3-Aminobenzeneboronic acid
- Product Name
- 3-Aminobenzeneboronic acid
- CAS No.
- 30418-59-8
- Chemical Name
- 3-Aminobenzeneboronic acid
- Synonyms
- 3-AMINOPHENYLBORONIC ACID;M-AMINOPHENYLBORONIC ACID;3-Boronoaniline;M-APBA;SKL739;EOS-62214;TIMTEC-BB SBB004197;3-Aminophenylboronic;3-Aminophenylboric Acid;3-aminophenylboronicaci
- CBNumber
- CB1357730
- Molecular Formula
- C6H8BNO2
- Formula Weight
- 136.94
- MOL File
- 30418-59-8.mol
3-Aminobenzeneboronic acid Property
- Melting point:
- 225 °C
- Boiling point:
- 376.0±44.0 °C(Predicted)
- Density
- 1.23±0.1 g/cm3(Predicted)
- storage temp.
- Keep in dark place,Inert atmosphere,Store in freezer, under -20°C
- form
- powder or crystals
- pka
- pK1: 4.46;pK2: 8.81 (25°C)
- color
- Off-white to light brown
- Water Solubility
- Soluble in water (partly miscible).
- InChI
- InChI=1S/C6H8BNO2/c8-6-3-1-2-5(4-6)7(9)10/h1-4,9-10H,8H2
- InChIKey
- JMZFEHDNIAQMNB-UHFFFAOYSA-N
- SMILES
- B(C1=CC=CC(N)=C1)(O)O
- CAS DataBase Reference
- 30418-59-8(CAS DataBase Reference)
Safety
- Hazard Codes
- Xi,Xn
- Risk Statements
- 36/37/38-22
- Safety Statements
- 26-36/37/39-37
- WGK Germany
- 3
- HazardClass
- IRRITANT
- HS Code
- 29310095
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405Store locked up.
N-Bromosuccinimide Price
- Product number
- 900988
- Product name
- 3-Aminophenylboronic acid
- Packaging
- 250mg
- Price
- $29.89
- Updated
- 2025/07/31
- Product number
- 900988
- Product name
- 3-Aminophenylboronic acid
- Packaging
- 1g
- Price
- $59.8
- Updated
- 2025/07/31
- Product number
- A615500
- Product name
- 3-Aminophenylboronic acid
- Packaging
- 1g
- Price
- $75
- Updated
- 2021/12/16
- Product number
- 261183
- Product name
- 3-Aminophenylboronic acid
- Packaging
- 5g
- Price
- $343
- Updated
- 2021/12/16
- Product number
- 8660-1-U0
- Product name
- 3-Aminobenzeneboronic acid
- Purity
- 98.0%
- Packaging
- 1g
- Price
- $20
- Updated
- 2021/12/16
3-Aminobenzeneboronic acid Chemical Properties,Usage,Production
Chemical Properties
hexagonal plates
Uses
3-Aminobenzeneboronic acid is used as an organic chemical synthesis intermediate. It is a boronic acid with potential use for biochemical research.
Uses
3-Aminobenzeneboronic acid is a boronic acid with potential use for biochemical research,it ie also used for suzuki reaction.
Synthesis
13331-27-6
30418-59-8
General method: 3-nitrophenylboronic acid (1 eq.), hexafluoroisopropanol (HFIP, 10 eq.) and iron powder (5 eq.) were added to the reaction tube and mixed. Subsequently, 2N aqueous hydrochloric acid solution was added dropwise to the reaction mixture. The reaction mixture was stirred at room temperature for 30 minutes and then neutralized with saturated aqueous sodium bicarbonate (NaHCO3). The organic layer was extracted three times with saturated aqueous sodium bicarbonate solution and combined. The organic layer was subsequently washed with brine, dried over anhydrous sodium sulfate (Na2SO4), filtered, and concentrated under reduced pressure. Finally, the crude product was purified by silica gel column chromatography to afford the target compound 3-aminophenylboronic acid.
References
[1] Tetrahedron Letters, 2017, vol. 58, # 37, p. 3646 - 3649
[2] Journal of the American Chemical Society, 1932, vol. 54, p. 4415,4418
[3] Journal of Organic Chemistry, 1937, vol. 2, p. 522,533
[4] Journal of the American Chemical Society, 1931, vol. 53, p. 713
[5] Patent: US2007/209123, 2007, A1. Location in patent: Page/Page column 7
3-Aminobenzeneboronic acid Preparation Products And Raw materials
Raw materials
Preparation Products
3-Aminobenzeneboronic acid Suppliers
- Tel
- 0512-0512-13285100231 13285100231
- 1119276773@qq.com
- Country
- China
- ProdList
- 54
- Advantage
- 58
- Tel
- 18210857532; 18210857532
- Fax
- 86-10-82849933
- jkinfo@jkchemical.com
- Country
- China
- ProdList
- 96815
- Advantage
- 76
- Tel
- 400-6106006
- Fax
- 021-67582001/03/05
- saleschina@alfa-asia.com
- Country
- China
- ProdList
- 30123
- Advantage
- 84
- Tel
- 400-021-7337 2355568890
- Fax
- 0086-21-50182339
- sales@demochem.com
- Country
- China
- ProdList
- 2572
- Advantage
- 57
- Tel
- 18515581800 18501085097
- Fax
- 010-89508210
- sales.bj@hwrkchemical.com
- Country
- China
- ProdList
- 9400
- Advantage
- 55
- Tel
- 021-021-58432009 400-005-6266
- Fax
- 021-58436166
- sales8178@energy-chemical.com
- Country
- China
- ProdList
- 44801
- Advantage
- 61
- Tel
- 86-027-67849912
- Fax
- 86-027-87531808
- sales@chemwish.com
- Country
- China
- ProdList
- 35896
- Advantage
- 56
- Tel
- +86 (0) 571 85 58 67 18
- Fax
- 0086-571-85864795
- Country
- China
- ProdList
- 18207
- Advantage
- 66
- Tel
- 13817811078
- Fax
- 86-021-50426522,50426273
- sales@jingyan-chemical.com
- Country
- China
- ProdList
- 9976
- Advantage
- 60
- Tel
- 0573-85285100 18627885956
- Fax
- 0573-85285100
- isenchem@163.com
- Country
- China
- ProdList
- 9310
- Advantage
- 66
View Lastest Price from 3-Aminobenzeneboronic acid manufacturers
- Product
- 3-Aminobenzeneboronic acid 30418-59-8
- Price
- US $10.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 10000kg
- Release date
- 2024-08-23
- Product
- 3-Aminobenzeneboronic acid 30418-59-8
- Price
- US $35.00-25.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 20 Ton
- Release date
- 2023-10-31
- Product
- 3-Aminobenzeneboronic acid 30418-59-8
- Price
- US $0.00-0.00/kg
- Min. Order
- 1kg
- Purity
- 99.9%
- Supply Ability
- 30000 Kg
- Release date
- 2023-12-01