3-FLUORO-5-(4,4,5,5-TETRAMETHYL-[1,3,2]DIOXABOROLAN-2-YL)PYRIDINE

Product Name: 3-FLUORO-5-(4,4,5,5-TETRAMETHYL-[1,3,2]DIOXABOROLAN-2-YL)PYRIDINE
CAS No.: 719268-92-5
Chemical Name: 3-FLUORO-5-(4,4,5,5-TETRAMETHYL-[1,3,2]DIOXABOROLAN-2-YL)PYRIDINE
Synonyms: 5-fluoropyridine-3-borate;5-Fluoropyridinyl-3-boronicacidpinacolate;5-Fluoro-3-pyridylboronic Acid Pinacol Ester;3-FLUOROPYRIDINE-5-BORONIC ACID PINACOL ESTER;5-Fluoropyridin-3-ylboronic acid pinacol ester;3-Fluoro-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl);(3-fluoro-5-(tetramethyl-1,3,2-dioxaborolan-2-yl)pyridine);2-(5-Fluoro-3-pyridyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane;3-fluoro-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)pyri...;3-Fluoro-5-(4,4,5,5-tetraMethy-[1,3,2]dioxaborolan-2-yl)pyridine
CBNumber: CB0839978
Molecular Formula: C11H15BFNO2
Formula Weight: 223.05
MOL File: 719268-92-5.mol

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3-FLUORO-5-(4,4,5,5-TETRAMETHYL-[1,3,2]DIOXABOROLAN-2-YL)PYRIDINE Property

Melting point:: 55.0 to 59.0 °C
Boiling point:: 294.5±25.0 °C(Predicted)
Density: 1.09±0.1 g/cm3(Predicted)
storage temp.: Storage temp. 2-8°C
form: powder to crystal
pka: 2.80±0.22(Predicted)
color: White to Almost white
InChIKey: VFMTUTYBMBTIGA-UHFFFAOYSA-N
CAS DataBase Reference: 719268-92-5

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Safety

Hazard Codes: Xi
WGK Germany: 3
Hazard Note: Irritant
HS Code: 2933399990

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P337+P313IF eye irritation persists: Get medical advice/attention.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: SYX00194
Product name: 3-Fluoro-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)pyridine
Purity: Aldrich
Packaging: 1g
Price: $475
Updated: 2025/07/31

TCI Chemical

Product number: F1026
Product name: 3-Fluoro-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)pyridine
Purity: >98.0%(GC)(T)
Packaging: 1g
Price: $196
Updated: 2025/07/31

TRC

Product number: F596233
Product name: 5-Fluoropyridine-3-boronicacid,pinacolester
Packaging: 100mg
Price: $45
Updated: 2021/12/16

TRC

Product number: F596233
Product name: 5-Fluoropyridine-3-boronicacid,pinacolester
Packaging: 500mg
Price: $65
Updated: 2021/12/16

SynQuest Laboratories

Product number: 8H60-3-13
Product name: 5-Fluoropyridine-3-boronic acid, pinacol ester
Packaging: 250mg
Price: $70
Updated: 2021/12/16

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3-FLUORO-5-(4,4,5,5-TETRAMETHYL-[1,3,2]DIOXABOROLAN-2-YL)PYRIDINE Chemical Properties,Usage,Production

Synthesis

73183-34-3

462652-75-1

719268-92-5

5-Fluoropyridin-3-yl trifluoromethanesulfonate (3.67 g, 15.0 mmol), potassium acetate (2.94 g, 30.0 mmol), bis(pinacolato)diboron (4.18 g, 17.0 mmol), and dichloro[1,1'-bis(diphenylphosphino)ferrocene]palladium(II) dichloromethane (0.37 g, 0.45 mmol) were used in a 45 ml of 1,4-dioxane containing 1% dimethyl sulfoxide, the mixture was degassed with nitrogen for 1 hr and then heated at 90 °C for 14 hrs for the reaction. After completion of the reaction, it was cooled to room temperature and subsequently concentrated under vacuum. To the residue was added 2N sodium hydroxide solution (300 ml), stirred for 10 minutes and filtered. The filtrate was extracted with ether (2 x 200 ml) and the organic phase was discarded. The aqueous phase was cooled to 0°C and the pH was adjusted to 5 by slow dropwise addition of 36% hydrochloric acid over a period of 15 min. The resulting precipitate was allowed to stand at 0°C for 2 h. It was filtered and washed with ice water. The obtained sand-colored solid was dried under vacuum at 300 mmHg in the presence of phosphorus pentoxide to afford 3-fluoro-5-(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl)pyridine (3.0 g, 90% yield) as a yellow oil. Its NMR hydrogen spectrum (400 MHz, CDCl3) data were as follows: δH 1.25 (12H, s), 7.75 (1H, dd, J=5Hz and 1Hz), 8.52 (1H, d, J=3Hz), 8.74 (1H, s).

References

[1] Patent: US2004/132767, 2004, A1. Location in patent: Page 11

3-FLUORO-5-(4,4,5,5-TETRAMETHYL-[1,3,2]DIOXABOROLAN-2-YL)PYRIDINE Preparation Products And Raw materials

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3-FLUORO-5-(4,4,5,5-TETRAMETHYL-[1,3,2]DIOXABOROLAN-2-YL)PYRIDINE Suppliers

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View Lastest Price from 3-FLUORO-5-(4,4,5,5-TETRAMETHYL-[1,3,2]DIOXABOROLAN-2-YL)PYRIDINE manufacturers

Shaanxi Dideu Medichem Co. Ltd

Product: 3-FLUORO-5-(4,4,5,5-TETRAMETHYL-[1,3,2]DIOXABOROLAN-2-YL)PYRIDINE 719268-92-5
Price: US $1.10/g
Min. Order: 1g
Purity: 99.0% min
Supply Ability: 100 tons min
Release date: 2021-05-26

LY Global chemicals co.,ltd .

Product: 3-FLUORO-5-(4,4,5,5-TETRAMETHYL-[1,3,2]DIOXABOROLAN-2-YL)PYRIDINE 719268-92-5
Price: US $0.00-0.00/kg
Min. Order: 1kg
Purity: 98.0%
Supply Ability: 1000kg
Release date: 2023-04-05

Career Henan Chemical Co

Product: 3-FLUORO-5-(4,4,5,5-TETRAMETHYL-[1,3,2]DIOXABOROLAN-2-YL)PYRIDINE 719268-92-5
Price: US $0.01/KG
Min. Order: 1KG
Purity: 98%; 99%
Supply Ability: 1kg; 5kg
Release date: 2020-02-03

719268-92-5, 3-FLUORO-5-(4,4,5,5-TETRAMETHYL-[1,3,2]DIOXABOROLAN-2-YL)PYRIDINERelated Search:

3-FLUORO-5-(4,4,5,5-TETRAMETHYL-[1,3,2]DIOXABOROLAN-2-YL)PYRIDINE

3-FLUOROPYRIDINE-5-BORONIC ACID PINACOL ESTER

5-Fluoropyridinyl-3-boronicacidpinacolate

3-Fluoro-5-(4,4,5,5-tetraMethy-[1,3,2]dioxaborolan-2-yl)pyridine

5-Fluoropyridin-3-ylboronic acid pinacol ester

3-Fluoro-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)pyridine, 2-(5-Fluoropyridin-3-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

3-Fluoro-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)

Pyridine, 3-fluoro-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-

2-(5-Fluoro-3-pyridyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

5-Fluoro-3-pyridylboronic Acid Pinacol Ester

3-FLUORO-5-(4,4,5,5-TETRAMETHYL-[1,3,2]DIOXABOROLAN-2-YL)PYRIDINE ISO 9001：2015 REACH

3-fluoro-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)pyri...

(3-fluoro-5-(tetramethyl-1,3,2-dioxaborolan-2-yl)pyridine)

5-fluoropyridine-3-borate

3-Fluoro-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)pyridine - [F5445]

719268-92-5

Boronic ester

Organoborons

Pyridine