ChemicalBook > CAS DataBase List > 4-Chloroindole

4-Chloroindole

Product Name
4-Chloroindole
CAS No.
25235-85-2
Chemical Name
4-Chloroindole
Synonyms
4-CHLORO-1H-INDOLE;NSC 88141;4-CHLOROINDOLE;Indole, 4-chloro-;4-CHLOROINDOLE 99%;4-Chloroindole >TIMTEC-BB SBB004057;4-Chloroindole ,99%;4 - chlorine indole;1H-Indole, 4-chloro-
CBNumber
CB1340273
Molecular Formula
C8H6ClN
Formula Weight
151.59
MOL File
25235-85-2.mol
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4-Chloroindole Property

Boiling point:
129-130 °C/4 mmHg (lit.)
Density 
1.259 g/mL at 25 °C (lit.)
refractive index 
n20/D 1.628(lit.)
Flash point:
>230 °F
storage temp. 
2-8°C
solubility 
ethanol: soluble50mg/mL, clear, colorless
pka
16.10±0.30(Predicted)
form 
liquid (clear)
color 
clear yellow
Specific Gravity
1.259
Water Solubility 
insoluble
BRN 
114880
Stability:
Store in Refrigerator
InChI
1S/C8H6ClN/c9-7-2-1-3-8-6(7)4-5-10-8/h1-5,10H
InChIKey
SVLZRCRXNHITBY-UHFFFAOYSA-N
SMILES
Clc1cccc2[nH]ccc12
CAS DataBase Reference
25235-85-2(CAS DataBase Reference)
NIST Chemistry Reference
1H-Indole, 4-chloro-(25235-85-2)
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Safety

Hazard Codes 
Xi,Xn
Risk Statements 
36/37/38-20/21/22
Safety Statements 
26-36-36/37/39
WGK Germany 
3
10
HazardClass 
IRRITANT
HS Code 
29339990
Storage Class
10 - Combustible liquids
Hazard Classifications
Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
246220
Product name
4-Chloroindole
Purity
98%
Packaging
1g
Price
$19.8
Updated
2023/06/20
TCI Chemical
Product number
C1248
Product name
4-Chloroindole
Purity
>98.0%(GC)
Packaging
1g
Price
$21
Updated
2025/07/31
TRC
Product number
C367000
Product name
4-Chloroindole
Packaging
5g
Price
$55
Updated
2021/12/16
TRC
Product number
C367000
Product name
4-Chloroindole
Packaging
50g
Price
$185
Updated
2021/12/16
Oakwood
Product number
016227
Product name
4-Chloroindole
Purity
95%
Packaging
1g
Price
$10
Updated
2021/12/16
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4-Chloroindole Chemical Properties,Usage,Production

Chemical Properties

Light-Yellow Liquid

Uses

Indole derivative. Inhibitor

General Description

The nitrosation rate of 4-chloroindole and the stability of its nitrosated products were studied.

Synthesis

1) Synthesis of N,N-dimethyl-2-chloro-6-nitrostyrene amine: 200g of 2-chloro-6-nitrotoluene, 183g of DMFDMA was added to 150ml of anhydrous DMF solution, heated to 80-120 ??, the reaction was kept warm for 4 hours, and the end point of the reaction was detected by a GC detector, and the resulting product was cooled down to room temperature and dissolved by adding 1L of toluene solution to the reaction system. After the reaction was complete, the product was cooled to room temperature, and 1L of toluene solution was added to the reaction system to dissolve the product, and after dissolution, the product was washed with saturated brine, after which it was dried with anhydrous sodium sulfate, filtered, and concentrated under reduced pressure to obtain 290g of N,N-dimethyl-2-chloro-6-nitrostyrene vinylamine crude product;

2) Synthesis of 4-chloroindole: 290g of the crude N,N-dimethyl-2-chloro-6-nitrostyrene vinylamine was dissolved in 250 ml of THF and 250 ml of methanol, and then the crude was added to the reaction system and dissolved in 250 ml of THF and 250 ml of methanol. 250 ml of THF and 250 ml of methanol in a mixed solvent, dissolved, under nitrogen protection, 30 ?? C, adding 40 g of Raney nickel, and dropwise addition of 300 ml of hydrazine hydrate with a purity of 80%, the N,N-dimethyl-2-chloro-6-nitrostyrene amine in the - NO2 is reduced to -NH2, the N,N-dimethyl-2-chloro-6-nitrostyrene amine in the - C = C- N- in the C-N bond is broken and the ring-closing reaction is carried out within the reaction system, the synthesis steps are as follows, the resulting product is filtered, the filtrate is concentrated and distilled under reduced pressure to obtain 135 g of 4-chloroindole pure product, and combining steps 1) and 2) to calculate the yield yields can be obtained from the 4-chloroindole obtained in a molar yield of 76.4%.

4-Chloroindole Preparation Products And Raw materials

Raw materials

Preparation Products

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4-Chloroindole Suppliers

Tongchuang Pharma(Suzhou). Co., Ltd.
Tel
0512-63263366 18912765016
Fax
0512-6326 3366
Email
tongtf110@sina.com
Country
China
ProdList
993
Advantage
62
J & K SCIENTIFIC LTD.
Tel
18210857532; 18210857532
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
4006356688 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
Advantage
62
3B Pharmachem (Wuhan) International Co.,Ltd.
Tel
821-50328103-801 18930552037
Fax
86-21-50328109
Email
3bsc@sina.com
Country
China
ProdList
15838
Advantage
69
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24529
Advantage
81
ShangHai DEMO Chemical Co.,Ltd
Tel
400-021-7337 2355568890
Fax
0086-21-50182339
Email
sales@demochem.com
Country
China
ProdList
2572
Advantage
57
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44801
Advantage
61
Capot Chemical Co., Ltd
Tel
+86 (0) 571 85 58 67 18
Fax
0086-571-85864795
Country
China
ProdList
18207
Advantage
66
JinYan Chemicals(ShangHai) Co.,Ltd.
Tel
13817811078
Fax
86-021-50426522,50426273
Email
sales@jingyan-chemical.com
Country
China
ProdList
9976
Advantage
60
Nanjing Chemlin Chemical Co., Ltd
Tel
025-83697070 13913916777;
Fax
+86-25-83453306
Email
info@chemlin.com.cn
Country
China
ProdList
15778
Advantage
64
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View Lastest Price from 4-Chloroindole manufacturers

LAURENT
Product
4-Chloroindole 25235-85-2
Price
US $0.00-0.00/g
Min. Order
1g
Purity
98%
Supply Ability
300kg
Release date
2026-01-29
WUHAN FORTUNA CHEMICAL CO., LTD
Product
4-Chloroindole 25235-85-2
Price
US $0.00/KG
Min. Order
1KG
Purity
98%min
Supply Ability
30tons/month
Release date
2023-02-02
Henan Bao Enluo International TradeCo.,LTD
Product
4-Chloroindole 25235-85-2
Price
US $30.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
1000tons
Release date
2023-08-23

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