Reaction Uses
ChemicalBook > CAS DataBase List > 4-ETHYNYLANILINE

4-ETHYNYLANILINE

Reaction Uses
Product Name
4-ETHYNYLANILINE
CAS No.
14235-81-5
Chemical Name
4-ETHYNYLANILINE
Synonyms
P-ETHYNYLANILINE;P-APAC;p-Ethnylaniline;4-ETHYNYLANILINE;4-Ethyylanilinen;4-Ethynylaniline>4-ETHYNYLANILINE 97%;4-ethenylbenzenamine;4-ETHYNYLPHENYLAMINE;4-Ethynylaniline ,98%
CBNumber
CB1317965
Molecular Formula
C8H7N
Formula Weight
117.15
MOL File
14235-81-5.mol
More
Less

4-ETHYNYLANILINE Property

Melting point:
98-102 °C (dec.) (lit.)
Boiling point:
99-101 °C(Press: 13 Torr)
Density 
1.05±0.1 g/cm3(Predicted)
storage temp. 
Keep in dark place,Sealed in dry,Room Temperature
pka
3.11±0.10(Predicted)
form 
Crystalline Powder
color 
Yellow to brown
BRN 
2205181
InChIKey
JXYITCJMBRETQX-UHFFFAOYSA-N
CAS DataBase Reference
14235-81-5(CAS DataBase Reference)
More
Less

Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36-36/37
WGK Germany 
3
8-10-23
HS Code 
29214990
More
Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

More
Less

N-Bromosuccinimide Price

Sigma-Aldrich
Product number
481122
Product name
4-Ethynylaniline
Purity
97%
Packaging
5g
Price
$166
Updated
2024/03/01
TCI Chemical
Product number
E0505
Product name
4-Ethynylaniline
Purity
>98.0%(HPLC)
Packaging
10g
Price
$255
Updated
2024/03/01
TCI Chemical
Product number
E0505
Product name
4-Ethynylaniline
Purity
>98.0%(HPLC)
Packaging
25g
Price
$453
Updated
2024/03/01
GFS CHEMICALS
Product number
20331
Product name
4-ETHYNYLANILINE,99%
Packaging
5G
Price
$132.78
Updated
2021/12/16
TRC
Product number
E685073
Product name
4-Ethynylaniline
Packaging
1g
Price
$75
Updated
2021/12/16
More
Less

4-ETHYNYLANILINE Chemical Properties,Usage,Production

Reaction

4-Ethynylaniline, also known as p-ethynylaniline, is a terminal alkyne. Its synthesis using 2-methyl-3-butyn-2-ol (MEBYNOL) has been reported. The transition metal catalyzed polymerization of 4-ethynylaniline to afford poly(4-ethynylaniline) has been reported.[3]The impact of the surface functionalization with 4-ethynylaniline on the thermal behavior of multi-walled carbon nanotubes (MWNTs) and graphene has been investigated.

Uses

4-Ethynylaniline may be used in the synthesis of N-methyliminodiethyl 4-(4-ethynylphenyliminomethyl) benzeneboronate. It can also be used to prepare an acetylene ligand, HC2-NDI (NDI= 1,4,5,8-naphthalenediimide).It can be used as an alkyne component in a synthesis of indoles from nitroarenes in the presence of a palladium-phenantroline catalyst.

Chemical Properties

White or light yellow solid

Uses

4-Ethynylaniline may be used in the synthesis of N-methyliminodiethyl 4-(4-ethynylphenyliminomethyl)benzeneboronate. It can also be used to prepare an acetylene ligand, HC2-NDI (NDI= 1,4,5,8-naphthalenediimide).

Definition

ChEBI: 4-ethynylaniline is a substituted aniline.

Synthesis Reference(s)

The Journal of Organic Chemistry, 59, p. 5818, 1994 DOI: 10.1021/jo00098a051

General Description

4-Ethynylaniline, also known as p-ethynylaniline, is a terminal alkyne. Its synthesis using 2-methyl-3-butyn-2-ol (MEBYNOL) has been reported. The transition metal catalyzed polymerization of 4-ethynylaniline to afford poly(4-ethynylaniline) has been reported. The impact of the surface functionalization with 4-ethynylaniline on the thermal behavior of multi-walled carbon nanotubes (MWNTs) and graphene has been investigated.

4-ETHYNYLANILINE Preparation Products And Raw materials

Raw materials

Preparation Products

More
Less

4-ETHYNYLANILINE Suppliers

Matrix Fine Chemicals GmbH
Tel
--
Fax
--
Email
nfo@matrix-fine-chemicals.com
Country
Switzerland
ProdList
6968
Advantage
58
MATRIX MARKETING GMBH
Tel
--
Fax
--
Email
info@matrix-marketing.ch
Country
Switzerland
ProdList
312
Advantage
46
SIGMA-RBI
Tel
--
Fax
--
Country
Switzerland
ProdList
6896
Advantage
91
More
Less

View Lastest Price from 4-ETHYNYLANILINE manufacturers

Shanghai Qyubiotech Co., Ltd.
Product
4-ethynylaniline 14235-81-5
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
99%+
Supply Ability
10000kgs per Month
Release date
2023-08-16
Kindchem(Nanjing)Co.,Ltd
Product
4-ETHYNYLANILINE 14235-81-5
Price
US $0.00/Kg
Min. Order
1Kg
Purity
4-ETHYNYLANILINE
Supply Ability
50000kg
Release date
2022-11-15
Zhuozhou Wenxi import and Export Co., Ltd
Product
4-ETHYNYLANILINE 14235-81-5
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-07-11

14235-81-5, 4-ETHYNYLANILINERelated Search:


  • 4-Ethynylaniline ,98%
  • 4-Ethynylaniline,1-Amino-4-ethynylbenzene
  • p-Ethnylaniline
  • 4-ethenylbenzenamine
  • 4-Ethynyl aniline (4-aminophenylacetylene)
  • 4-ETHYNYLANILINE 97%
  • Benzenamine, 4-ethynyl- (9CI)
  • 4-ETHYNYLANILINE, 99%4-ETHYNYLANILINE, 99%4-ETHYNYLANILINE, 99%4-ETHYNYLANILINE, 99%
  • Erlotinib Hydrochloride iMpurity 41
  • 4-Ethynyl-benzenaMine
  • P-APAC
  • Benzenamine, 4-ethynyl-
  • P-ETHYNYLANILINE
  • 4-AMINOPHENYLACETYLENE
  • 4-ETHYNYLANILINE
  • 4-ETHYNYLPHENYLAMINE
  • 4-Ethynylaniline, 97.5%
  • Erlotinib Impurity 41
  • 1-AMINO-4-ETHYNYLBENZENE
  • 4-Ethynylaniline&gt
  • 4-aminophenoxyacetylene
  • 4-Ethyylanilinen
  • 14235-81-5
  • HCCC6H4NH2
  • HC8801CC6H4NH2
  • Chalcones, etc. (Building Blocks for Liquid Crystals)
  • Functionalized Acetylenes
  • Building Blocks for Liquid Crystals
  • Acetylenes
  • Organic Building Blocks
  • Terminal
  • Alkynes
  • Building Blocks
  • Acetylenes
  • Building Blocks for Liquid Crystals
  • Chalcones, etc. (Building Blocks for Liquid Crystals)
  • Functional Materials
  • Functionalized Acetylenes