Dess-Martin periodinane
- Product Name
- Dess-Martin periodinane
- CAS No.
- 87413-09-0
- Chemical Name
- Dess-Martin periodinane
- Synonyms
- DESS-MARTIN;Dess-Martin periodane;DESS-MARTIN REAGENT;PERIODINANE;DESS-MARTINE;1,1,1-TRIACETOXY-1,1-DIHYDRO-1,2-BENZIODOXOL-3(1H)-ONE;Dess-Martin periodinane,D M P, TAPI;3-oxo-1l5-benzo[d][1,2]iodaoxole-1,1,1(3H)-triyl triacetate;1,1,1-TRIS(ACETYLOXY)-1,1-DIHYDRO-1,2-BENZIODOXOL-3-(1H)-ONE;Martin's reagent
- CBNumber
- CB0776475
- Molecular Formula
- C13H13IO8
- Formula Weight
- 424.14
- MOL File
- 87413-09-0.mol
Dess-Martin periodinane Property
- Melting point:
- 130-133 °C (lit.)
- Boiling point:
- 40 °C
- Density
- 1.369 g/mL at 25 °C
- Flash point:
- >221 °F
- storage temp.
- -20°C
- solubility
- Soluble in chloroform, acetone, acetonitrile and methylene chloride. Slightly soluble in ether and hexane.
- form
- Liquid
- color
- Colorless to light yellow
- Sensitive
- Light Sensitive
- Merck
- 14,2933
- BRN
- 4548207
- Stability:
- Light Sensitive
- InChI
- InChI=1S/C13H13IO8/c1-8(15)19-14(20-9(2)16,21-10(3)17)12-7-5-4-6-11(12)13(18)22-14/h4-7H,1-3H3
- InChIKey
- NKLCNNUWBJBICK-UHFFFAOYSA-N
- SMILES
- I1(OC(=O)C)(OC(=O)C)(OC(=O)C)OC(=O)C2C=CC=CC1=2
- CAS DataBase Reference
- 87413-09-0(CAS DataBase Reference)
Safety
- Hazard Codes
- Xn,O,Xi
- Risk Statements
- 22-36/37/38-40-8-20/21/22-44
- Safety Statements
- 26-36-36/37-24/25-23-17-45-36/37/39
- RIDADR
- UN 1593 6.1/PG 3
- WGK Germany
- 3
- Hazard Note
- Harmful/Light sensitive
- TSCA
- No
- HazardClass
- 5.1
- PackingGroup
- Ⅲ
- HS Code
- 29349990
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H272May intensify fire; oxidizer
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P220Keep/Store away from clothing/…/combustible materials.
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 274623
- Product name
- Dess-Martin periodinane
- Purity
- 97%
- Packaging
- 5g
- Price
- $136
- Updated
- 2024/03/01
- Product number
- 274623
- Product name
- Dess-Martin periodinane
- Purity
- 97%
- Packaging
- 25g
- Price
- $648
- Updated
- 2024/03/01
- Product number
- D2045
- Product name
- Dess-Martin Periodinane
- Purity
- >95.0%(T)
- Packaging
- 1g
- Price
- $35
- Updated
- 2024/03/01
- Product number
- D2045
- Product name
- Dess-Martin Periodinane
- Purity
- >95.0%(T)
- Packaging
- 5g
- Price
- $106
- Updated
- 2024/03/01
- Product number
- L15779
- Product name
- Dess-Martin periodinane
- Packaging
- 1g
- Price
- $39.3
- Updated
- 2024/03/01
Dess-Martin periodinane Chemical Properties,Usage,Production
Description
Dess-Martin periodinane (DMP) is a hypervalent iodine compound widely used as a mild reagent for the oxidation of primary/secondary alcohols to aldehydes/ketones; oxidation of amides into imides; the dehydrogenation of amines to nitriles, and disulfides to sulfones. It is also used to selectively oxidize alkenes to epoxides. This is a useful reaction for generating three-membered cyclic ethers. Additionally, DMP is used to oxidatively cleave 1,2-diols to form aldehydes or ketones and in the synthesis of lactones.
Chemical Properties
White Crystalline powder
Uses
Dess-Martin Periodinaneis a very usefulreagent used in the oxidation of primary alcohols to aldehydes and secondary alcohols to ketones.
Uses
Dess Martin periodinane is used to oxidize primary alcohols to aldehydes and secondary alcohols to ketones. It is also used as an oxidant for complexes with multifunctional alcohols. It is actively involved in the oxidation of N-protected-amino alcohols without epimerization and allylic alcohols.
Uses
Oxidizing reagent.
Advantages
Benefits of using Dess-Martin periodinane (DMP) as an oxidizing reagent:
milder reaction conditions (room temperature, neutral pH)
shorter reaction times and higher yields
high chemoselectivity
tolerance of sensitive functional groups, and a long shelf life
simplified workups
Dess-Martin periodinane Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from Dess-Martin periodinane manufacturers
- Product
- Dess-Martin periodinane 87413-09-0
- Price
- US $79.00-38.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 20ton
- Release date
- 2024-11-21
- Product
- 1,1,1-triacetoxy-1,1-dihydro-1,2-benziodoxol-3(1H)-one 87413-09-0
- Price
- US $786.00/g
- Min. Order
- 1g
- Purity
- 98
- Supply Ability
- 500 Kg
- Release date
- 2024-11-12
- Product
- Dess-Martin periodinane 87413-09-0
- Price
- US $1.00/g
- Min. Order
- 1g
- Purity
- 99%
- Supply Ability
- 10 tons
- Release date
- 2021-03-23