ChemicalBook > CAS DataBase List > L(+)-Diethyl L-tartrate
L(+)-Diethyl L-tartrate
- Product Name
- L(+)-Diethyl L-tartrate
- CAS No.
- 87-91-2
- Chemical Name
- L(+)-Diethyl L-tartrate
- Synonyms
- DET;DIETHYL TARTRATE;L-DET;DIETHYL L-TARTRATE;Diethyl (2R,3R)-tartrate;diethyl tartarate;(2S,3S)-diethyl 2,3-dihydroxysuccinate;Diethyl (2R,3R)-2,3-dihydroxybutanedioate;FEMA 2378;-tartrate
- CBNumber
- CB0456290
- Molecular Formula
- C8H14O6
- Formula Weight
- 206.19
- MOL File
- 87-91-2.mol
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L(+)-Diethyl L-tartrate Property
- Melting point:
- 17 °C
- Boiling point:
- 280 °C (lit.)
- alpha
- 7.5 º (neat)
- Density
- 1.204 g/mL at 25 °C (lit.)
- vapor pressure
- 0.402Pa at 25℃
- refractive index
- n20/D 1.446(lit.)
- FEMA
- 2378 | DIETHYL TARTRATE
- Flash point:
- 200 °F
- storage temp.
- Sealed in dry,Room Temperature
- solubility
- Chloroform (Slightly), Water (Slightly)
- pka
- 11.61±0.20(Predicted)
- form
- Viscous Liquid
- color
- Clear
- Odor
- at 100.00 %. mild fruity wine caramellic
- Odor Type
- fruity
- optical activity
- [α]20/D +8.5°, neat
- Water Solubility
- insoluble
- JECFA Number
- 622
- Merck
- 14,3855
- BRN
- 1727145
- Dielectric constant
- 4.5（20℃）
- InChIKey
- YSAVZVORKRDODB-PHDIDXHHSA-N
- LogP
- 0.2 at 25℃
- CAS DataBase Reference
- 87-91-2(CAS DataBase Reference)
- NIST Chemistry Reference
- Diethyl tartrate(87-91-2)
- EPA Substance Registry System
- Butanedioic acid, 2,3-dihydroxy- (2R,3R)-, 1,4-diethyl ester (87-91-2)
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Safety
- Hazard Codes
- Xi
- Risk Statements
- 36/37/38
- Safety Statements
- 24/25-36-26
- WGK Germany
- 3
- TSCA
- Yes
- HS Code
- 29181300
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N-Bromosuccinimide Price
Sigma-Aldrich
- Product number
- W237809
- Product name
- Diethyl L-tartrate
- Purity
- ≥99%, FG
- Packaging
- 100g
- Price
- $76.5
- Updated
- 2024/03/01
Sigma-Aldrich
- Product number
- W237809
- Product name
- Diethyl L-tartrate
- Purity
- ≥99%, FG
- Packaging
- 1kg
- Price
- $231
- Updated
- 2024/03/01
Sigma-Aldrich
- Product number
- W237809
- Product name
- Diethyl L-tartrate
- Purity
- ≥99%, FG
- Packaging
- 5kg
- Price
- $846
- Updated
- 2024/03/01
Sigma-Aldrich
- Product number
- 156841
- Product name
- (+)-Diethyl L-tartrate
- Purity
- ≥99%
- Packaging
- 100g
- Price
- $30.2
- Updated
- 2024/03/01
Sigma-Aldrich
- Product number
- 156841
- Product name
- (+)-Diethyl L-tartrate
- Purity
- ≥99%
- Packaging
- 25g
- Price
- $34.3
- Updated
- 2024/03/01
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L(+)-Diethyl L-tartrate Chemical Properties,Usage,Production
Chemical Properties
Colorless to light yellow liqui
Chemical Properties
Diethyl tartrate has a mild, fruity, wine aroma.
Occurrence
The d-isomer has not been reported found in nature; the l-isomer and the racemic form are of little importance. Reported found in sherry, white and red wine.
Uses
(+)-Diethyl L-tartrate is used as a chiral auxiliary in the Sharpless enantioselective epoxidation of allylic alcohols, for Sharpless-type enantioselective oxidation of sulfides to sulfoxides and as a chiral auxiliary in the enantioselective construction of cyclopropanes from allylic alcohols by an asymmetric Simmons-Smith reaction. It is also used as a chiral reagent in a host of chemical reactions, such as the synthesis of isoquinoline alkaloids and arundic acid, which has been used in acute ischemic stroke therapy.
Uses
(+)-Diethyl L-tartrate can be used in the synthesis of biologically active compounds such as (+)-altholactone, (-)-aspicilin, (+)-monomorine I and (+)-(1R,2R,3S,6S)-3,6-di-O-methyl conduritol-E.
Uses
Diethyl L-(+)-Tartrate is used as a chiral reagent in a host of chemical reactions, such as the synthesis of isoquinoline alkaloids and arundic acid, which has been used in acute ischemic stroke thera py.
General Description
Made from natural tartaric acid
Flammability and Explosibility
Non flammable
L(+)-Diethyl L-tartrate Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from L(+)-Diethyl L-tartrate manufacturers
Shaanxi Dideu Medichem Co. Ltd
- Product
- Diethyl L-(+)-Tartrate 87-91-2
- Price
- US $1.00-0.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 50 tons
- Release date
- 2020-01-17
Zibo Hangyu Biotechnology Development Co., Ltd
- Product
- L(+)-Diethyl L-tartrate 87-91-2
- Price
- US $80.00-800.00/kg
- Min. Order
- 10kg
- Purity
- 0.99
- Supply Ability
- 20tons
- Release date
- 2023-10-31
Hebei Zhuanglai Chemical Trading Co.,Ltd
- Product
- L(+)-Diethyl L-tartrate 87-91-2
- Price
- US $200.00-85.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 20ton
- Release date
- 2024-04-23
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