ChemicalBook > CAS DataBase List > 1-Butyl nitrite

1-Butyl nitrite

Product Name
1-Butyl nitrite
CAS No.
544-16-1
Chemical Name
1-Butyl nitrite
Synonyms
BUTYL NITRITE;N-BUTYL NITRITE;NBN;n-C4H9ONO;NCI-C56553;NCL-C-56553;butylnitrites;N-Butynitrite;1-butylnitrite;ButylNitrite>
CBNumber
CB1295375
Molecular Formula
C4H9NO2
Formula Weight
103.12
MOL File
544-16-1.mol
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1-Butyl nitrite Property

Boiling point:
78 °C (lit.)
Density 
0.882 g/mL at 25 °C (lit.)
vapor pressure 
760 mm Hg ( 78 °C)
refractive index 
n20/D 1.376(lit.)
Flash point:
8 °F
storage temp. 
2-8°C
solubility 
alcohol: miscible(lit.)
form 
clear liquid
color 
Light yellow to Yellow
Water Solubility 
SLIGHTLY SOLUBLE
Merck 
14,1582
BRN 
1701036
Stability:
Light Sensitive, Volatile
InChIKey
NALZTFARIYUCBY-UHFFFAOYSA-N
LogP
2.35
CAS DataBase Reference
544-16-1(CAS DataBase Reference)
NIST Chemistry Reference
n-Butyl nitrite(544-16-1)
EPA Substance Registry System
Butyl nitrite (544-16-1)
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Safety

Hazard Codes 
F,T
Risk Statements 
11-23/25
Safety Statements 
16-24-45
RIDADR 
UN 2351 3/PG 2
WGK Germany 
1
RTECS 
RA0780000
8-10-23
TSCA 
Yes
HazardClass 
3.1
PackingGroup 
II
HS Code 
29209090
Toxicity
LD50 orally in Rabbit: 83 mg/kg
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H225Highly Flammable liquid and vapour

H301Toxic if swalloed

H330Fatal if inhaled

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P233Keep container tightly closed.

P240Ground/bond container and receiving equipment.

P241Use explosion-proof electrical/ventilating/lighting/…/equipment.

P242Use only non-sparking tools.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
226637
Product name
Butyl nitrite
Purity
95%
Packaging
25g
Price
$59.5
Updated
2024/03/01
Sigma-Aldrich
Product number
226637
Product name
Butyl nitrite
Purity
95%
Packaging
100g
Price
$196
Updated
2024/03/01
TCI Chemical
Product number
N0376
Product name
Butyl Nitrite
Purity
>95.0%(GC)
Packaging
25mL
Price
$53
Updated
2024/03/01
TCI Chemical
Product number
N0376
Product name
Butyl Nitrite
Purity
>95.0%(GC)
Packaging
500mL
Price
$422
Updated
2024/03/01
Alfa Aesar
Product number
H56501
Product name
n-Butyl nitrite, 95%
Packaging
100g
Price
$121.65
Updated
2024/03/01
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1-Butyl nitrite Chemical Properties,Usage,Production

Chemical Properties

CLEAR YELLOW LIQUID

Uses

Butyl nitrite is used in the manufacture of rare earth azides. It is used as a recreational drug due its vasodilator property.

Uses

It is used as pharmaceutical intermediate.

Definition

ChEBI: Butyl nitrite is a nitroso compound.

General Description

A yellow oily liquid with a pleasant odor. A mixture of isomers (n-butyl, sec-butyl and tert-butyl). Slightly soluble in water. Slightly less dense than water. Vapors are much heavier than air. Flash point about 15°F. Toxic by ingestion, mildly toxic by inhalation. Used to make fuel for jet airplanes.

Air & Water Reactions

Highly flammable.Slightly soluble in water.

Reactivity Profile

1-Butyl nitrite si an oxidizing agent but can serve as a reducing agent. May begin a vigorous reaction that culminates in a detonation if mixed with reducing agents, including hydrides, sulfides, nitrides, ammonium salts, cyanides, and many fuels.

Health Hazard

May cause toxic effects if inhaled or absorbed through skin. Inhalation or contact with material may irritate or burn skin and eyes. Fire will produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution.

Fire Hazard

HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water.

Flammability and Explosibility

Not classified

Safety Profile

A poison by ingestion and intraperitoneal routes. Mildly toxic by inhalation. An irritant. Human systemic effects by ingestion: methemoglobinemiacarboxyhemoglobinemia. Resembles amyl nitrite in causing fall in blood pressure, headache, pulse throbbing, and weakness. Mutation data reported. Flammable when exposed to heat or flame or by spontaneous chemical reaction. When heated to decomposition it emits toxic fumes of NOx. See also NITRITES, n-BUTYL ALCOHOL, and ESTERS

Environmental Fate

Butyl nitrite causes rapid S-nitrosyl glutathione formation and simultaneously reduces protein thiols, followed by marked adenosine triphosphate depletion. It also causes lipid peroxidation. It produces methemoglobinemia in which oxidized hemoglobin has no oxygen carrying capacity. Also, in the clinical state of methemoglobinemia, the unaltered hemoglobin shows an increased affinity for oxygen that results in symptoms of tissue hypoxia. Cyanosis occurs when methemoglobin levels are greater than 10%. Levels above 70% are potentially lethal.

Toxicity evaluation

It is an extremely flammable, insoluble liquid with vapor pressure of 62 mm Hg and boiling point of 75°C.

1-Butyl nitrite Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from 1-Butyl nitrite manufacturers

Hebei Mingeng Biotechnology Co., Ltd
Product
Butyl nitrite 544-16-1
Price
US $0.00/kg
Min. Order
10kg
Purity
99%
Supply Ability
500kg/month
Release date
2022-05-05
Hebei Senko Biotechnology Co., Ltd.
Product
1-Butyl nitrite 544-16-1
Price
US $5.00/KG/Tin
Min. Order
1KG
Purity
99%
Supply Ability
10Tons
Release date
2021-08-16
Zhuozhou Wenxi import and Export Co., Ltd
Product
1-Butyl nitrite 544-16-1
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-07-10

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