ChemicalBook > CAS DataBase List > Methyl trifluoroacetate

Methyl trifluoroacetate

Product Name
Methyl trifluoroacetate
CAS No.
431-47-0
Chemical Name
Methyl trifluoroacetate
Synonyms
Methyl 2,2,2-trifluoroacetate;TFAME;Methyl trifluoroacet;Methyltrifluoracetat;Mthyl trifluoroacetate;METHYL TRIFLUOROACETATE;Methyletrifluoroacetate;Methyl perfluoroacetate;Methyltrifluoroacetate99%;Methyltrifluoroacetate,97%
CBNumber
CB0737399
Molecular Formula
C3H3F3O2
Formula Weight
128.05
MOL File
431-47-0.mol
More
Less

Methyl trifluoroacetate Property

Melting point:
-78 °C
Boiling point:
43-43.5 °C (lit.)
Density 
1.273 g/mL at 25 °C (lit.)
vapor pressure 
5.77 psi ( 20 °C)
refractive index 
n20/D 1.291(lit.)
Flash point:
19 °F
storage temp. 
Inert atmosphere,2-8°C
solubility 
8g/l
form 
Liquid
Specific Gravity
1.273
color 
Clear colorless
PH
7 (8g/l, H2O, 20℃)
explosive limit
6.1-24.8%(V)
Water Solubility 
8 g/L
Sensitive 
Moisture Sensitive
BRN 
1756070
Dielectric constant
11.460000000000001
Stability:
Volatile
LogP
0.6
CAS DataBase Reference
431-47-0(CAS DataBase Reference)
NIST Chemistry Reference
CF3C(O)OCH3(431-47-0)
EPA Substance Registry System
Acetic acid, trifluoro-, methyl ester (431-47-0)
More
Less

Safety

Hazard Codes 
F,C
Risk Statements 
11-34
Safety Statements 
16-26-36/37/39-45
RIDADR 
UN 2924 3/PG 2
WGK Germany 
1
19
Hazard Note 
Flammable/Corrosive
TSCA 
T
HazardClass 
3
PackingGroup 
II
HS Code 
29159080
More
Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H225Highly Flammable liquid and vapour

H314Causes severe skin burns and eye damage

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P233Keep container tightly closed.

P240Ground/bond container and receiving equipment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

More
Less

N-Bromosuccinimide Price

Sigma-Aldrich
Product number
249831
Product name
Methyl trifluoroacetate
Purity
99%
Packaging
25g
Price
$51.6
Updated
2024/03/01
Sigma-Aldrich
Product number
249831
Product name
Methyl trifluoroacetate
Purity
99%
Packaging
100g
Price
$165
Updated
2024/03/01
TCI Chemical
Product number
T0680
Product name
Methyl Trifluoroacetate
Purity
>98.0%(GC)
Packaging
25g
Price
$19
Updated
2024/03/01
TCI Chemical
Product number
T0680
Product name
Methyl Trifluoroacetate
Purity
>98.0%(GC)
Packaging
500g
Price
$126
Updated
2021/12/16
Alfa Aesar
Product number
A17338
Product name
Methyl trifluoroacetate, 98+%
Packaging
50g
Price
$61.65
Updated
2024/03/01
More
Less

Methyl trifluoroacetate Chemical Properties,Usage,Production

Chemical Properties

clear colorless liquid

Uses

Methyl trifluoroacetate has been used as reagent for trifluoroacetylation of amines and amino acids.

Synthesis Reference(s)

Journal of the American Chemical Society, 113, p. 700, 1991 DOI: 10.1021/ja00002a063

General Description

Methyl trifluoroacetate along with cesium fluoride or cesium chloride and CuI constitutes a valuable trifluoromethylating reagent for substituting aromatic (or heteroaromatic) iodides and bromides. Adsorption of methyl trifluoroacetate on amorphous silica has been investigated. Fragmentation mechanism of generation of metastable ions from methyl trifluoroacetate has been investigated by mass analyzed ion kinetic energy spectra and ab initio molecular orbital calculations.

Flammability and Explosibility

Flammable

Methyl trifluoroacetate Preparation Products And Raw materials

Raw materials

Preparation Products

More
Less

Methyl trifluoroacetate Suppliers

Shandong Jiaoyang Chemical Co., Ltd
Tel
18265196555 18265196555
Email
27207437@qq.com
Country
China
ProdList
43
Advantage
58
Shanghai Yihe Biological Technology Co., Ltd.
Tel
17721395025
Fax
021-68882955
Email
2423903095@qq.com
Country
China
ProdList
3149
Advantage
58
SHANG FLUORO
Tel
021-021-65170832 15601903708
Email
qinba_1@163.com
Country
China
ProdList
306
Advantage
60
Linyi Hongda Chemical Co., Ltd
Tel
0539-7578168 13791585810
Email
46439760@qq.com
Country
China
ProdList
50
Advantage
58
Shandong longyue of chemical co., LTD
Tel
15318857512
Email
1912317598@qq.com
Country
China
ProdList
47
Advantage
58
Shandong Ruibowen New Material Technology Co., Ltd
Tel
15064961989
Email
420700630@qq.com
Country
China
ProdList
249
Advantage
58
Jinan New Era Chemical Co., Ltd.
Tel
0531-84319199 18660131512
Email
1417934650@qq.com
Country
China
ProdList
47
Advantage
58
jinanzhonglanhuagongyouxiangongsi
Tel
0531-84215177 15169176553
Email
644658103@qq.com
Country
China
ProdList
22
Advantage
58
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
4006608290; 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40241
Advantage
62
More
Less

View Lastest Price from Methyl trifluoroacetate manufacturers

airuikechemical co., ltd.
Product
methyl trifluoroacetate 431-47-0
Price
US $0.00-0.00/Kg
Min. Order
1Kg
Purity
99.9%
Supply Ability
200tons
Release date
2024-04-08
Hebei Yanxi Chemical Co., Ltd.
Product
Methyl trifluoroacetate 431-47-0
Price
US $30.00/KG
Min. Order
1KG
Purity
0.99
Supply Ability
25MT/MON
Release date
2023-09-04
Hebei Guanlang Biotechnology Co,.LTD
Product
Methyl Trifluoroacetate 431-47-0
Price
US $5.00-2.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10000kg
Release date
2023-04-14

431-47-0, Methyl trifluoroacetateRelated Search:


  • Methyl trifluoroacet
  • Methyl trifluoroacetate, 99% 25ML
  • METHYL TRIFLUOROACETATE FOR SYNTHESIS
  • Trifluoroacetic acid methyl ester, Methyl 2,2,2-trifluoroethanoate
  • Methyl trifluoroacetate (TFAM)
  • Methyletrifluoroacetate
  • METHYL TRIFLUOROACETATE
  • Acetic acid, trifluoro-, methyl ester
  • trifluoro-aceticacimethylester
  • TFAME
  • Methyl trifluoroacetate 99%
  • 2,2,2-TRIFLOUROMETHYLACETATE(TFAMT)
  • Methyltrifluoroacetate99%
  • Methyltrifluoracetat
  • Mthyl trifluoroacetate
  • Methyl trifluoroacetate, 98+%
  • Methyl 2,2,2-trifluoroacetate
  • Methyl perfluoroacetate
  • Methyltrifluoroacetate,97%
  • Trifluoroacetic Acid Methyl Ether
  • TRIFLUOROACETIC ACID METHYL ESTER
  • Methyl Trifluoroacetate &gt
  • Acetic acid, 2,2,2-trifluoro-, methyl ester
  • TIANFU CHEM---Methyl trifluoroacetate
  • 431-47-0
  • CF3CO2CH3
  • C3H3F3O2
  • CF3COOCH3
  • Reagents for Oligosaccharide Synthesis
  • Building Blocks
  • Carbonyl Compounds
  • C2 to C5
  • Organic Building Blocks
  • Esters
  • Biochemistry
  • Reagents for Oligosaccharide Synthesis
  • C2 to C5
  • Carbonyl Compounds
  • Esters
  • PHARMACEUTICAL INTERMEDIATES
  • john's