ChemicalBook > CAS DataBase List > Potassium trifluoromethanesulfonate

Potassium trifluoromethanesulfonate

Product Name
Potassium trifluoromethanesulfonate
CAS No.
2926-27-4
Chemical Name
Potassium trifluoromethanesulfonate
Synonyms
TRIFLUOROMETHANESULFONIC ACID POTASSIUM SALT;Potassium trifL;POTASSIUM TRIFLATE;Potassium trifluorometh;POTASSIUM TRIFLUOROMETHANESULFOTE;Potassium trifluoromethylsulfonate;Potassium trifluoromethanesulfonate;POTASSIUM TRIFLUOROMETHANESULPHONATE;Potassiumtrifluoromethanesulphonate99%;POTASSIUM TRIFLUOROMETHANESULFONIC ACID
CBNumber
CB1215063
Molecular Formula
CF3KO3S
Formula Weight
188.17
MOL File
2926-27-4.mol
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Potassium trifluoromethanesulfonate Property

Melting point:
238.5°C
storage temp. 
Inert atmosphere,Room Temperature
form 
solid
color 
White to Almost white
Water Solubility 
Soluble in water.
Sensitive 
Hygroscopic
Hydrolytic Sensitivity
6: forms irreversible hydrate
BRN 
3727495
InChI
InChI=1S/CHF3O3S.K/c2-1(3,4)8(5,6)7;/h(H,5,6,7);/q;+1/p-1
InChIKey
GLGXXYFYZWQGEL-UHFFFAOYSA-M
SMILES
C(F)(F)(F)S([O-])(=O)=O.[K+]
CAS DataBase Reference
2926-27-4(CAS DataBase Reference)
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Safety

Hazard Codes 
Xi,C
Risk Statements 
36/37/38
Safety Statements 
26-36
WGK Germany 
3
3-10
TSCA 
No
HazardClass 
CORROSIVE
HS Code 
29049090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
422843
Product name
Potassium trifluoromethanesulfonate
Purity
98%
Packaging
5g
Price
$37.4
Updated
2024/03/01
Sigma-Aldrich
Product number
422843
Product name
Potassium trifluoromethanesulfonate
Purity
98%
Packaging
25g
Price
$117
Updated
2024/03/01
TCI Chemical
Product number
T1549
Product name
Potassium Trifluoromethanesulfonate
Purity
>98.0%(T)
Packaging
25g
Price
$80
Updated
2024/03/01
Alfa Aesar
Product number
020361
Product name
Potassium trifluoromethanesulfonate, 98%
Packaging
10g
Price
$51.7
Updated
2024/03/01
Alfa Aesar
Product number
020361
Product name
Potassium trifluoromethanesulfonate, 98%
Packaging
50g
Price
$177
Updated
2024/03/01
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Potassium trifluoromethanesulfonate Chemical Properties,Usage,Production

Chemical Properties

white crystals or crystalline powder

Uses

Potassium trifluoromethanesulfonate is used as a reagent in the synthesis of guanine-quadruplex hybrid materials. It acts as a supporting electrolyte in the electrochemical study of evidence for gold anion in ethylenediamine. It is involved in the preparation of N-fluoro-2,4,6-trimethylpyridinium triflate by reacting with 2,4,6-trimethyl-pyridine. Further, it is used in the preparation of imidazolium salt, 3-methyl-1-(3R,3aR,6S,6aR)-[6-(benzyloxy)-hexahydrofuro[3,2-b]furan-3-yl]imidazolium trifluoromethanesulfonate.

Uses

Potassium trifluoromethanesulfonate is used in studies of mixed alkali effects and short range interactions in poly(ethylene oxide) electrolytes,1 and characteristics of the electrochemical behavior of glassy carbon in super-acid media.

General Description

Potassium trifluoromethanesulfonate (KOTf, potassium triflate) is the potassium salt of trifluoromethanesulphonic acid. It has been prepared by neutralizing a warm aqueous solution of trifluoromethanesulphonic acid with potassium carbonate. The structure of siloxane–poly(oxyethylene) hybrids doped with potassium triflate has been investigated.

structure and hydrogen bonding

According to the results of temperature dependent powder diffractometry potassium trifluoromethanesulfonate is dimorphic. The phase transition occurs between -63 degreesC and 45 degreesC. The low-temperature modification crystallizes monoclinic with a=10.300(3)Angstrom, b = 6.052(1) Angstrom, c = 14.710(4) Angstrom, beta =111.83(2)degrees (-120 degreesC) and the room-temperature modification with a=10.679(5) Angstrom, b=5.963(2)Angstrom, c=14.624(5)Angstrom, beta =111.57(3)degrees, Z=6, P2(1). According to single crystal structure determination, potassium trifluoromethanesulfonate consists of three different potassium-oxygen-coordination polyhedra, linked by sulfur atoms of the trifluoromethanesulfonate groups. This results in a channel structure with all lipophilic trifluoromethane groups pointing into these channels[1].

References

[1] Korus, G. , and M. Jansen . "Crystal structure, phase transition, and potassium ion conductivity of potassium trifluoromethanesulfonate." (2001).

Potassium trifluoromethanesulfonate Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from Potassium trifluoromethanesulfonate manufacturers

Wuhan Boyuan Import & Export Co., LTD
Product
Potassium trifluoromethanesulfonate 2926-27-4
Price
US $9.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
50000tons
Release date
2023-07-12
Hebei Guanlang Biotechnology Co., Ltd.
Product
Potassium trifluoromethanesulfonate 2926-27-4
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
500000kg
Release date
2023-03-07
Hebei Mojin Biotechnology Co., Ltd
Product
POTASSIUM TRIFLUOROMETHANESULFONATE 2926-27-4
Price
US $100.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
5000KG
Release date
2023-08-24

2926-27-4, Potassium trifluoromethanesulfonateRelated Search:


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