ETHYL ANTHRANILATE

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ETHYL ANTHRANILATE

Product Name: ETHYL ANTHRANILATE
CAS No.: 87-25-2
Chemical Name: ETHYL ANTHRANILATE
Synonyms: ETHYL 2-AMINOBENZOATE;ethyl-o-amino;o-(Ethoxycarbonyl)aniline;FEMA 2421;Ethylanthranilat;ETHYL ANTHRANILATE;2-carboethoxyaniline;ETHYL O-AMINOBENZOATE;Ethylanthranilate,98+%;Anthranilic acid ethyl
CBNumber: CB1221396
Molecular Formula: C9H11NO2
Formula Weight: 165.19
MOL File: 87-25-2.mol

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ETHYL ANTHRANILATE Property

Melting point:: 13-15 °C (lit.)
Boiling point:: 129-130 °C/9 mmHg (lit.)
Density: 1.117 g/mL at 25 °C (lit.)
vapor density: 5.7 (vs air)
refractive index: n20/D 1.564(lit.)
FEMA: 2421 | ETHYL ANTHRANILATE
Flash point:: >230 °F
storage temp.: Keep in dark place,Inert atmosphere,Room temperature
solubility: Insoluble in water but soluble in organic solvents
form: Clear liquid
pka: 2.20±0.10(Predicted)
color: Light yellow
Specific Gravity: 1.1170
Odor: at 100.00 %. sweet floral grape orangeblossom wintergreen
Odor Type: floral
JECFA Number: 1535
BRN: 878874
Stability:: Stable. Combustible. Incompatible with acids, bases, oxidizing agents.
LogP: 2.57
CAS DataBase Reference: 87-25-2(CAS DataBase Reference)
EPA Substance Registry System: Ethyl anthranilate (87-25-2)

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Safety

Hazard Codes: Xi
Risk Statements: 36/38
Safety Statements: 26-36
WGK Germany: 2
RTECS: DG2448000
Hazard Note: Irritant
TSCA: Yes
HS Code: 29224999
Hazardous Substances Data: 87-25-2(Hazardous Substances Data)
Toxicity: The acute oral LD₅₀ value in rats was reported as 3.75 g/kg (3.32-4.18 g/kg) and the acute dermal LD₅₀ value in rabbits exceeded 5 g/kg (Moreno, 1975).

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H303May be harmfulif swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: W242101
Product name: Ethyl 2-aminobenzoate
Purity: ≥96%, FCC, FG
Packaging: sample-k
Price: $54.6
Updated: 2024/03/01

Sigma-Aldrich

Product number: W242101
Product name: Ethyl 2-aminobenzoate
Purity: ≥96%, FCC, FG
Packaging: 1kg
Price: $173
Updated: 2024/03/01

Sigma-Aldrich

Product number: W242101
Product name: Ethyl 2-aminobenzoate
Purity: ≥96%, FCC, FG
Packaging: 10Kg
Price: $1070
Updated: 2024/03/01

Sigma-Aldrich

Product number: 242977
Product name: Ethyl 2-aminobenzoate
Purity: ≥99%
Packaging: 100g
Price: $61.9
Updated: 2024/03/01

Sigma-Aldrich

Product number: PHR9022
Product name: Ethyl 2-aminobenzoate
Purity: reference material
Packaging: 100MG
Price: $318
Updated: 2022/05/15

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ETHYL ANTHRANILATE Chemical Properties,Usage,Production

Chemical Properties

colourless liquid

Chemical Properties

Ethyl anthranilate has a faint, orange-flower odor and similar taste.

Occurrence

Reported found in grapes, orange juice, orange peel oil, starfruit and Vitis labrusca L.

Uses

Ethyl 2-aminobenzoate is used as a reactant in the amination of aryl chlorides, bromides, and triflates.

Uses

Perfumery and flavors, similar to methyl anthranilate.

Preparation

By esterification of anthranilic acid with ethanol in the presence of acid catalysts; by reacting sodium hypochlorite with an alkaline solution of phthalimide

Definition

ChEBI: Ethyl 2-aminobenzoate is a benzoate ester.

General Description

Colorless liquid with a fruity odor. Insoluble in water.

Air & Water Reactions

ETHYL ANTHRANILATE should be protected from air and light. Insoluble in water.

Reactivity Profile

ETHYL ANTHRANILATE may hydrolyze under acidic and basic conditions.

Fire Hazard

Flash point data for ETHYL ANTHRANILATE are not available. ETHYL ANTHRANILATE is probably combustible.

Pharmacology

Ethyl anthranilate behaved as a local anaesthetic, as measured by depression of muscle twitch, but was 50% less effective than the m- and p-aminobenzoate isomers. All three compounds potentiated the initial phase of caffeine-induced contracture of frog sartorius muscle, but the o-isomer had no effect on the peak tension of the contracture (Friedman, Bianchi & Weiss. 1974). It was proposed that the o-amino group has both steric and polar effects, its bulk preventing the inhibitory action of the carbonyl group on the caffeine-induced contracture of sartorius muscle, while the lone electron pair of the nitrogen atom induces a contracture on its own accord and potentiates a caffeine-induced contracture (Friedman, 1975).
Ethyl anthranilate (0-1 mmol/litre) decreased the frequency of the electric-organ discharges of the electric fish, Gnathonemus moori, but did not affect the individual pulse amplitudes, indicating that the compound acted on the pacemaker cells of the mesencephalic command nucleus (Walsh & Schopp, 1966).

Safety Profile

Moderately toxic by ingestion. A skin irritant. Combustible liquid. When heated to decomposition it emits toxic fumes of NOx.

ETHYL ANTHRANILATE Preparation Products And Raw materials

Raw materials

Sodium hypochlorite DIALIFOS Anthranilic acid

Preparation Products

Bentazone

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View Lastest Price from ETHYL ANTHRANILATE manufacturers

Hebei Zhuanglai Chemical Trading Co.,Ltd

Product: ETHYL ANTHRANILATE 87-25-2
Price: US $20.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 20MT
Release date: 2024-04-22

Hebei Yanxi Chemical Co., Ltd.

Product: ETHYL ANTHRANILATE 87-25-2
Price: US $20.00-9.00/kg
Min. Order: 1kg
Purity: 0.99
Supply Ability: 10 tons
Release date: 2023-10-12

Hebei Weibang Biotechnology Co., Ltd

Product: ETHYL ANTHRANILATE 87-25-2
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 500000kg
Release date: 2024-10-24

87-25-2, ETHYL ANTHRANILATERelated Search:

ALLYL ANTHRANILATE 1-GLYCERYL N-[7-CHLORO-4-QUINOLYL]ANTHRANILATE HYDROCHLORIDE ETHYL ANTHRANILATE DECYL ANTHRANILATE ETHYL 4,5-DIMETHOXY-2-NITROBENZOATE 2-(Dimethylamino)ethyl benzoate Phenylethyl Anthranilate ETHYL 2-NITROBENZOATE ETHYL 2-ISOCYANATOBENZOATE ETHYL 2-AMINO-4,5-DIMETHOXYBENZOATE ETHYL 4-(4-PENTYLOXYBENZYLIDENEAMINO)BENZOATE Ethyl 4-dimethylaminobenzoate Ethyl 3-aminobenzoate Tricaine methanesulfonate Ethyl 4-[[(methylphenylamino)methylene]amino]benzoate Ethyl 3,4-diaminobenzoate Ethyl 2-dimethylaminobenzoate Benzocaine

FEMA 2421

ETHYL ANTHRANILATE

ETHYL O-AMINOBENZOATE

ETHYL 2-AMINOBENZOATE

2-AMINOBENZOIC ACID ETHYL ESTER

ethyl-o-amino

o-(Ethoxycarbonyl)aniline

o-aminobenzoicacid,ethylester

o-amino-benzoicaciethylester

ETHYL ANTHRANILATE 96+% FCC

ETHYL 2-AMINOBENZOATE, 99+%

ETHYL-2-AMINOBENZOATE 99% (GC)

Ethylanthranilate,98+%

Ethylanthranilat

2-Aminobenzoic acid ethyl

Anthranilic acid ethyl

Ethyl 2-aminobenzoate,Ethyl anthranilate

4-(phenylmethylthio)quinazoline

ANTHRANILIC ACID ETHYL ESTER

2-(ethoxycarbonyl)aniline

2-amino-benzoicaciethylester

2-carboethoxyaniline

Aminobenzoicacid,ethylester

Benzoic acid, o-amino-, ethyl ester

benzoicacid,2-amino-,ethylester

Ethyl 2-aMinobenzoate, 99% 100GR

2-Aminobenzoic Acid Ethyl Ester Ethyl 2-Aminobenzoate Anthranilic Acid Ethyl Ester

Ethyl Anthranilate &gt

Tetracaine Impurity 6 (Ethyl 2-Aminobenzoate)

Ethyl anthranilate USP/EP/BP

ETHYL ANTHRANILATE FOR SYNTHESIS

Benzocaine Impurity D (BP)

87-25-2

H2NC6H4CO2C2H5

ESTER

Building Blocks

C8 to C9

Carbonyl Compounds

Organic Building Blocks

Esters

Aromatic Esters