
2025-11-20
Shaanxi Dideu Medichem Co. Ltd
Product
Lutonal A25 and 50 25104-37-4
Price
US $1.10/g
Min. Order
1g
Purity
99.0% min
Supply Ability
100 tons min
Release date
2025-09-11
Baoji Guokang Healthchem Co., Ltd.
Product
Poly(ethyl vinyl ether) 50% in ethanol (LUT-A5050E) 25104-37-4
Price
US $0.00/kg
Min. Order
20kg
Purity
50.0±2%
Supply Ability
20t
Release date
2023-10-30

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